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Rock geochemical characteristics and genesis of the Xihuang vanadium deposit in Henan Province |
WANG Xiao-Gao1,2( ), WANG Ying-Chao1, CHENG Bao-Cheng1, YANG Yong-Qian1, WANG Jie1( ), CHEN Peng1 |
1.Henan Institute of Non-ferrous Metal Exploration,Zhengzhou 450052, China 2.Key Laboratory of Deep Ore-prospecting Technology Research for Non-ferrous Metals of Henan Province, Zhengzhou 450052, China |
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Abstract The Xihuang vanadium deposit is located in the black rock series of the lower Cambrian Shuigoukou Formation in southern Qinling Mountain. The orebody is large, and the ore-bearing horizon and grade are relatively stable. The ore types are mainly carbonaceous mudstone and siliceous mudstone. The analysis of petro-geochemical elements and REE indicates that the vanadium deposit was formed in the hypoxic reductive environment from the continental margin to the deep sea, and the rock material source came from sea water, hydrothermal jet and terrigenous debris, with the biological activity playing an important role in the aggregation and precipitation of the vanadium deposit. Based on the comprehensive geological and geochemical characteristics, it is concluded that the vanadium deposit belongs to the biogenesis of hot water deposition, and that the vanadium deposit should be of biological and hydrothermal sedimentary origin.
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Received: 04 March 2019
Published: 26 October 2020
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Corresponding Authors:
WANG Jie
E-mail: 43571649@qq.com;404817633@qq.com
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The regional geologic structure(revised according to reference[10])
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Geological sketch of the Xihuang vanadium deposit 1—Quaternary; 2—Ordovician second section in Bailongmiao formation; 3—Ordovician first section in Bailongmiao formation; 4—Cambrian Wugongya formation; 5—Cambrian second section in Yuejiaping formation; 6—Cambrian first section in Yuejiaping formation; 7—Cambrian Shuigoukou formation; 8—Sinian third section in Dengying formation; 9—Sinian second section in Dengying formation 2; 10—Sinian first section in Dengying formation; 11—Sinian Doushantuo formation; 12—upper rock formation of Mesoproterozoic Wudang group; 13—Sinian Fengzishan granodiorite; 14—diabase vein; 15—fault and its number; 16—ore body and number
