Please wait a minute...
E-mail Alert Rss
 
物探与化探  2025, Vol. 49 Issue (2): 490-499    DOI: 10.11720/wtyht.2025.2480
  生态地质调查 本期目录 | 过刊浏览 | 高级检索 |
鄂西典型高硒区土壤和农作物硒含量特征及其影响因素研究
秦浩林1(), 李明龙2,3(), 郑德顺1, 孙风波1, 张凯3
1.河南理工大学 资源与环境学院,河南 焦作 454000
2.资源与生态环境地质湖北省重点实验室(湖北省地质局),湖北 武汉 430034
3.湖北省地质局 第二地质大队,湖北 恩施 445000
Characteristics and influencing factors of selenium content in soils and crops in typical high-selenium-content regions of western Hubei Province, China
QIN Hao-Lin1(), LI Ming-Long2,3(), ZHENG De-Shun1, SUN Feng-Bo1, ZHANG Kai3
1. School of Resources and Environment, Henan Polytechnic University, Jiaozuo 454000, China
2. Hubei Key Laboratory of Resource and Eco-Environment Geology (Hubei Geological Bureau), Wuhan 430034, China
3. Second Geological Brigade of Hubei Geological Bureau, Enshi 445000, China
全文: PDF(3616 KB)   HTML
输出: BibTeX | EndNote (RIS)      
摘要 

掌握硒在土壤和农作物中的分布规律对于富硒产业发展至关重要。湖北省恩施市分布大量富硒土壤,为发展当地富硒农业,本文以鄂西典型高硒区恩施新塘乡为研究区,通过对2 469件土壤样和玉米、土豆、水稻、萝卜、白菜、茶叶6种共237件农作物样的硒地球化学数据进行整理分析,系统地总结出该区土壤硒分布规律及影响农作物硒含量的因素。结果表明:新塘乡表层土壤硒含量范围为(0.14~25.74)×10-6,背景值为0.81×10-6,是全国土壤硒背景值的3.7倍,且达到富硒土壤标准的土壤面积占总面积的86.23%,存在2条NEE向的富硒带;土壤硒空间分布与成土母质密切相关,成土母质为二叠系黑色岩系的土壤中硒含量明显较高,富集系数达到3.74;高硒区水稻、萝卜、白菜富硒率均超过65%,除土豆外的农作物硒含量与对应根系土硒含量均呈正相关,其中茶叶(P<0.01,R=0.84)相关性最高,说明富硒作物硒含量与根系土硒含量关系密切;成土母质为二叠系黑色岩系类及三叠系碳酸盐岩类的耕地区农作物硒生物富集系数较高,成土母质为二叠系黑色岩系的农作物中硒平均值最高,说明成土母质对农作物硒含量影响较大。

服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
秦浩林
李明龙
郑德顺
孙风波
张凯
关键词 新塘乡富硒土壤分布规律农作物硒含量影响因素    
Abstract

Understanding the distribution patterns of selenium in soils and crops is critical to developing selenium-rich industries. Enshi City in Hubei Province is known for its extensive selenium-rich soils, establishing this city as a promising area for selenium-rich agriculture. This study investigated Xintang Township in Enshi. Based on the organization and analysis of the geochemical data of 2 469 soil samples and 237 crop samples of maize, potatoes, rice, radish, cabbage, and tea, this study offered a systematic summary of the selenium distribution in soils and factors influencing selenium content in crops in the study area. The results indicate that the topsoils exhibit selenium content ranging from 0.14×10-6 to 25.74×10-6, with a background value of 0.81×10-6, which is 3.7 times the national background of selenium content in soils. Selenium-rich soils cover 86.23% of the total area of the study area, and two NEE-directed selenium-rich belts are found. The spatial distribution of selenium in soils is closely related to soil-forming parent materials. Soils with Permian black rock series as parent materials exhibit notably higher selenium content, with an enrichment coefficient of 3.74. In high-selenium-content areas, rice, radish, and cabbage exhibit selenium enrichment rates exceeding 65%. Except for potatoes, crops display positive correlations between their selenium content and the selenium content in their root soils, with tea showing the highest correlation (P<0.01, R=0.84). This suggests a close relationship between the selenium content in crops and their root soils. The crops in cultivated areas with Permian black rock series and Triassic carbonate rock series as soil-forming parent materials exhibit high bioconcentration factors of selenium, with soils and crops with Permian black rock series as soil-forming parent materials presenting the highest average selenium content. This highlights the significant impacts of soil-forming parent materials on crop selenium content.

