洛阳市伊川县鸦岭镇—汝阳县小店镇一带表层土壤硒形态研究

doi:10.11720/wtyht.2022.1242

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Abstract

Surface soil samples in Yaling Town, Yichuan County -Xiaodian Town, Ruyang County in Luoyang City were collected and analyzed to study the selenium (Se) speciation and its influencing factors. The study results are as follows. Existing Se in the surface soil of the study area mainly occurs in humic acid, residue, and strong organic states, while the sum of Se in water-soluble and ion-exchange states only accounts for 2.70% of total Se in the surface soil. Therefore, the Se in the study area shows the characteristics of the low content of water-soluble Se and a significantly high proportion of organic Se in total Se. The Se speciation in the surface soil is affected by the total Se content, pH, organic matter content, and type of soil. Specifically, the proportion of bioavailable Se in alkaline soil is significantly higher than that in neutral and acidic soils, and the bioavailable selenium content increases with increasing soil pH. Especially, the organic matter content in the soil has the most significant effects on organic Se but has no significant effect on bioavailable Se. For different types of soils, the proportion of the sum of Se in water-soluble and ionic-exchange states in total Se is in the order of red clay>paddy soil>brown soil>skeleton soil>fluvo-aquic soil>lime concretion black soil.

Key words： Luoyang surface soil selenium speciation influencing factor

Received: 27 April 2021 Published: 28 June 2022

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	Articles by authors
	Jin-Kai HOU
	Yan-Bin SONG
	Rui-Zhen ZHU
	Feng-Pei XIN
	Jian-Chuan ZHOU
	Fu-Lan LU
	Jie YAO

Cite this article:

Jin-Kai HOU,Yan-Bin SONG,Rui-Zhen ZHU, et al. Selenium speciation in surface soil in Yaling Town, Yichuan County—Xiaodian Town,Ruyang County in Luoyang City[J]. Geophysical and Geochemical Exploration, 2022, 46(2): 511-517.

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https://www.wutanyuhuatan.com/EN/10.11720/wtyht.2022.1242 OR https://www.wutanyuhuatan.com/EN/Y2022/V46/I2/511

Soil type map and sampling plot map in the study area

Statistic table of charactor values of selenium speciation content in soil

Statistic table of correlation coefficients of total selenium, organic matter, pH and selenium speciation

Statistic table of charactor values of selenium speciation in soils with different pH

Statistic table of charactor values of selenium speciation in different soil types

