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Eco-geochemical survey and evaluation of heavy metals and other elements in soil in Anning City, Yunnan Province |
FAN Chen-Zi1,2( ), YUAN Ji-Hai1,2, LIU Cheng-Hai1,2, GUO Wei1,2, SUN Dong-Yang1,2, LIU Wei1,2, ZHAO Jiu-Jiang1,2, HU Jun-Dong1,2, ZHAO Ling-Hao1,2 |
1. National Geological Experiment and Testing Center, Beijing 100037,China 2. Key Laboratory of Micro- and Element Forms Analysis of China Geological Survey, Beijing 100037, China |
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Abstract Anning City, Yunnan Province, China is an important area of economic development and ecological civilization construction in central Yunnan on the upper reaches of the Yangtze River. This study investigated the contents and enrichment degrees of elements including heavy metals in the surface soil samples that were systematically collected in the Anning area from 2018 to 2020. Then, this study assessed the ecological risks of heavy metals in the soil using the geoaccumulation index and the assessment indices of potential ecological risks and analyzed the sources of heavy metals using the methods of the Pearson correlation and principal component analysis. The results show that heavy metals Cr, Zn, As, Cd, Pb, Hg, and radioactive element U in the soil in the study area have significantly higher contents than corresponding background values of soil in Yunnan Province and show high-degree variation and uneven spatial distribution. Moreover, Cr has the highest accumulation degree of geological anomalies, elements As, Cd, and Hg have high potential ecological risks, and ecological risks are mainly concentrated in the phosphate mining area and the vicinity of steel plants and chemical plants in the Tanglangchuan basin. In terms of sources, Cr, Ni, and Cu may mainly originate from soil parent materials; areas with high Cd, Pb, Zn, and As contents are significantly affected by human activities, and Hg may have a composite pollution source. These results will provide a scientific basis for understanding the sources of heavy metals in soil in Anning City and for the management and protection of local land resources.
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Received: 01 July 2021
Published: 21 June 2022
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Geological sketch of Anning City (modified according to 1 : 200,000 geological map of Wananning City) [25]
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特征参数 | Cr | Ni | Cu | Zn | As | Cd | Pb | Hg | Th | U | Se | F | 最大值/10-6 | 514 | 351 | 1405 | 2910 | 977 | 67.03 | 3599 | 8.48 | 49.2 | 46.7 | 48.2 | 26700 | 最小值/10-6 | 5.29 | 4.79 | 2.43 | 10.6 | 0.95 | — | 6.12 | 0.003 | 0.91 | 0.94 | 0.01 | 1.74 | 平均值/10-6 | 87.6 | 40.2 | 42.8 | 183 | 25.3 | 0.567 | 124 | 0.167 | 15.9 | 7.74 | 0.41 | 230 | 中位值/10-6 | 84.0 | 36.7 | 31.7 | 127 | 20.7 | 0.25 | 67.2 | 0.099 | 15.6 | 6.35 | 0.27 | 81.0 | 标准偏差/10-6 | 47.0 | 23.6 | 59.9 | 195 | 28.8 | 1.81 | 173.5 | 0.271 | 6.58 | 5.14 | 1.57 | 419 | 变异系数 | 0.54 | 0.59 | 1.40 | 1.06 | 1.14 | 3.20 | 1.40 | 1.62 | 0.41 | 0.66 | 3.83 | 1.82 | 云南省土壤背景值[29]/10-6 | 65.2 | 42.5 | 46.3 | 89.7 | 18.4 | 0.218 | 40.6 | 0.058 | 16.05 | 4.53 | 0.423 | 592 | 全国土壤背景值[31]/10-6 | 57.3 | 24.9 | 20.7 | 68.0 | 9.60 | 0.079 | 23.5 | 0.038 | 12.4 | 2.72 | 0.207 | 453 | K1 | 1.34 | 0.95 | 0.93 | 2.04 | 1.37 | 2.60 | 3.05 | 2.88 | 0.99 | 1.71 | 0.97 | 0.39 | K2 | 1.53 | 1.62 | 2.07 | 2.69 | 2.63 | 7.18 | 5.27 | 4.39 | 1.28 | 2.85 | 1.98 | 0.51 |
