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Prediction of the soil element accumulation trends based on 1∶250 000 and 1∶50 000 geochemical surveys and assessments of land quality:A case study of Xixiangtang District, Nanning City, Guangxi zhuang Autonomous Region |
WANG Lei1,2( ), ZHUO Xiao-Xiong1,2, WU Tian-Sheng2, LING Sheng-Hua3, ZHONG Xiao-Yu2, ZHAO Xiao-Meng1,4 |
1. Project Office of Land Quality Geochemical Assessment of Guangxi, Nanning 530023, China 2. Guangxi Institute of Geological Survey, Nanning 530023, China 3. No. 307 Nuclear Geological Team of Guangxi Zhuang Autonomous Region, Guigang 537100, China 4. No. 272 Gedogical Team of Guangxi Zhuang Autonomous Region, Nanning 530033, China |
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Abstract The heavy metal element contents in soil affect the quality of soil environment. Their prediction using different models based on survey data is an important means to study the changing trends of soil element contents and soil environmental quality. Based on the data from 1∶250 000 multi-purpose regional geochemical surveys and 1∶50 000 land quality geochemical assessments, this study predicted the contents of five heavy metal elements in the soil of the study area in 2027 using the single-period incremental model and the input-output flux model individually. The results are as follows. The two models yielded different prediction results but consistent trends that the contents of five heavy metal elements increased to different degrees. Moreover, the single-period incremental model yielded larger increments than the input-output flux model. Among the various input channels of the flux model, Cd and Pb entered the soil mainly through dry and wet atmospheric subsidence, As and Cr entered the soil mainly through fertilization, and Hg entered the soil mainly through irrigation water. Based on the survey and prediction data of soil monitoring sites, the soil environmental quality grade was classified for these sites. The proportion of the sites for priority protection showed a downward trend, indicating that the soil environmental quality decreased year by year.
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Received: 15 November 2021
Published: 24 February 2023
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分析 指标 | 要求检 出限 | 1∶25万多目标区域 地球化学调查 | 1∶5万土地质量 地球化学评价 | 分析方法 | 实际检出限 | 分析方法 | 实际检出限 | As | 1.0 | AFS | 0.2 | AFS | 0.2 | Cd | 0.03 | GFAAS | 0.02 | ICP-MS | 0.02 | Cr | 5 | XRF | 3 | XRF | 2 | Hg | 0.0005 | AFS | 0.0004 | AFS | 0.0002 | Pb | 2.0 | XRF | 1.5 | XRF | 1.0 | pH | 0.10 | ISE | 0.08 | ISE | 0.01 |
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Analysis method and detection limit of topsoil survey samples
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指标 | 1∶25万多目标区域地球化学调查 | 1∶5万土地质量地球化学评价 | 准确度 | 精密度 | 合格率 | 准确度 | 精密度 | 合格率 | 最小值 | 最大值 | 最小值 | 最大值 | | 最小值 | 最大值 | 最小值 | 最大值 | | As | -0.013 | 0.023 | 0.007 | 0.042 | 100% | -0.061 | 0.086 | 0.002 | 0.061 | 100% | Cd | -0.045 | 0.050 | 0.010 | 0.076 | 100% | -0.096 | 0.090 | 0.003 | 0.080 | 100% | Cr | -0.014 | 0.014 | 0.002 | 0.037 | 100% | -0.062 | 0.069 | 0.010 | 0.048 | 100% | Hg | -0.008 | 0.040 | 0.006 | 0.046 | 100% | -0.100 | 0.098 | 0.007 | 0.072 | 100% | Pb | -0.015 | 0.021 | 0.007 | 0.043 | 100% | -0.097 | 0.085 | 0.009 | 0.069 | 100% | pH | | | 0.01 | 0.10 | 100% | | | 0.01 | 0.07 | 100% |
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Accuracy and precision of first grade standard materials in topsoil survey samples
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指标 | 1∶25万多目标 区域地球化学调查 | 1∶5万土地 质量地球化学评价 | As | 93.33% | 97.42% | Cd | 86.67% | 92.90% | Cr | 98.67% | 100.00% | Hg | 86.67% | 94.84% | Pb | 98.67% | 98.06% | pH | 100.00% | 100.00% |
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Qualification rate of duplicate topsoil survey samples
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Survey point map of the study area
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数据集 | 数据量 | w(As)/10-6 | w(Cd)/10-6 | w(Cr)/10-6 | w(Hg)/10-6 | w(Pb)/10-6 | pH | WA | 189 | 32.71 | 0.448 | 111.50 | 0.194 | 35.18 | 5.97 | WB1(全区平均) | 6524 | 37.68 | 0.439 | 154.49 | 0.222 | 37.49 | 5.73 | WB2(调查配对点1km2) | 697 | 37.51 | 0.467 | 156.89 | 0.221 | 38.27 | 5.81 | WB3(分析配对点4km2) | 189 | 36.47 | 0.456 | 154.31 | 0.218 | 37.78 | 5.82 |
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Arithmetic mean value of element content and pH in topsoil survey samples
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元素 类别 | 样本 数量 | 相关性分析 | t检验 | 相关系数 | Sig. | t | Sig.(双侧) | As(WB3)-As(WA) | 189 | 0.91** | 0 | 4.86 | 0 | Cd(WB3)-Cd(WA) | 189 | 0.91** | 0 | 0.38 | 0.70 | Cr(WB3)-Cr(WA) | 189 | 0.92** | 0 | 13.90 | 0 | Hg(WB3)-Hg(WA) | 189 | 0.90** | 0 | 4.74 | 0 | Pb(WB3)-Pb(WA) | 189 | 0.96** | 0 | 6.67 | 0 | pH(WB3)-pH(WA) | 189 | 0.66** | 0 | -2.81 | 0.01 |
