Geochemical characteristics of major elements in the black soil profiles of the Hailun area, Heilongjiang Province and their implications for provenance
SONG Yun-Hong1,2,3(), YANG Feng-Chao1(), LIU Kai1,2,3, DAI Hui-Min1,2,3, XU Jiang1,2,3, HAN Xiao-Meng1,2,3
1. Shenyang Center of China Geological Survey, Shenyang 110034, China 2. Key Laboratory for Evolution and Ecological Effect in Black Land, Ministry of Natural Resources, Shenyang 110034, China 3. Key Laboratory for Evolution and Ecological Effect in Black Land of Liaoning Province, Shenyang 110034, China
The geochemical characteristics of the major elements in the black soil profiles and their ratios are closely related to the formation and development of the soil. They reflect the degree of the formation and development of soil as well as the environmental changes in the provenance areas. Moreover, they are important geological records of environmental evolution and climate change in the Songnen Plain. To explore the origin, provenance, and chemical weathering intensity of the typical black soil in northeast China, this study analyzed the major elements of nine representative black soil profiles in the Hailun area and then compared these elements with the element geochemical characteristics of typical aeolian deposits. The results are as follows. ①The sum of the content of the major elements (SiO2, Al2O3, and Fe2O3) and the UCC standardized curve of the Hailun black soil profiles were highly similar to those of typical aeolian deposits, indicating that the typical black soil in Hailun is aeolian; ②The average chemical index of alteration (CIA) was 63.97. The CIA-Na/K diagrams all indicated a low degree of chemical weathering. By comparison with the weathering intensity of typical aeolian deposits, the weathering intensity of the soil was in the order of loess in Huangshan, Harbin > loess in Xiashu, Zhenjiang > red clay in Xifeng > black soil in Hailun≈loess in Luochuan; ③The black soil at a depth of 0~30 cm has higher w(SiO2)/w(TiO2) and w(SiO2)/w(Al2O3) ratios than the black soil below 30 cm, indicating that the late typical black soil in Hailun has a coarser grain size and higher quartz content. The geochemical characteristics of the major elements indicate that the typical black soil in the surface layer and the deep layer may not have the same climate, environment, and provenance conditions, which may change at a depth of approximately 30 cm.
宋运红, 杨凤超, 刘凯, 戴慧敏, 许江, 韩晓萌. 黑龙江省海伦地区黑土剖面常量元素地球化学特征及其对物源的指示意义[J]. 物探与化探, 2022, 46(5): 1105-1113.
SONG Yun-Hong, YANG Feng-Chao, LIU Kai, DAI Hui-Min, XU Jiang, HAN Xiao-Meng. Geochemical characteristics of major elements in the black soil profiles of the Hailun area, Heilongjiang Province and their implications for provenance. Geophysical and Geochemical Exploration, 2022, 46(5): 1105-1113.
Powlson D S, Gregory P J, Whalley W R, et al. Soil management in relation to sustainable agriculture and ecosystem services[J]. Food Policy, 2011, 36:72-87.
Song Y H, Liu K, Dai H M, et al. Spatio-temporal variation of total N content in farmland soil of Songliao Plain in Northeast China during the past 35 years[J]. Geology in China, 2021, 48(1):332-333.
[3]
Song Y H, Dai H M, Yang F C, et al. A preliminary study on soil degradation and nutrient imbalance of typical black soil in Northeast China[C]// Proceedings of the 6th Academic Conference of Geology Resource Management and Sustainable Development, 2018:328-335.
Song Y H, Liu K, Dai H M, et al. Palynological Assemblages of typical black soil profile in the eastern Songliao Plain and their Age and Paleoclimatic Significances[J]. Geological Bulletin of China, 2020a, https://kns.cnki.net/kcms/detail/11.4648.P.20201015.0930.002.html.
Song Y H, Liu K, Dai H M, et al. The first reported of the AMS14C age of typical black soil mollisol—Paleosol profile of Songliao Plain[J]. Geology in China, 2020, 47(6):1926-1927.
Zhang X R, Ping S F, Jiao J Y, et al. Characteristics of magentic susceptibility,grain size and chromaticity of modern sedimentsin the southern margin of Songnen Plain and their paleoclimate environment significance[J]. Journal of Jlilin University:Earth Science Edition, 2020, 50(2):465-479.