Key wordsXintang Township    high-selenium soil    distribution pattern    crop    selenium content    influencing factor
收稿日期: 2023-11-04      修回日期: 2024-05-11      出版日期: 2025-04-20
ZTFLH:  X142  
  X825  
基金资助:国家自然科学基金青年基金项目(42302070);湖北省金土地工程项目(HBJTD20180105)
通讯作者: 李明龙(1988-),男,湖北枣阳人,高级工程师,博士,主要从事沉积学及硒的环境地球化学研究工作。Email:leeminglong@126.com
作者简介: 秦浩林(1998-),男,河南信阳人,主要从事沉积学及地球化学研究工作。Email:75830261@qq.com
引用本文:   
秦浩林, 李明龙, 郑德顺, 孙风波, 张凯. 鄂西典型高硒区土壤和农作物硒含量特征及其影响因素研究[J]. 物探与化探, 2025, 49(2): 490-499.
QIN Hao-Lin, LI Ming-Long, ZHENG De-Shun, SUN Feng-Bo, ZHANG Kai. Characteristics and influencing factors of selenium content in soils and crops in typical high-selenium-content regions of western Hubei Province, China. Geophysical and Geochemical Exploration, 2025, 49(2): 490-499.
链接本文:  
https://www.wutanyuhuatan.com/CN/10.11720/wtyht.2025.2480      或      https://www.wutanyuhuatan.com/CN/Y2025/V49/I2/490
Fig.1  新塘乡采样点分布(a)及地层分布(b)[18]
地区 背景值/10-6 变幅/10-6 数据来源
新塘乡 0.81 0.14~25.74 本文
恩施市 9.36 2.70~87.30 [22]
黑龙江省 0.15 0.01~0.66 [23]
香港 0.76 0.07~2.26 [24]
全国 0.22 0.05~0.99 [25]
巴西 0.19 0.09~1.61 [26]
全球 0.40 [27]
Table 1  新塘乡土壤Se与其他地区Se背景值的比较
Fig.2  新塘乡表层土壤硒含量分布(a)及等级(b)
指标 缺乏 边缘 适量 丰富 极丰富 富硒标准
标准值/
10-6
≤0.125 0. 125~
0.175
0.175~
0.40
0.40~
3.00
≥3.00 ≥0.45
样品数量 0 5 225 1964 275 2129
占比/% 0 0.20 9.11 79.55 11.14 86.23
Table 2  土壤硒等级划分
成土母质 硒含量/10-6 总样
品数
EF
范围 平均值
S1lr碎屑沉积岩类风化区 0.18~1.04 0.47 65 0.55
S1-2s碎屑沉积岩类风化区 0.24~1.10 0.51 178 0.61
D2y-D3C1x 碎屑沉积岩类
风化区
0.19~2.80 0.71 431 0.84
C2d+h碳酸盐岩类风化区 0.26~3.54 0.74 133 0.94
P1l+q黑色岩系风化区 0.16~9.41 0.85 224 1.19
P1m+g黑色岩系风化区 0.33~25.74 2.19 448 3.12
P2l-d黑色岩系风化区 0.20~20.70 2.82 419 3.74
T1d碳酸盐岩类风化区 0.14~23.23 1.44 571 1.71
Table 3  不同地质背景区表层土壤硒含量
Fig.3  成土母质与硒含量等级叠合分析
作物 总样品数 样品数 硒含量/10-6 CV/% 富硒率/%
一级 二级 三级 极差 平均值 标准差
玉米 70 13 17 40 0.02~3.54 0.16 0.38 235 42.86
土豆 48 3 3 42 0.01~1.59 0.05 0.05 105 12.50
水稻 25 17 2 6 0.05~3.99 0.50 0.57 114 76.00
萝卜 38 25 10 3 0.06~3.85 0.41 0.79 193 65.79
白菜 31 21 6 4 0.05~3.74 1.42 1.78 125 67.74
茶叶 38 14 13 11 0.03~3.48 0.40 0.68 170 36.84
Table 4  新塘乡农作物硒含量统计
Fig.4  新塘乡农作物与根系土硒含量散点图
农作物 S D C P T
