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Geological characteristics and origin of the Mogou fluorite deposit in Fangcheng County, Henan Province |
ZHANG Qing-Song1,2(), XIA Ming-Zhe1(), WANG Chun-Lian3, LI Ke-Kun2, LIU Zeng-Zheng2, JIANG Ji-Yong2, JIANG Jian-Lang2 |
1. School of Earth Science and Recourses, Chang'an University, Xi'an 710054, China 2. Henan Geological Bureau of CCGMB, Zhengzhou 450000, China 3. MLR Key Laboratory of Metallogeny and Mineral Assessment, Institute of Mineral Resources, Chinese Academy of Geological Sciences, Beijing 100037, China |
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Abstract The Mogou fluorite deposit of Fangcheng County, residing in the Neoproterozoic Meiyaogou Formation, is a crucial part of the fluorite metallogenic belt in southern Henan Province. Based on the analysis of the geological characteristics of the Mogou fluorite deposit, this study conducted petrographic and petrogeochemical studies to define the source of ore-forming materials and probe into the genetic mechanism of the fluorite deposit. The results show that the fluorite ore body is veined or lenticular, with mineralization-related alterations composed of silicification, fluorite and sericite alterations. Its ore structures are primarily massive, followed by banded, striped, and brecciated types. The chondrite-normalized rare earth element distribution pattern of the fluorite ore body is similar to that of the Meiyaogou Formation marbles and the Yanshanian porphyritic plagiogranites, suggesting a genetic relationship. The possible genetic mechanism is that the F-enriched ore-bearing hydrothermal liquids intruded along the interbedded fault and reacted with the surrounding rocks to form the fluorite ore /mineralized body. The deposit belongs to the epithermal filling type along the interbedded structure.
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Received: 27 November 2022
Published: 26 February 2024
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Geology (a) and regional structure (b) of Mogou area,Fangcheng County, Henan Province
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Geological profile of exploration line 2 in Mogou fluorite mining area
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Fluorite ore and its microscopic characteristics in Mogou area, Fangcheng County a—filling fluorite ore along cracks; b—massive fluorite ore; c—purple fluorite and its deformation characteristics of surrounding rock;d—white banded fluorite and Molybdenite developed along fractures; e—striped fluorite in the borehole; f—banded fluorite, single polarized;g—banded fluorite deformation, orthogonal polarization;Fl—fluorite;Mot—molybdenite;Ms—muscovite;Cal—calcite;Phl—phlogopite;Qz—quartz
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| Hf | Ta | W | Pb | Bi | Th | U | Li | Be | XT1 | 0.06 | 0.07 | 0.14 | 1.65 | 0.01 | 0.13 | 0.1 | 3.11 | 0.22 | XT2 | 8.5 | 2.45 | 2.07 | 16.98 | 0.08 | 21.04 | 4.81 | 85.12 | 6.06 | XT3 | 0.16 | 0.09 | 0.3 | 2.04 | 0.03 | 0.34 | 1.15 | 7.83 | 0.5 | XT4 | 0.09 | 0.1 | 32.59 | 91.33 | 1.45 | 0.34 | 0.28 | 37.88 | 1.04 | | V | Cr | Co | Ni | Cu | Zn | Ga | Rb | Sr | XT1 | 2.09 | 2.1 | 2.93 | 10.29 | 2.65 | 2.46 | 0.89 | 1.55 | 242.78 | XT2 | 148.98 | 138.61 | 20.5 | 41.09 | 25.43 | 127.36 | 27.09 | 212.67 | 213.94 | XT3 | 2.29 | 3.34 | 3.19 | 10.4 | 3.12 | 3.76 | 1.31 | 3.67 | 82.8 | XT4 | 5.43 | 2.91 | 2.97 | 10.17 | 8.47 | 51.4 | 1.63 | 8.68 | 63.68 | | Zr | Nb | Mo | Cd | In | Sn | Sb | Cs | Ba | XT1 | 2.16 | 0.19 | 0.08 | 0.01 | 0 | 0.12 | 6.87 | 0.13 | 11.03 | XT2 | 297.37 | 33.65 | 7.89 | 0.37 | 0.13 | 4.73 | 3.68 | 19.35 | 820.13 | XT3 | 5.57 | 0.79 | 0.19 | 0.02 | 0.01 | 0.17 | 6.86 | 0.42 | 18.05 | XT4 | 2.31 | 0.5 | 5.23 | 0.66 | 0.01 | 0.23 | 6.7 | 1.69 | 11.3 |
