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Accessing the distribution and ecological risks of heavy metals in soil in Hong’an County, Hubei Province through ecological geological surveys |
JU Zi-Long( ), QIN Zhi-Jun, Wan Xiang( ), YUAN Hang, ZHANG Xiao-Bo, WANG Deng |
Hubei Geological Survey, Wuhan 430034, China |
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Abstract This study selected the Jinsha Lake and the Miersi Industry Park as key survey areas to study the distribution of heavy metals in soil in Hong’an County, Hubei Province. Samples were collected from surface soil and vertical soil profiles to assay the contents of eight heavy metals, i.e., Cu, Pb, Zn, Cr, Ni, Cd, As, and Hg. Both the single factor pollution index method and the potential ecological hazard index method were used to assess the distribution and the ecological risk of heavy metals. The study results are as follows:The average contents of the above eight heavy metals were 21.48×10-6, 21.75×10-6, 63.60×10-6, 53.24×10-6, 20.25×10-6, 0.13×10-6, 5.44×10-6, and 0.04×10-6,respectively. The cumulative Cu, Cr, Ni, and Cd are relatively enriched in the soil and their pollution is slight. The heavy metals show distinct distribution patterns. Minor pollution exists in the Gaoqiao-Yongjiahe basic-ultrabasic melange zone and around the Miershi Industrial Park, while severe pollution exists in Mn-Co mineralized points scattered in the northeastern Baliwan. Pb and Hg are enriched in the surface layer but decrease in the deep layer, Cr and Ni show an inverse trend, while other elements show indistinct distribution patterns. Cd and Hg have high potential ecological risk individually in the soil in the surveyed areas. The comprehensive ecological risk assessment based on Cd and Hg shows that the surrounding area of the Jinsha Lake Chengguan Town, the basic-ultrabasic melange zone, the surrounding area of the Miersi Industrial Park, and the Baliwan manganese-cobalt mineralization zone are areas with moderate potential ecological risks, where ecological supervision and protection should be strengthened. This study can provide a scientific basis for later ecological management in Hongan. It also serves as a good soil reference for other ecological geological surveys.
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Received: 16 July 2021
Published: 17 August 2022
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Corresponding Authors:
Wan Xiang
E-mail: zilongcug@163.com;wxzgdz@hotmail.com
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Overview of study area and the distribution of sampling points
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元素 | 土地 类型 | 土壤环境质量标准(GB 15168—2018) | 湖北省 背景 值[21,25] | pH≤5.5 | 5.5<pH ≤6.5 | 6.5<pH ≤7.5 | pH>7.5 | Cu | 其他 | 50 | 60 | 100 | 100 | 30.7 | 果园 | 150 | 150 | 200 | 200 | Pb | 其他 | 70 | 90 | 120 | 170 | 26.7 | 水田 | 80 | 100 | 140 | 240 | Zn | 所有 | 200 | 200 | 250 | 300 | 83.6 | Cr | 其他 | 150 | 150 | 200 | 250 | 86 | 水田 | 250 | 250 | 300 | 350 | Ni | 所有 | 60 | 70 | 100 | 190 | 26.9 | Cd | 其他 | 0.3 | 0.3 | 0.3 | 0.6 | 0.17 | 水田 | 0.3 | 0.4 | 0.6 | 0.8 | As | 其他 | 40 | 40 | 30 | 25 | 12.3 | 水田 | 30 | 30 | 25 | 20 | Hg | 其他 | 1.3 | 1.8 | 2.4 | 3.4 | 0.08 | 水田 | 0.5 | 0.5 | 0.6 | 1 |
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Reference value of heavy metal contents in single factor index method10-6
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Statistics for soil heavy metal contents in the study area
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重金属 | 以湖北省土壤背景值为参考 | 以GB15618—2018为参考 | 超标个数 | 超标率 | 单因子污染指数 最小值~最大值(平均值) | 超标个数 | 超标率 | 单因子污染指数 最小值~最大值(平均值) | Cu | 107 | 14.59% | 1~5.21/(1.37) | 10 | 1.48% | 1.07~3.2/(1.43) | Pb | 79 | 10.81% | 1~8.31/(1.26) | 1 | 0.14% | 3.1 | Zn | 170 | 23.11% | 1~13.77/(1.28) | 1 | 0.27% | 1.41~5.75/(3.58) | Cr | 88 | 11.89% | 1~2.95/(1.47) | 19 | 2.57% | 1~1.69/(1.26) | Ni | 158 | 21.49% | 1~9.03/(1.6) | 15 | 2.16% | 1.04~4.05/(1.42) | Cd | 107 | 14.59% | 1~191.17/(2.75) | 14 | 2.03% | 1~9.33/(8.66) | As | 32 | 4.46% | 1~6.17/(1.63) | 1 | 0.27% | 1.02~1.9/(1.46) | Hg | 65 | 8.78% | 1~7.68/(1.57) | 0 | 0 | |
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Statistics of heavy metals exceeding the standard in the survey area
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Pollution assessment of heavy metal content exceeding standard in study area
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Distribution of heavy meatal pollution assessment and samples exceeding standard in Jinshahu investigation area
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Distribution of heavy meatal pollution assessment and samples exceeding standard in Miersi investigation area
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项目 | Cu | Pb | Zn | Cr | Ni | Cd | As | Hg | 最小值/10-6 | 9.35 | 8.27 | 41.70 | 7.25 | 4.48 | 0.03 | 2.26 | 0.004 | 最大值/10-6 | 90.40 | 52.80 | 234.00 | 122.00 | 69.60 | 0.71 | 43.30 | 0.13 | 平均值/10-6 | 32.87 | 22.73 | 97.58 | 53.82 | 27.07 | 0.22 | 13.46 | 0.04 | 变异系数/% | 81.27 | 48.10 | 61.91 | 60.41 | 73.11 | 101.51 | 78.07 | 78.43 | 湖北省背景值/10-6 | 30.70 | 26.70 | 83.60 | 86.00 | 26.90 | 0.17 | 12.30 | 0.08 | 背景值倍数 | 1.07 | 0.85 | 1.17 | 0.63 | 1.01 | 1.32 | 1.09 | 0.50 |
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Statistics of soil heavy metal content in vertical profile
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Soil profiles for heavy metal contents
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Principal components analysis for soil heavy metal content in study area
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单项生态风险因子(Ei) | 综合生态风险指数(RI) | 等级 | 得分 | 等级 | 得分 | 低生态风险 | <40 | 低生态风险 | <150 | 中等生态风险 | 40~80 | 中等生态风险 | 150~300 | 较高生态风险 | 80~160 | 较高生态风险 | 300~600 | 高生态风险 | >160 | 高生态风险 | >600 |
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Evaluation criteria of potential ecological hazard derived from heavy metal
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Ecological risk distribution in the study area
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