The Ximole area is located in the iron, gold, copper, titanium, cobalt, nickel prospective zone. In this area, secondary halos are well developed and have relatively high intensity. They are mainly distributed in migmatite strata of 2^nd member of Budaergan Formation in Neo-Archean Seertengshan rock group, Ordovician gabbro bodies, diabase veins and NE-trending faulted shatter zone, with the superimposition of aeromagnetic anomaly. An analysis of the geochemical parameters of elements and anomalies shows that Co, V and Ti exhibit logarithmic positive offset distribution with relatively high mean values and hence belong to elements of extremely uneven differentiation or uneven differentiation whose content values are close to indices of accompanying components of iron ores, indicating that they might have come from the same material source as Fe; therefore, these elements can be regarded as the main accompanying elements as well as the geochemical indicator elements. Secondary halo element association is fairly rich with good correlation, and exhibits characteristics of outer zone and middle zone. Rock geochemical profile verification of some secondary halos led to the discovery of Fe-Co mineralized body, Fe-V mineralized body and Fe-V-Co mineralized body, which are fairly large and are mainly distributed in gabbro intrusive body and NE-trending faulted shatter zone, and show direct correlation with lemonitization, magnetitization, pyritization and hematitization. Ximole area possesses fairly good ore-forming geological and geochemical environment and hence has favorable metallogenic potential for such ore deposits as Fe, Co, V and Ti.