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地层 | 地层符号 | 出露地段 | 岩性特征 | 中—新元古界武当岩群 | Pt2-3w | 朱家扒—后湾—马湾一带 | 主要岩性为变流纹岩、变流纹质凝灰岩、变流纹质角砾岩,夹薄层变质砂岩,为一套中酸性喷发沉积建造夹陆源碎屑建造 | 震旦系陡山沱组 | Z2d | 中部、东部的范河—张南沟—东沟一带 | 岩性为土黄色中厚层铁质砂岩、砂质白云岩、泥岩,灰白色厚层隐晶白云岩,为一套浅海斜坡相沉积建造 | 震旦系灯影组 | Z2dn | 鸡冠土地—狮子沟—张南沟一带 | 下部岩性为角砾状白云岩,中部为白云岩,上部为硅质网格状白云岩,顶部为钙质白云岩夹黏土质磷块岩及钙质白云岩,具有海侵到海退的沉积旋回特征 | 寒武系水沟口组 | ∈1s | 大寺—狮子沟—张南沟—李家湾一带 | 由下至上为灰黑色薄层状硅质岩、杂色黏土岩、紫红色页岩和鲕状钙质磷块岩,该组是磷、钒矿的含矿岩系,硅质岩、黏土岩为含矿层,硅质岩中局部夹透镜状灰岩,并常含磷质结核,紫红色页岩底部也常含磷质结核,局部相变为泥灰岩,鲕状钙质磷块岩为磷矿层 | 寒武系岳家坪组 | ∈2y | 平行于水沟口组分布 | 下段为灰白色厚层—中厚层微晶—中细晶白云岩,上段为灰色厚层微晶白云岩、土黄色厚层白云岩、灰色微晶灰岩、紫红色厚层—巨厚层泥岩 | 寒武系蜈蚣丫组 | ∈3w | 大寺—狮子沟—张南沟—李家湾一带 | 灰色厚层藻纹白云岩、灰白色微晶白云岩、土黄色中厚层泥质白云岩 | 奥陶系白龙庙组 | O1b | 大寺沟—三岔沟脑—母猪沟—张南沟—王家庄一带 | 下段为灰白色中厚层微细晶白云岩夹灰黑色中厚层中细晶白云岩,上段为灰黑色厚层中细晶白云岩夹薄层泥岩 |
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Lithological feature of strata exposed in Xihuang district
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The photograph of clay rocks(a) and siliceous rocks(b) under the microscope
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样号 | 岩石类型 | V2O5 | SiO2 | Al2O3 | Fe2O3 | TiO2 | K2O | Na2O | CaO | MgO | MnO | P2O5 | H1 | 含硅质泥岩 | 0.82 | 73.18 | 8.75 | 4.19 | 0.22 | 1.21 | 0.04 | 1.36 | 0.61 | 0.01 | 1.26 | H2 | 含硅质泥岩 | 0.61 | 68.53 | 2.79 | 1.95 | 0.05 | 0.66 | 0.05 | 5.44 | 0.36 | 0.03 | 0.65 | H3 | 炭质泥岩 | 0.91 | 59.4 | 7.99 | 4.40 | 0.18 | 0.43 | 0.05 | 1.25 | 0.59 | 0.01 | 0.47 | H4 | 炭质泥岩 | 0.62 | 59.33 | 8.08 | 3.85 | 0.17 | 0.57 | 0.06 | 0.72 | 0.38 | 0.01 | 0.27 | H5 | 炭质泥岩 | 1.14 | 52.26 | 7.43 | 5.15 | 0.12 | 0.44 | 0.14 | 2.59 | 1.58 | 0.01 | 0.15 | H6 | 炭质泥岩 | 1.46 | 62.87 | 7.48 | 4.25 | 0.20 | 0.85 | 0.05 | 1.10 | 0.39 | 0.03 | 0.52 | H7 | 炭质泥岩 | 1.18 | 62.89 | 8.64 | 2.88 | 0.16 | 2.65 | 0.07 | 0.43 | 0.55 | 0.01 | 0.41 | H8 | 炭质泥岩 | 0.80 | 57.48 | 11.71 | 5.11 | 0.35 | 1.30 | 0.08 | 1.06 | 0.62 | 0.01 | 0.39 | H9 | 炭质泥岩 | 1.08 | 62.71 | 4.55 | 3.95 | 0.14 | 1.03 | 0.07 | 4.53 | 0.42 | 0.01 | 3.00 | H10 | 炭质泥岩 | 1.17 | 59.18 | 7.32 | 4.33 | 0.17 | 3.28 | 0.06 | 0.53 | 0.88 | 0.01 | 0.22 | 样号 | 岩石类型 | BaO | Loss | r1 | r2 | r3 | r4 | r5 | H1 | 含硅质泥岩 | 2.15 | 5.19 | 8.36 | 0.61 | 0.82 | 0.68 | 0.05 | H2 | 含硅质泥岩 | 3.90 | 11.47 | 24.56 | 0.52 | 0.92 | 0.59 | 0.60 | H3 | 炭质泥岩 | 2.20 | 22.11 | 7.43 | 0.58 | 0.79 | 0.64 | 0.06 | H4 | 炭质泥岩 | 1.98 | 23.69 | 7.34 | 0.61 | 0.80 | 0.68 | 0.06 | H5 | 炭质泥岩 | 2.78 | 23.68 | 7.03 | 0.52 | 0.76 | 0.59 | 0.08 | H6 | 炭质泥岩 | 0.46 | 18.76 | 8.41 | 0.57 | 0.81 | 0.64 | 0.15 | H7 | 炭质泥岩 | 4.22 | 8.63 | 7.28 | 0.69 | 0.82 | 0.75 | 0.06 | H8 | 炭质泥岩 | 1.36 | 18.06 | 4.91 | 0.63 | 0.73 | 0.70 | 0.03 | H9 | 炭质泥岩 | 2.41 | 16.16 | 13.78 | 0.46 | 0.85 | 0.54 | 0.07 | H10 | 炭质泥岩 | 4.49 | 18.35 | 8.08 | 0.56 | 0.80 | 0.63 | 0.06 |
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Petrochemical analysis and related parameters of Xihuang vanadium deposit