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Results of trace element analysis of Mogou fluorite deposit,Fangcheng County 10-6
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17]) ">
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Spider map of trace elements of Mogou fluorite mine in Fangcheng County(standardized data by Sun et al.[17])
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岩矿石名称 | 萤石 | 萤石 | 萤石 | 萤石 | 萤石 | 萤石 | 萤石 | 大理岩 | 片岩 | 片岩 | 编号 | XT1 | XT2 | XT3 | XT4 | XT5 | XT6 | XT7 | XT8 | XT9 | XT10 | La | 5.87 | 64.08 | 11.85 | 9.24 | 8.45 | 7.4 | 6.52 | 3.85 | 10.8 | 18.41 | Ce | 10.20 | 135.69 | 21.48 | 18.03 | 16.6 | 14.9 | 13.7 | 7.31 | 17.9 | 37.91 | Pr | 1.12 | 15.34 | 2.15 | 2.24 | 2.11 | 1.78 | 1.7 | 0.79 | 3.33 | 4.57 | Nd | 3.87 | 58.51 | 6.91 | 8.93 | 7.89 | 6.86 | 6.62 | 2.96 | 15.4 | 18.07 | Sm | 1.20 | 11.61 | 1.53 | 2.61 | 1.9 | 1.57 | 1.57 | 0.66 | 4.15 | 3.90 | Eu | 0.42 | 2.65 | 0.41 | 0.96 | 0.54 | 0.4 | 0.42 | 0.23 | 1.58 | 1.17 | Gd | 1.58 | 11.51 | 2.05 | 3.71 | 2.2 | 1.86 | 1.88 | 0.81 | 4.37 | 4.56 | Tb | 0.29 | 1.53 | 0.38 | 0.68 | 0.4 | 0.31 | 0.34 | 0.13 | 0.68 | 0.61 | Dy | 1.92 | 8.31 | 2.72 | 4.62 | 2.09 | 1.8 | 1.77 | 0.72 | 3.7 | 3.51 | Ho | 0.41 | 1.53 | 0.64 | 0.98 | 0.46 | 0.36 | 0.37 | 0.15 | 0.7 | 0.67 | Er | 1.30 | 4.39 | 2.28 | 2.84 | 1.3 | 1.03 | 0.97 | 0.45 | 1.99 | 1.96 | Tm | 0.18 | 0.55 | 0.36 | 0.37 | 0.22 | 0.13 | 0.15 | 0.065 | 0.26 | 0.27 | Yb | 1.43 | 3.59 | 2.70 | 2.72 | 1.11 | 0.69 | 0.69 | 0.38 | 1.58 | 1.80 | Lu | 0.23 | 0.52 | 0.42 | 0.38 | 0.2 | 0.1 | 0.13 | 0.058 | 0.24 | 0.26 | Y | 24.67 | 40.40 | 46.65 | 53.54 | 17.1 | 16 | 15.1 | 5.23 | 17 | 18.95 | ΣREE | 30.02 | 319.81 | 55.90 | 58.29 | 45.47 | 39.19 | 36.83 | 18.56 | 66.68 | 97.68 | LREE | 22.68 | 287.89 | 44.33 | 42.01 | 37.49 | 32.91 | 30.53 | 15.80 | 53.16 | 84.03 | HREE | 7.35 | 31.92 | 11.57 | 16.28 | 7.98 | 6.28 | 6.30 | 2.76 | 13.52 | 13.65 | w(LREE)/w(HREE) | 3.09 | 9.02 | 3.83 | 2.58 | 4.70 | 5.24 | 4.85 | 5.72 | 3.93 | 6.16 | [w(La)/w(Yb)]N | 2.94 | 12.82 | 3.15 | 2.44 | 5.46 | 7.69 | 6.78 | 7.27 | 4.90 | 7.32 | δEu | 0.93 | 0.69 | 0.70 | 0.94 | 0.81 | 0.71 | 0.75 | 0.96 | 1.13 | 0.84 | δCe | 0.91 | 1.03 | 0.97 | 0.94 | 0.94 | 0.97 | 0.99 | 0.97 | 0.73 | 0.98 |
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Trace element analysis results and characteristic values of Mogou fluorite deposite,Fangcheng County 10-6
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17],XT11 is Yanshan period porphyry plagiogranite, data quoted from Henan Department of Geology and Mineral Resources [21]) ">
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Spider web of rare earth elements in fluorite deposits in Mogou area,Fangcheng County(standardized data by Sun et al[17],XT11 is Yanshan period porphyry plagiogranite, data quoted from Henan Department of Geology and Mineral Resources [21])
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[w(La)+w(Y)]-w(Y)/w(La) relation of fluorite mine in mogou area,Fangcheng County
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w(Y)/w(Ho)-w(La)/w(Ho) relation of fluorite mine in mogou area,Fangcheng County
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Metallogenic model of fluorite deposit in Mogou area, Fangcheng County
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