Song Y H, Liu Z K, Yang F C, et al. Vertical distribution characteristics of main nutrient elements in typical black soil profile before and after reclamation in Helun Area,Heilongjiang Province[J]. Geology and Resources, 2020, 26(6):543-549.
[8]
Song Y H, Dai H M, Yang F C, et al. Temporal and spatial change of soil organic matter and pH in cultivated land of the Songliao Plain in Northeast China during the past 35 years[J]. Acta Geologica Sinica:English Edition, 2019, 93(S1):142-143.
Shi W J, Wang J K, Wei D, et al. Spatial variability of soil trace elements in black soil region of south Heilongjiang province and its affecting factors:A case study of Shuangcheng city[J]. Acta pedologica sinica, 2009, 46(2):342-347.
Jia S H, Zhang J N, Zhang Y L, et al. Changes of the characteristics of soil organic carbon and total nitrogen after conversation from upland to paddy field in black soil region of Northeast China[J]. Scientia Agricultura Sinica, 2017, 50(7):1252-1262.
Han X Z, Li N. Research progress of black soil in Northeast China[J]. Scientia Geographica Sinica, 2018, 38(7):1032-1041.
doi: 10.13249/j.cnki.sgs.2018.07.004
Cui M, Zhang X D, Cai Q G, et al. Relationship between black soil development and climate change and geomorphological evolution in Northeast China[J]. Geographical Research, 2008, 27(3):527-535.
doi: 10.11821/yj2008030006
Qi L, Qiao Y S, Wang Y, et al. Geochemical characteristics of the Xiashu loess-palaeosol sequence in Nanjing and their implicationa for provence[J]. Quaternary Sciences, 2020, 40(1):190-202.
Chen L Y, Zhang K, Fu J L, et al. Major element geochemical characteristics of Mangshan loess since L5 and its implications for provenance[J]. Quaternary Sciences, 2017, 37(6):1293-1308.
[15]
Hao Q Z, Guo Z T, Qiao Y S, et al. Geochemical evidence for the provenance of Middle Pleistocene loess deposits in Southern China[J]. Quaternary Science Reviews, 2010, 29(23/24):3317-3326.
doi: 10.1016/j.quascirev.2010.08.004
[16]
Guan H C, Zhu C, Zhu T X, et al. Grain size,magnetic susceptibility and geochemical characteristics of the loess in the Chaohu Lake basin: Implications for the origin,palaeoclimatic change and provenance[J]. Journal of Asian Earth Sciences, 2016, 117: 170-183.
doi: 10.1016/j.jseaes.2015.12.013
[17]
Li Y, Song Y G, Chen X L, et al. Geochemical composition of Tajikistan loess and its provenance implications[J]. Palaeogeography,Palaeoclimatology,Palaeoecology, 2016, 446: 186-194.
doi: 10.1016/j.palaeo.2016.01.025
[18]
Zhang L, Qin X G, Liu J Q, et al. Geochemistry of sediments from the Huaibei Plain (East China):Implications for provenance,weathering,and invasion of the Yellow River into the Huaihe River[J]. Journal of Asian Earth Sciences, 2016, 121:72-83.
doi: 10.1016/j.jseaes.2016.02.008
Wu P, Xie Y Y, Kang C G, et al. The genesis of Huangshan loess in Harbin: Integrated evidence from grain size,geochemistry,magnetization,sedimentation and landform[J]. Acta Geoscientica Sinica, 2020, 41(3):420-430.
Chen J, Ji J F, Chou G, et al. Geochemical study on chemical weathering degree of loess in Luochuan,Shaanxi Province[J]. Science in China(Series D):Earth Sciences, 1997, 27(6):531-536.
[21]
Chen Y Y, Li X S, Han Z Y, et al. Chemical weathering intensity and element migration features of the Xiashu loess profile in Zhenjiang,Jiangsu Province[J]. Journal of Geographical Sciences, 2008, 18(3):341-352.doi:10.1007/s11442-008-0341-9.
doi: 10.1007/s11442-008-0341-9
Chen Y, Chen J, Liu L W. Chemical composition and characterization of chemical weathering of late tertiary red clay in Xifeng,Gansu Province[J]. Journal of Geomechanics, 2001, 7(2):167-175.