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样品名称 | H1 | H2 | H3 | H4 | H5 | H6 | H7 | H8 | H9 | H10 | 北美 页岩[23] | 球粒 陨石[24] | La | 14.41 | 11.33 | 56.45 | 41.58 | 49.99 | 60.62 | 34.3 | 48.1 | 32.43 | 45.41 | 32 | 0.31 | Ce | 19.52 | 11.69 | 45.09 | 54.48 | 50.3 | 50.34 | 42.63 | 55.13 | 38.26 | 57.92 | 73 | 0.808 | Pr | 2.70 | 3.17 | 12.63 | 7.99 | 11.36 | 13.74 | 9.26 | 10.74 | 7.19 | 9.99 | 7.9 | 0.122 | Nd | 10.01 | 16.02 | 60.62 | 30.37 | 52.25 | 64.19 | 41.32 | 44.89 | 32.63 | 42.54 | 33 | 0.6 | Sm | 1.86 | 4.32 | 13.05 | 5.78 | 10.62 | 13.8 | 8.91 | 8.91 | 6.95 | 8.33 | 5.7 | 0.195 | Eu | 8.82 | 7.24 | 8.53 | 19.88 | 10.15 | 11.24 | 4.98 | 9.36 | 10.61 | 8.7 | 1.24 | 0.0735 | Gd | 1.69 | 4.22 | 12.94 | 5.68 | 10.06 | 13.7 | 8.87 | 8.87 | 6.67 | 8.45 | 5.2 | 0.259 | Tb | 0.25 | 1.01 | 2.70 | 0.84 | 1.98 | 2.87 | 1.85 | 1.63 | 1.38 | 1.52 | 0.85 | 0.047 | Dy | 1.68 | 8.18 | 19.96 | 5.27 | 13.63 | 20.68 | 13.33 | 11.26 | 10.14 | 10.19 | 5.8 | 0.322 | Ho | 0.34 | 1.96 | 4.64 | 1.14 | 3.18 | 4.92 | 3.03 | 2.6 | 2.45 | 2.32 | 1.04 | 0.0718 | Er | 1.11 | 6.32 | 14.3 | 3.66 | 9.75 | 15.15 | 9.3 | 8.35 | 7.72 | 7 | 3.4 | 0.21 | Tm | 0.17 | 0.96 | 2.12 | 0.51 | 1.43 | 2.24 | 1.37 | 1.24 | 1.17 | 0.98 | 0.5 | 0.0324 | Yb | 1.29 | 5.99 | 12.41 | 3.27 | 8.55 | 13.32 | 8.28 | 7.69 | 7.17 | 5.87 | 3.1 | 0.209 | Lu | 0.18 | 1.01 | 2.05 | 0.51 | 1.39 | 2.23 | 1.36 | 1.29 | 1.18 | 0.93 | 0.48 | 0.0322 | REE | 64.03 | 83.42 | 267.49 | 180.96 | 234.64 | 289.04 | 188.79 | 220.06 | 165.95 | 210.15 | 173.21 | 3.29 | LREE | 57.32 | 53.77 | 196.37 | 160.08 | 184.67 | 213.93 | 141.40 | 177.13 | 128.07 | 172.89 | 152.84 | 2.11 | HREE | 6.71 | 29.65 | 71.12 | 20.88 | 49.97 | 75.11 | 47.39 | 42.93 | 37.88 | 37.26 | 20.37 | 1.18 | wLREE/wHREE | 8.54 | 1.81 | 2.76 | 7.67 | 3.70 | 2.85 | 2.98 | 4.13 | 3.38 | 4.64 | 7.50 | 1.78 | [w(La)/w(Sm)]N | 4.87 | 1.65 | 2.72 | 4.53 | 2.96 | 2.76 | 2.42 | 3.40 | 2.94 | 3.43 | 3.53 | | [w(Ce)/w(Yb)]N | 3.91 | 0.50 | 0.94 | 4.31 | 1.52 | 0.98 | 1.33 | 1.85 | 1.38 | 2.55 | 6.09 | | [w(Gd)/w(Yb)]N | 1.06 | 0.57 | 0.84 | 1.40 | 0.95 | 0.83 | 0.86 | 0.93 | 0.75 | 1.16 | 1.35 | | δEuN | 15.21 | 5.18 | 2.01 | 10.61 | 3.00 | 2.50 | 1.71 | 3.22 | 4.76 | 3.17 | 0.70 | | δCeN | 0.75 | 0.47 | 0.41 | 0.72 | 0.51 | 0.42 | 0.58 | 0.58 | 0.60 | 0.65 | 1.11 | |
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REE analyses and relavent parameters in Xihuang area
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24]) ">
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REE distribution patterns of ores in Xihuangvandium deposit(modified from Sun et al[24])
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26]) ">
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w(La)/w(Yb)-w(REE) diagram for the Xihuang formation black rock series (modified from Allegre et al[26])
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The genetic model of vanadium deposit
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