玉米 5.69 3.74 5.96 7.14 15.06
土豆 4.19 2.89 4.36 5.21 5.38
水稻 13.46 14.94 10.83 23.60 15.17
萝卜 18.95 14.10 21.74 36.60 60.04
白菜 23.68 17.86 19.23 55.88 83.34
茶叶 11.60 10.51 8.16 26.42 23.92
Table 5  不同地质年代成土母质中农作物生物富集系数
Fig.5  不同地质年代成土母质与农作物生物富集系数关系
[1] Rayman M P. The Importance of selenium to human health[J]. Clinical Toxicology, 1980, 17(2):171-230.
[2] 中国环境监测总站. 中国土壤元素背景值[M]. 北京: 中国环境科学出版社, 1990.
[2] China National Environmental Monitoring Centre. Background value of soil elements in China[M]. Beijing: China Environmental Science Press, 1990.
[3] Yang G, Chen J, Wen Z, et al. The role of selenium in Keshan disease[J]. Advances in Nutritional Research, 1985, 6(1):203-231.
[4] Ning Y, Hu M, Chen S, et al. Investigation of selenium nutritional status and dietary pattern among children in Kashin-beck disease endemic areas in Shaanxi Province,China using duplicate portion sampling method[J]. Environment International, 2022, 164:107255-107255.
[5] Yang G, Wang S, Zhou R, et al. Endemic Se intoxication of humans in China[J]. American Journal of Clinical Nutrition, 1983, 37(5):872-881.
pmid: 6846228
[6] 贺栋, 祁珊珊, 郑红星, 等. 硒的生理功能及富硒产品研究进展[J]. 食品研究与开发, 2023, 44(1):191-196.
[6] He D, Qi S S, Zheng H X, et al. Physiological functions of selenium and selenium-enriched products:A review[J]. Food Research and Development, 2023, 44(1):191-196.
[7] 周诗悦, 李茉, 周晨霓, 等. 硒在“土壤—作物—食品—人体”食物链中的流动[J]. 食品科学, 2023, 44(9):231-244.
[7] Zhou S Y, Li M, Zhou C N, et al. Flow of selenium in the “soil-crop-food-human” Chain[J]. Food Science, 2023, 44(9):231-244.
doi: 10.7506/spkx1002-6630-20220716-184
[8] Khanam A, Platel K. Bioaccessibility of selenium,selenomethionine and selenocysteine from foods and influence of heat processing on the same[J]. Food Chemistry, 2016, 194(1):1293-1299.
[9] Sharma N, Prakash R, Srivastava A, et al. Profile of selenium in soil and crops in seleniferous area of Punjab,India by neutron activation analysis[J]. Journal of Radioanalytical and Nuclear Chemistry, 2009, 281(1):59-62.
[10] 郝栗涛, 张湜溪, 雒昆利. 陕西省典型高硒土壤的空间分布及主要农作物硒的含量特征和主要来源研究[J]. 环境科学研究, 2023, 36(5):1032-1041.