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Statistics of heavy metals, uranium, thorium, seleniumand fluorine content in the surface soil of the study area (n=2 424)
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Geochemistry maps of heavy metals in soil in Anning
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Geochemistry maps of U, Th, Se and F in soil in Anning
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重金属元素 | 各元素不同地累积指数级别样品数占比/% | Igeo<0 | 0≤Igeo<1 | 1≤Igeo<2 | 2≤Igeo<3 | 3≤Igeo<4 | 4≤Igeo<5 | Igeo≥5 | 无 | 较弱 | 弱 | 中等 | 较强 | 强烈 | 极强 | Cr | 63.52 | 4.21 | 7.61 | 4.63 | 3.51 | 2.48 | 14.0 | Ni | 90.84 | 1.03 | 2.10 | 1.57 | 0.05 | 0.05 | 3.55 | Cu | 90.80 | 3.34 | 1.98 | 0.74 | 0.70 | 0.54 | 1.90 | Zn | 54.81 | 19.19 | 12.01 | 4.17 | 2.60 | 1.49 | 5.74 | As | 71.16 | 5.41 | 8.02 | 4.26 | 2.23 | 1.40 | 7.52 | Cd | 56.37 | 23.79 | 9.22 | 3.25 | 2.59 | 0.92 | 3.86 | Pb | 50.04 | 32.66 | 8.34 | 2.73 | 1.82 | 0.83 | 3.59 | Hg | 45.16 | 29.03 | 12.99 | 5.09 | 0.91 | 1.36 | 5.46 |
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Geoaccumulation index of soil heavy metals in Anning
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重金属元素 | 不同潜在生态风险样品数占该区域样品总数百分比/% | 轻微 | 中等 | 强 | 很强 | 极强 | Cr | 100 | 0 | 0 | 0 | 0 | Ni | 99.95 | 0.05 | 0 | 0 | 0 | Cu | 99.51 | 0.41 | 0.08 | 0 | 0 | Zn | 99.92 | 0.08 | 0 | 0 | 0 | As | 64.89 | 28.17 | 5.87 | 0.90 | 0.16 | Cd | 56.10 | 19.38 | 14.00 | 7.22 | 3.29 | Pb | 93.02 | 5.50 | 1.27 | 0.16 | 0.04 | Hg | 28.34 | 26.65 | 23.74 | 15.36 | 5.38 |
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Potential ecological risk coefficient of soil heavy metals in Anning
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Soil potential ecological risk index spatial distribution of heavy metals in Anning
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元素 | Cr | Ni | Cu | Zn | As | Cd | Pb | Hg | Cr | 1 | | | | | | | | Ni | 0.546** | 1 | | | | | | | Cu | 0.378** | 0.464** | 1 | | | | | | Zn | -0.038 | 0.239** | 0.152** | 1 | | | | | As | 0.127** | 0.155** | 0.292** | 0.363** | 1 | | | | Cd | -0.047* | 0.068** | 0.085** | 0.445** | 0.181** | 1 | | | Pb | -0.035 | 0.105** | 0.003 | 0.469** | 0.463** | 0.172** | 1 | | Hg | -0.059** | 0.090** | -0.018 | 0.247** | 0.212** | 0.112** | 0.293** | 1 |
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Pearson correlation coefficient of heavy metals in soil in Anning
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重金属 元素 | 成分矩阵 | 旋转后成分载荷矩阵 | F1 | F2 | F1 | F2 | Cr | 0.344 | 0.748 | -0.133 | 0.813 | Ni | 0.575 | 0.598 | 0.142 | 0.817 | Cu | 0.510 | 0.569 | 0.104 | 0.757 | Zn | 0.719 | -0.349 | 0.791 | 0.113 | As | 0.687 | -0.133 | 0.644 | 0.275 | Cd | 0.456 | -0.304 | 0.549 | 0.003 | Pb | 0.620 | -0.435 | 0.758 | -0.014 | Hg | 0.398 | -0.352 | 0.527 | -0.069 | 特征值 | 2.451 | 1.786 | | | 累积方差百分比/% | 30.641 | 52.972 | | |
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Component matrix of soil heavy metals principal component analysis in Anning
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重金属元素 | 磷矿石 | 白云岩 | 炭质砂页岩 | 地壳丰度[41] | Cr | 39.16 | 13.78 | 66.16 | 102 | As | 15.91 | 6.94 | 21.56 | 1.8 | Cd | 0.61 | 0.56 | 0.35 | 0.15 | Hg | 0.15 | 0.05 | 0.15 | 0.085 | Pb | 82.09 | 27.48 | 115.17 | 14 | Ni | 15.99 | 8.80 | 36.24 | 84 | Cu | 11.79 | 9.33 | 24.51 | 60 | Zn | 137.84 | 61.39 | 129.91 | 70 |
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Information table of the content of heavy metal elements in the three rock types in the Xianjie phosphate mine in Anning county10-6
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