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Distribution characteristics and source analysis of heavy metals from dry and wet atmospheric deposition in northern Xiushan County, Chongqing |
CAI Ke-Ke1( ), ZHAO Zhi-Qiang1, MENG Li2,3, WANG Xiao-Meng1, LIU Jian1, LUO Ren-Feng1 |
1. Chongqing Geological and Mineral Resource Exploration and Development Bureau 607 Geological Team, Chongqing 400054, China 2. Chongqing Institute of Geology and Mineral Resources, Chongqing 401120, China 3. College of Environment and Ecology, Chongqing University, Chongqing 400044, China |
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Abstract This study aims to determine the contents of heavy metals from dry and wet atmospheric deposition in northern Xiushan County for targeted environmental pollution prevention and control and safe farmland soil utilization. Based on the dry and wet atmospheric deposition samples continuously received from 18 sampling sites in northern Xiushan County from November 2019 to November 2020, this study tested the contents of seven heavy metal elements, including Cd, Cr, Cu, Ni, Pb, Zn, and Hg. Considering the topographic features, this study analyzed the distribution patterns and sources of heavy metals from dry and wet atmospheric deposition in northern Xiushan County. Moreover, this study assessed the soil pollution caused by heavy metals from dry and wet atmospheric deposition using the geoaccumulation index method. The results show that except Hg, the other six heavy metal elements exhibited significant zoning, with their high-value deposition areas distributed primarily in the flanks and eastern segment of Chuanhegai, where their contents were much higher than the national and Chongqing's averages. In contrast, their depositional fluxes in other general deposition areas were less than the national averages by 25%. The high dry and wet atmospheric deposition in the flanks of Chuanhegai was subjected to both the mining of the lead-zinc deposit in Huayuan County in the east and the special topography. The abrupt topography increased the fluxes of the seven heavy metals in the dry and wet atmospheric deposition by 49 times. Therefore, the monitoring and assessment of environmental safety in this type of landform area should be strengthened. According to the assessment results of the geoaccumulation index method, the flanks of Chuanhegai were moderately-severely to extremely polluted by Cd, slightly-moderately polluted by Pb, and slightly-moderately to severely polluted by Zn.
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Received: 29 August 2022
Published: 26 February 2024
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Study area and distribution of atmospheric dust sampling sites
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Symbol diagram of heavy metal element deposition flux at various points Note:blue points are below 25% percentile;green points are in 25%~50% percentile;orange points are in 50%~75% percentile;rose points are in 75%~90% percentile;red points are above 90% percentile
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分区 | 样品编号 | Cd | Cr | Cu | Ni | Pb | Zn | Hg | 一般区 | JC01 | 0.077 | 0.935 | 1.150 | 0.550 | 2.014 | 4.765 | 0.155 | JC02 | 0.059 | 0.948 | 0.909 | 1.597 | 1.506 | 3.664 | 0.040 | JC03 | 0.042 | 1.067 | 1.091 | 1.179 | 1.528 | 4.723 | 0.129 | JC04 | 0.113 | 2.505 | 1.046 | 0.628 | 1.762 | 5.096 | 0.048 | JC05 | 0.058 | 0.679 | 0.617 | 0.441 | 1.459 | 3.689 | 0.042 | JC06 | 0.053 | 0.656 | 0.649 | 0.492 | 1.532 | 3.131 | 0.065 | JC07 | 0.120 | 0.766 | 1.053 | 0.433 | 2.432 | 5.658 | 0.059 | JC08 | 0.071 | 1.371 | 1.141 | 0.788 | 5.550 | 5.516 | 0.173 | JC09 | 0.061 | 1.353 | 1.024 | 1.653 | 1.695 | 3.753 | 0.083 | JC13 | 0.213 | 2.043 | 3.109 | 1.558 | 4.678 | 13.765 | 0.063 | JC14 | 0.138 | 0.784 | 1.209 | 0.459 | 2.853 | 6.769 | 0.162 | JC15 | 0.082 | 3.491 | 1.478 | 1.041 | 3.199 | 6.476 | 0.079 | JC18 | 0.115 | 0.837 | 1.065 | 0.341 | 3.393 | 4.935 | 0.102 | JC20 | 0.162 | 0.643 | 0.655 | 0.352 | 2.647 | 8.851 | 0.176 | 平均值 | 0.097 | 1.291 | 1.157 | 0.822 | 2.589 | 5.771 | 0.098 | 川河盖两翼沉 降量高值区 | JC10 | 2.500 | 40.500 | 17.200 | 14.500 | 65.400 | 108.000 | 0.138 | JC11 | 76.100 | 388.800 | 298.400 | 237.900 | 1395.600 | 3482.200 | 0.146 | JC16 | 0.737 | 9.689 | 8.284 | 5.076 | 21.439 | 66.948 | 0.101 | JC17 | 1.250 | 3.530 | 3.542 | 1.621 | 15.753 | 93.506 | 0.078 | 平均值 | 20.981 | 117.633 | 85.052 | 64.271 | 376.904 | 960.891 | 0.097 | 全区 | 最大值 | 76.100 | 388.8 | 298.400 | 237.900 | 1395.6 | 3482.2 | 0.176 | 最小值 | 0.042 | 0.643 | 0.617 | 0.341 | 1.459 | 3.131 | 0.024 | 平均值 | 4.554 | 25.585 | 19.087 | 15.032 | 85.246 | 212.859 | 0.102 | 标准差 | 17.31 | 88.54 | 67.85 | 54.14 | 318.15 | 793.58 | 0.05 | 变异系数 | 3.81 | 3.46 | 3.55 | 3.60 | 3.73 | 3.73 | 0.45 | 全国[19] | 平均值 | 0.71 | 18.21 | 15.55 | 7.57 | 36.72 | 147.85 | 0.07 | 重庆主城区降水[20] | 平均值 | 0.44 | 2.9 | 13 | 2.22 | 30.25 | 76.26 | |
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Flux of heavy metals in atmospheric dry and wet deposition mg·(m2·a)-1
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样品编号 | Cd | Cr | Cu | Hg | Ni | Pb | Zn | | 样品编号 | Cd | Cr | Cu | Hg | Ni | Pb | Zn | JC01 | 0.20 | 68.0 | 27.8 | 0.08 | 34.4 | 32.6 | 84.1 | | JC13 | 0.40 | 81.2 | 32.4 | 0.24 | 33.6 | 33.9 | 99.1 | JC02 | 0.21 | 71.1 | 28.5 | 0.06 | 34.4 | 32.1 | 89.5 | | JC14 | 0.34 | 72.9 | 28.3 | 0.57 | 34.5 | 42.8 | 95.1 | JC03 | 0.19 | 68.6 | 25.3 | 0.07 | 33.0 | 29.8 | 86.4 | | JC15 | 0.36 | 86.7 | 26.0 | 0.21 | 33.5 | 40.7 | 95.8 | JC04 | 0.16 | 59.2 | 19.0 | 0.07 | 25.8 | 26.3 | 69.5 | | JC18 | 0.43 | 77.9 | 29.2 | 0.55 | 32.9 | 39.9 | 102.6 | JC05 | 0.33 | 82.3 | 29.5 | 0.17 | 34.1 | 46.9 | 88.6 | | JC20 | 0.39 | 77.6 | 32.6 | 0.17 | 39.0 | 44.0 | 104.0 | JC06 | 0.46 | 69.5 | 27.0 | 0.30 | 30.2 | 47.6 | 90.2 | | JC10 | 0.28 | 75.2 | 28.2 | 0.09 | 34.2 | 33.7 | 85.9 | JC07 | 0.94 | 98.1 | 50.2 | 1.46 | 49.9 | 29.1 | 122.2 | | JC11 | 0.32 | 74.0 | 47.7 | 0.07 | 34.5 | 35.7 | 87.9 | JC08 | 0.26 | 76.1 | 28.6 | 0.35 | 35.5 | 31.1 | 84.3 | | JC16 | 0.33 | 74.5 | 46.7 | 0.07 | 39.3 | 34.9 | 89.8 | JC09 | 0.39 | 83.0 | 26.8 | 0.23 | 32.9 | 46.0 | 94.9 | | JC17 | 0.53 | 71.4 | 32.1 | 0.22 | 34.4 | 48.8 | 94.2 |
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The content of heavy metal elements in the soil around the atmospheric dry and wet deposition sample site 10-6
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样品编号 | 占比/% | Cd | Cr | Cu | Ni | Pb | Zn | Hg | JC10 | 1.01 | 16.30 | 6.93 | 5.84 | 26.35 | 43.51 | 0.06 | JC11 | 1.29 | 6.61 | 5.08 | 4.05 | 23.74 | 59.23 | <0.01 | JC16 | 0.66 | 8.63 | 7.38 | 4.52 | 19.09 | 59.63 | 0.09 | JC17 | 1.05 | 2.96 | 2.97 | 1.36 | 13.21 | 78.39 | 0.07 | 川河盖顶土壤 | 0.26 | 30.73 | 9.91 | 12.77 | 12.37 | 33.90 | 0.06 |
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Proportion comparison of heavy metals between JC10、JC11、JC16、JC17 and soil of Chuanhegai
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Section of atmospheric dry and wet deposition points
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项目 | 地累积指数 | Cd | Cr | Cu | Hg | Ni | Pb | Zn | JC10 | 3.6 | -0.2 | -0.1 | 0.7 | -0.6 | 1.5 | 0.9 | JC11 | 4.6 | -0.8 | 0.2 | -3.1 | -0.4 | 2.0 | 2.0 | JC16 | 2.5 | -1.6 | -0.4 | 1.0 | -1.4 | 0.6 | 0.9 | JC17 | 4.2 | -2.1 | -0.7 | 1.5 | -2.1 | 1.1 | 2.3 |
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Geoaccumulation index of atmospheric dry and wet deposition in two wings of Chuanhegai
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Surface soil and crop sample points around JC11 within 1 km
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