[10] Hao L T, Zhang S X, Luo K L. Study on spatial distribution of typical high-selenium soil and content characteristics and main sources of selenium in main crops in Shaanxi Province[J]. Research of Environmental Sciences, 2023, 36(5):1032-1041.
[11] 周文辉, 李雪珍, 李永春, 等. 宁夏固原原州区土壤及农作物硒地球化学特征及其研究意义[J]. 地质论评, 2023, 69(2):795-808.
[11] Zhou W H, Li X Z, Li Y C, et al. Geochemical characteristics of selenium in soils and crops andits significance in Yuanzhou District,Guyuan,Ningxia[J]. Geological Review, 2023, 69(2):795-808.
[12] Jiang C, Zhou W, Yang L, et al. Geochemical relationship and profile distribution of selenium and cadmium in typical selenium-enriched areas in Enshi[J]. Chemosphere, 2023, 338:139423-139423.
[13] Zhu J, Wang N, Li S, et al. Distribution and transport of selenium in Yutangba,China:Impact of human activities[J]. Science of the Total Environment, 2007, 392(2):252-261.
[14] Cui L, Zhao J, Chen J, et al. Translocation and transformation of selenium in hyperaccumulator plant Cardamine enshiensis from Enshi,Hubei,China[J]. Plant and Soil, 2018, 425(1/2):577-588.
[15] Wang M, Li B Q, Li S, et al. Selenium in wheat from farming to food[J]. Journal of Agricultural and Food Chemistry, 2021, 69(51):15458-15467.
doi: 10.1021/acs.jafc.1c04992 pmid: 34907773
[16] 曾庆良, 余涛, 王锐. 土壤硒含量影响因素及富硒土地资源区划研究——以湖北恩施沙地为例[J]. 现代地质, 2018, 32(1):105-112.
[16] Zeng Q L, Yu T, Wang R. The influencing factors of selenium in soils and classifying the selenium-rich soil resources in the typical area of Enshi,Hubei[J]. Geoscience, 2018, 32(1):105-112.
[17] 郭宇. 恩施地区硒的地球化学研究及富硒作物栽培实验研究[D]. 武汉: 中国地质大学(武汉), 2012.
[17] Guo Y. Geochemistry of selenium in Enshi area and experimental study of selenium-enriched crop cultivation[D]. Wuhan: China University of Geosciences (Wuhan), 2012.
[18] 李明龙. 表生环境介质中硒与重金属的地球化学特征及生态效应研究——以湖北省恩施市为例[D]. 成都: 成都理工大学, 2021.
[18] Li M L. Geochemical characteristics and ecological effects of Se and heavy metals in supergene environmental media:A case study of Enshi City,Hubei Province[D]. Chengdu: Chengdu University of Technology, 2021.
[19] 中华人民共和国国土资源部. DZ/T 0258—2014多目标区域地球化学调查规范(1:250 000)[S]. 2014.
[19] Ministry of Land and Resources of the People's Republic of China. DZ T 0258—2014 Specification of multi-purpose regional geochemical survey(1:250,000)[S]. 2014.
[20] 中国地质调查局. DD2005-03生态地球化学评价样品分析技术要求(试行)[S]. 2005.
[20] China Geological Survey. DD2005-03 Technical requirements for sample analysis of ecological geochemical evaluation (Trial)[S]. 2005.
[21] Zoller W, Duce R. Atmospheric concentrations and sources of trace metals at the south Pole[J]. Science, 1974, 183(4121):198-200.
pmid: 17777264
[22] Qin H B, Zhu J M, Liang L, et al. The bioavailability of selenium and risk assessment for human selenium poisoning in high-Se areas,China[J]. Environment International, 2013, 52(1):66-74.
[23] 迟凤琴, 徐强, 匡恩俊, 等. 黑龙江省土壤硒分布及其影响因素研究[J]. 土壤学报, 2016, 53(5):1262-1274.