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Correlation and t-test of element contents and pH in WB3 and WA
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Element contents and pH distribution of WB3 and WA
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端元 | As | Cd | Cr | Hg | Pb | 大气 | 0.722 | 0.081 | 0.986 | 0.009 | 1.668 |
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Average input fluxes of heavy metals from dry and wet atmospheric deposition in Xixiangtang District in 2017 kg/(km2·a)
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端元 | As | Cd | Cr | Hg | Pb | 灌溉水 | 0.812 | 0.012 | 0.773 | 0.010 | 0.012 |
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Average input fluxes of heavy metals from irrigation water in Xixiangtang District in 2017kg/(km2·a)
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端元 | As | Cd | Cr | Hg | Pb | 化肥 | 0.373 | 0.011 | 0.393 | 0.0003 | 0.185 |
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Average input fluxes of heavy metals from fertilizer in Xixiangtang District in 2017kg/(km2·a)
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端元 | As | Cd | Cr | Hg | Pb | 农作物 | 花生 | 0.096 | 0.387 | 0.218 | 0.006 | 0.146 | 蔬菜瓜类 | 0.008 | 0.014 | 0.016 | 0.000 | 0.012 | 水稻籽实 | 0.356 | 0.088 | 0.240 | 0.009 | 0.083 | 香蕉 | 0.017 | 0.004 | 0.050 | 0.001 | 0.034 | 玉米 | 0.050 | 0.021 | 0.201 | 0.001 | 0.142 | 按种植面积 加权平均 | 0.030 | 0.015 | 0.051 | 0.001 | 0.032 |
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Average output fluxes of heavy metals from crops in Xixiangtang District in 2017 kg/(km2·a)
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端元 | As | Cd | Cr | Hg | Pb | 灌溉排水 | 0.450 | 0.006 | 0.428 | 0.005 | 0.006 |
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Average output fluxes of heavy metals from irrigation and drainage in Xixiangtang District in 2017kg/(km2·a)
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指数 | 污染物 | 分级类型 | Pi=实测值/风险筛选值 Pj=实测值/风险管控值 | i=As、Cd、Cr、Cu、Hg、Pb、Ni、Zn; j =As、Cd、Cr、Hg、Pb | pi≤1 优先保护 | pi>1,pj≤1 安全利用 | pj>1 严格管控 |
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Grade classification of soil environmental quality of agricultural land
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指标 | w(As) | w(Cd) | w(Cr) | w(Hg) | w(Pb) | pH | 10-6 | 10-6 | 10-6 | 10-6 | 10-6 | 含量 | 40.23 | 0.465 | 197.12 | 0.243 | 40.38 | 5.67 |
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Prediction of soil heavy metal contents in 2027 by single-period incremental model
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净输入通量 | As | Cd | Cr | Hg | Pb | W | 2.466 | 0.115 | 2.769 | 0.014 | 2.342 |
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Flux model annual net input flux of heavy metals into soilkg/(km2·a)
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指标 | w(As) | w(Cd) | w(Cr) | w(Hg) | w(Pb) | pH | 10-6 | 10-6 | 10-6 | 10-6 | 10-6 | 含量 | 36.58 | 0.461 | 154.43 | 0.219 | 37.88 | 5.67 |
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Prediction of soil heavy metal contents in 2027 by flux model
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Contribution ratio of different input paths to input and output fluxes of each element
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评价类别 | 评价对象 | As | Cd | Cr | Hg | Pb | 综合分级 | 优先保护 | 2007年(1∶25万) | 126 | 133 | 152 | 189 | 186 | 99 | 2017年(1∶5万) | 118 | 121 | 103 | 188 | 185 | 75 | 2027年(通量模型) | 115 | 121 | 106 | 188 | 181 | 70 | 2027年(单时段增量) | 107 | 113 | 89 | 187 | 177 | 56 | 安全利用 | 2007年(1∶25万) | 63 | 56 | 37 | 0 | 3 | 90 | 2017年(1∶5万) | 71 | 68 | 86 | 1 | 4 | 114 | 2027年(通量模型) | 73 | 68 | 83 | 1 | 8 | 118 | 2027年(单时段增量) | 81 | 76 | 100 | 2 | 12 | 132 | 严格管控 | 2007年(1∶25万) | 0 | 0 | 0 | 0 | 0 | 0 | 2017年(1∶5万) | 0 | 0 | 0 | 0 | 0 | 0 | 2027年(通量模型) | 1 | 0 | 0 | 0 | 0 | 1 | 2027年(单时段增量) | 1 | 0 | 0 | 0 | 0 | 1 | 优先保护点位占比 | 2007年(1∶25万) | 66.67% | 70.37% | 80.42% | 100.00% | 98.41% | 52.38% | 2017年(1∶5万) | 62.43% | 64.02% | 54.50% | 99.47% | 97.88% | 39.68% | 2027年(通量模型) | 60.85% | 64.02% | 56.08% | 99.47% | 95.77% | 37.04% | 2027年(单时段增量) | 56.61% | 59.79% | 47.09% | 98.94% | 93.65% | 29.63% |
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Grade statistical of soil environmental quality at point (n=189)
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Comprehensive grade map of soil environmental quality a—2007 survey data;b—2017 survey data;c—2027 flux model forecast data;d—2027 single-period incremental model forecast data
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