Mao X, Liu L J, Li C A, et al. Elemental composition features of loess-paleosol profile in Fengning,Hebei Provinc[J]. Earth Science, 2017, 42(10):1750-1759.
[24]
McLennan S M. Weathering and global denudation[J]. The Journal of Geology, 1993, 101(2):295-303.
doi: 10.1086/648222
Han X M, Dai H M, Liang S, et al. Elemental geochemistry characteristics and environmental indication of typical black soil profile in Baiquan Area,Heilongjiang Province[J]. Geology and Resources, 2020, 29(6):556-563.
Wang P, Ning K, Shi Y C, et al. Geochemical characteristics of major elements of holocene soil from Wuqi,Shaanxi Province[J]. Chinese Journal of Soil Science, 2019, 50(6): 1261-1268.
Xu S J, Ni Z C, Ding X C. Geochemical characteristics of major elements of the Pingyin loess in Shandong Province[J]. Bulletin of Mineralogy,Petrology and Geochemistry, 2016, 35(2):353-359.
[28]
Blanca B, Maria J M, Constanza F N, et al. Geochemistry of precambrian and paleozoic siliciclastic rocks from the iberian range(NE Spain):Implications for source-area weathering,sorting,provenance,and tectonic setting[J]. Chemical Geology, 2000, 168(1):135-150.doi:10.1016/S0009-2541(00)00192-3.
doi: 10.1016/S0009-2541(00)00192-3
[29]
文启忠. 中国黄土地球化学[M]. 北京: 科学出版社, 1989:71-133.
[29]
Wen Q Z. Loess geochemistry in China[M]. Beijing: Science Press, 1989:71-133.
Li H, Huang Y, Zhang Q R, et al. Soil geochemical characteristics and influencing factors in Beijing Plain[J]. Geophysical and Geochemical Exploration, 2021, 45(2):502-516.
Liu Y F, Sun B B, H L, et al. Distribution characteristics of elements in vertical soil profile in Longhai,Fujian province[J]. Geophysical and Geochemical Exploration, 2016, 40(4): 713-721.
[32]
Gallet S, Jahn B, Torii M. Geochemical characterizati0n of the Luochuan loess paleosol sequence,China,and paleoclimatic implications[J]. Chemical Geology, 1996, 133(14):67-88.
doi: 10.1016/S0009-2541(96)00070-8
[33]
Chen J, An Z S, Liu L W, et al. Variations in chemical compositions of the eolian dust in Chinese Loess Plateau over past 2.5Ma and chemical weathering in the Asian inland[J]. Science in China (Series D):Earth Sciences, 2001, 44(5):403-413.
Gu Z Y, Ding Z L, Xiong S F, et al. A seven million geochemical record from Chinese red-clay and loess-paleosol sequence:Weathering and erosion in northwestern China[J]. Quaternary sciences, 1999, 19(4):357-365.
[35]
Yang L H, Zhou J, Lai Z P, et al. Lateglacial and Holocene dune evolution in the Horqin dunefield of northeastern China based on luminescence dating[J]. Palaeogeography,Palaeoclimatology,Palaeoecology, 2010, 296:44-51.
doi: 10.1016/j.palaeo.2010.06.014
[36]
Peng S Z, Guo Z T. Geochemical indicator of original eolian grain size and implications on winter monsoon evolution[J]. Science in China (Series D):Earth Sciences, 2001, 44(1): 261-266.
[37]
Xiao J L, Porter S C, An Z S, et al. Grain size of quartz as an indicator of winter monsoon strength on the Loess Plateau of Central China during the last 130,000 yr[J]. Quaternary Research, 1995, 43(1):22-29.
doi: 10.1006/qres.1995.1003
[38]
An Z S, Porter S C. Millennia1 scale climatic oscillations during the last interglaciation in Central China[J]. Geology, 1997, 25(7):603-606.
doi: 10.1130/0091-7613(1997)025<0603:MSCODT>2.3.CO;2
[39]
Chen J, Li G. Geochemical studies on the source region of asian dust[J]. Science China Earth Sciences, 2011, 54(9):1279-1301.doi:10.1007/s11430-011-4269-z.
doi: 10.1007/s11430-011-4269-z