[23] Chi F Q, Xu Q, Kuang E J, et al. Distribution of selenium and its influencing factors in soils of Heilongjiang Province,China[J]. Acta Pedologica Sinica, 2016, 53(5):1262-1274.
[24] 章海波, 骆永明, 吴龙华, 等. 香港土壤研究II:土壤硒的含量、分布及其影响因素[J]. 土壤学报, 2005, 42(3):404-410.
[24] Zhang H B, Luo Y M, Wu L H, et al. Hong Kong soil reserches II:Distribution and contect of selenium in soils[J]. Acta Pedologica Sinica, 2005, 42(3):404-410.
[25] 侯青叶. 中国土壤地球化学参数[M]. 北京: 地质出版社, 2020.
[25] Hou Q Y. Soil geochemical parameters in China[M]. Beijing: Geological Publishing House, 2020.
[26] Gabos M B, Alleoni L R F, Abreu C A. Background levels of selenium in some selected Brazilian tropical soils[J]. Journal of Geochemical Exploration, 2014, 145(1):35-39.
[27] Fordyce F M. Selenium deficiency and toxicity in the environment[M]. Belin: Springer Netherlands, 2012:375-416.
[28] 中华人民共和国国土资源部. 土地质量地球化学评价规范DZ/T 0295—2016[S]. 2016.
[28] Ministry of Land and Resources of the People’s Republic of China. DZ/T 0295—2016 Geological and Mineral Industry Standard[S]. 2016.
[29] 谭见安, 朱文郁, 李日邦, 等. 克山病与环境硒等生命元素的关系[J]. 中国地方病学杂志, 1991, 10(5):15-20.
[29] Tian J A, Zhu W Y, Li R B, et al. New progress in the causal association of Keshan disease with environmental selenium in China[J]. China Jousal of Endemiology, 1991, 10(5):15-20.
[30] Chang H, Zhu J M, Lin Z Q, et al. Topographic constraints on the distribution of selenium in the supergene environment:A case study at Yutangba,China[J]. Environmental pollution, 2023:121026-121026.
[31] Gong J J, Yang J Z, Wu H, et al. Distribution of soil selenium and its relationship with parent rocks in Chengmai County,Hainan Island,China[J]. Applied Geochemistry, 2022, 136:105147.
[32] Liu W H, Wu Y Q, Zhong Y Z, et al. Concentrations,distribution and influencing factors of selenium (Se) in soil of arid and semi-arid climate:A case from Zhangye-Yongchang Region,North-Western China[J]. Journal of Geochemical Exploration, 2023, 250:107239.
[33] 李明龙, 徐辉, 许克元, 等. 恩施地区富硒地层分布规律及其控制因素探讨[J]. 资源环境与工程, 2018, 32(4):557-562.
doi: 10.16536/j.cnki.issn.1671-1211.2018.04.008
[33] Li M L, Xu H, Xu K Y, et al. Discussion on distribution regularity and controlling factors of selenium-rich strata in Enshi,Hubei Province[J]. Resources Environment & Engineering, 2018, 32(4):557-562.
[34] 中华全国供销合作总社. GH/T 1135—2017富硒农产品[S]. 2017.
[34] All China Federation of Supply and Marketing Cooperatives. GH/T 1135—2017 Se-enriched agricultural products[S]. 2017.
[35] 湖北省卫生健康委员会. DBS42/002—2022富有机硒食品硒含量要求[S]. 2022.
[35] Health Commission of Hubei Province. DBS42/002—2022 Selenium content requirements of organic selenium rich food[S]. 2022.
[36] Dinh Q T, Wang M K, Tran T A T, et al. Bioavailability of selenium in soil-plant system and a regulatory approach[J]. Critical Reviews in Environmental Science and Technology, 2019, 49(6):443-517.
[37] 吕瑶瑶. 典型生态地带硒元素生物有效性的控制机理研究[D]. 北京: 中国地质大学(北京), 2016.
[37] Lyu Y Y. The regulation mechanism of selenium bioavailability in typical ecological landscape[D]. Beijing: China University of Geosciences (Beijing), 2016.
[1] 廖启林, 黄顺生, 许伟伟, 崔晓丹, 金洋, 刘玲, 汪媛媛, 李文博, 周强. 江苏省里下河地区富硒土壤元素地球化学特征及其成因机制[J]. 物探与化探, 2024, 48(4): 1114-1124.
[2] 肖凯琦, 徐宏根, 戴亮亮, 李毅, 李凯. 凤凰县土壤—农作物系统中Cd含量及迁移富集特征[J]. 物探与化探, 2024, 48(4): 1136-1145.
[3] 齐娟娟. 基于微动的千米深度勘探关键影响因素[J]. 物探与化探, 2024, 48(3): 777-785.
[4] 史敬涛, 刘俊建, 张军超, 王江玉龙, 姜禹戈, 王末, 李横飞, 杨文号, 颜翔锦. 浅山区典型小流域土壤重金属影响因素及来源分析[J]. 物探与化探, 2024, 48(3): 834-846.
[5] 余飞, 王锐, 周皎, 张风雷, 蒋玉莲, 张云逸, 朱世林. 典型汞矿区周边耕地土壤重金属来源解析与农作物健康风险评价[J]. 物探与化探, 2024, 48(3): 847-857.
[6] 蒋羽雄, 文美兰, 潘启明, 蒋柏昌, 王忠伟. 广西荔浦市土壤—农作物中重金属迁移转化及生态效应[J]. 物探与化探, 2024, 48(3): 858-867.
[7] 彭学锐, 陈翔, 周思裕. 广西梧州六堡茶茶叶及根系土中硒含量影响因素[J]. 物探与化探, 2024, 48(2): 545-554.
[8] 任蕊, 张志敏, 王晖, 陈继平, 乔新星, 梁东丽. 陕西关中土壤富硒标准研究与探讨——以小麦为例[J]. 物探与化探, 2023, 47(5): 1354-1360.
[9] 多吉卫色, 次仁旺堆, 尼玛洛卓, 周鹏, 尼玛次仁. 西藏白朗县农田系统硒含量特征及影响因素[J]. 物探与化探, 2023, 47(4): 1118-1126.
[10] 黄平安, 王夏青, 唐湘玲, 王玉堂, 李玮, 罗增, 吕飞亚. X射线荧光光谱岩心扫描影响因素及校正方法的研究进展[J]. 物探与化探, 2023, 47(3): 726-738.
[11] 包凤琴, 成杭新, 永胜, 周立军, 杨宇亮. 包头南郊农田土壤环境质量特征及农作物健康风险评价[J]. 物探与化探, 2023, 47(3): 816-825.
[12] 张亚峰, 姬丙艳, 沈骁, 姚振, 马强, 王帅, 贺连珍, 韩伟明. 西宁盆地咸水湖相沉积型富硒土壤的形成机理及意义[J]. 物探与化探, 2023, 47(2): 470-476.
[13] 李世宝, 杨立国, 熊万里, 马志超, 袁宏伟, 段吉学. 内蒙古巴彦淖尔市临河区富硒耕地硒形态特征及其影响因素[J]. 物探与化探, 2023, 47(2): 477-486.
[14] 赵军, 孟欣佳, 李冰, 刘志民. 坑道聚焦直流激电法电流场分布特性及探测影响因素分析[J]. 物探与化探, 2023, 47(1): 120-128.
[15] 王志强, 杨建锋, 石天池. 宁夏石嘴山地区富硒土壤及其利用前景[J]. 物探与化探, 2023, 47(1): 228-237.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
京ICP备05055290号-3
版权所有 © 2021《物探与化探》编辑部
通讯地址:北京市学院路29号航遥中心 邮编:100083
电话:010-62060192;62060193 E-mail:whtbjb@sina.com , whtbjb@163.com