[1]	齐玉薇, 史长义. 硒的生态环境与人体健康[J]. 微量元素与健康研究, 2005, 22(2):63-66.
[1]	Qi Y W, Shi C Y. Se ecological environment and human body health[J]. Studies of Trace Elements and Health, 2005, 22(2): 63-66.
[2]	袁丽君, 袁林喜, 尹雪斌, 等. 硒的生理功能、摄入现状与对策研究进展[J]. 生物技术进展, 2016, 6(6):396-405.
[2]	Yuan L J, Yuan L X, Yin X B, et al. Physiological function, deficiency and its solution on selenium[J]. Current Biotechnology, 2016, 6(6): 396-405.
[3]	梁立军. 微量元素与人体健康[J]. 医学理论与实践, 2008, 21(3):782-783.
[3]	Liang L J. Trace elements and human health[J]. The Journal of Medical Theory and Practice, 2008, 21(3): 782-783.
[4]	王张民, 袁林喜, 朱元元, 等. 我国富硒农产品与土壤标准研究[J]. 土壤, 2018, 50(6):1080-1086.
[4]	Wang Z M, Yuan L X, Zhu Y Y, et al. On standards of selenium enriched agricultural products and selenium-rich soil in China[J]. Soils, 2018, 50(6): 1080-1086.
[5]	杨海滨, 邓敏, 盛中雷, 等. 土壤中硒元素研究进展[J]. 南方农业, 2014, 22:36-39.
[5]	Yang H B, Deng M, Sheng Z L, et al. Research progress of selenium in soil[J]. South China Agriculture, 2014, 22: 36-39.
[6]	Fairweathe-Tait S J, Bao Y, Broadley M R, et al. Selenium in human health and disease[J]. Antioxidants and Redox Signaling, 2011, 14(7): 1337-1383.
[7]	吕瑶瑶, 余涛, 杨忠芳, 等. 大骨节病区硒元素分布的调控机理研究:以四川省阿坝地区为例[J]. 环境化学, 2012, 31(7):935-944.
[7]	Lu Y Y, Yu T, Yang Z F, et al. The regulation mechanism of selenium distribution in Kaschin-Beck disease area:A case study in Aba area,Sichuan Province[J]. Environmental Chemistry, 2012, 31(7): 935-944.
[8]	Sager M. Selenium in agriculture, food and nutrition[J]. Pure and Applied Chemistry, 2006, 78(1): 111-133.
[9]	王锐, 余涛, 杨忠芳, 等. 富硒土壤硒生物有效性及影响因素研究[J]. 长江流域资源与环境, 2018, 27(7):1647-1654.
[9]	Wang R, Yu T, Yang Z F, et al. Bioavailability of soil selenium and its influencing factors in selenium-enriched soil[J]. Resources and Environment in the Yangtze Basin, 2018, 27(7): 1647-1654.
[10]	梁东丽, 彭琴, 崔泽玮, 等. 土壤中硒的形态转化及其对有效性的影响研究进展[J]. 生物技术进展, 2017, 7(5):374-380.
[10]	Liang D L, Peng Q, Cui Z W, et al. Progress on selenium bioavailability and influential factors in soil[J]. Current Biotechnology, 2017, 7(5): 374-380.
[11]	Rayman M P. Food-chain selenium and human health:emphasis on intake[J]. British Journal of Nutrition, 2008, 100(2): 254-268.
[12]	Kieliszek M, BazEjak S. Selenium:Significance,and outlook for supplementation[J]. Nutrition, 2013, 29(5): 713-718.
[13]	Harada T, Takahashi Y. Origin of the difference in the distribution behavior of tellurium and selenium in a soil-water system[J]. Geochimica et Cosmochimica Acta, 2008, 72(5): 1281-1294.
[14]	Frankanberger W T, Benson S. Selenium in the environment[M]. New York: Marcel DekkerInc, 1994.
[15]	Chen Q X, Shi W M, Wang X C. Selenium speciation and distribution characteristics in the rhizosphere soil of rice (Oryza sativa L.) seedlings[J]. Communications in Soil Science and Plant Analysis, 2010, 41: 1411-1425.
[16]	Lyons G, Ortiz-Monasterio I, Stangoulis J, et al. Selenium concentration in wheat grain: Is there sufficient genotypic variation to use in breeding[J]. Plant and Soil, 2005, 269: 369-380.
[17]	臧华伟, 张泽洲, 龙泽东, 等. 中国硒资源利用中若干关键科学问题的探讨[J]. 生物技术进展, 2021, 11(4):542-549.
[17]	Zang H W, Zhang Z Z, Long Z D, et al. Some key scientific questions in utilization of selenium resources in China[J]. Current Biotechnology, 2021, 11(4): 542-549.
[18]	邢颖, 刘永贤, 梁潘霞, 等. 土壤硒形态及其相互转化因子的研究[J]. 中国农学通报, 2018, 34(17):83-88.
[18]	Xing Y, Liu Y X, Liang P X, et al. Morphology and interconversion factor of selenium in soil[J]. Chinese Agricultural Science Bulletin, 2018, 34(17): 83-88.
[19]	宋晓珂, 李宗仁, 王金贵, 等. 青海东部富硒土壤中硒的形态和价态转化特征[J]. 干旱区资源与环境, 2018, 32(6):136-142.
[19]	Song X K, Li Z R, Wang J G, et al. Speciation and valence state transformation characteristics of selenium-rich soil in eastern Qinghai[J]. Journal of Arid Land Resources and Environment, 2018, 32(6): 136-142.
[20]	伊芹, 程皝, 尚文郁. 土壤硒的存在特征及分析测试技术研究进展[J]. 岩矿测试, 2021, 40(4):461-475.
[20]	Yin Q, Cheng H, Shang W Y. Review on characteristics of selenium in soil and the analytical techniques[J]. Rock and Mineral Analysis, 2021, 40(4): 461-475.
[21]	樊海峰, 温汉捷, 凌宏文, 等. 表生环境中硒形态研究现状[J]. 地球与环境, 2006, 34(2):19-26.
[21]	Fan H F, Wen H J, Ling H W, et al. Recent progress in research on selenium speciation in the supergene environment[J]. Earth and Environment, 2006, 34(2): 19-26.
[22]	瞿建国, 徐伯兴, 龚书椿. 连续浸提技术测定土壤和沉积物中硒的形态[J]. 环境化学, 1997, 16(3):277-283.
[22]	Qu J G, Xu B X, Gong S C. Sequential extraction techniques for determination of selenium speciation in soils and sediments[J]. Environmental Chemistry, 1997, 16(3): 277-283.
[23]	沈燕春, 周俊. 土壤硒的赋存状态与迁移转化[J]. 安徽地质, 2011, 21(3):186-191.
[23]	Shen Y C, Zhou J. Occurrence,migration and reansformation of selenium in soil[J]. Geology of Anhui, 2011, 21(3): 186-191.
[24]	秦海波, 朱建明, 李社红, 等. 环境中硒形态分析方法及研究进展[J]. 矿物岩石地球化学通报, 2008, 27(2):180-187.
[24]	Qin H B, Zhu J M, Li S H, et al. Advances in the speciation analysis of selenium in the environment[J]. Bullet of Mineralogy, Petrology and Geochemistry, 2008, 27(2): 180-187.
[25]	周越, 吴文良, 孟凡桥, 等. 土壤中硒含量、形态及有效性分析[J]. 农业资源与环境学报, 2014, 31(6):527-532.
[25]	ZHou Y, Wu W L, Meng F Q, et al. Review on the content,specification of selenium and its availability in soils[J]. Journal of Agricultural Resources and Environment, 2014, 31(6): 527-532.
[26]	张亚峰, 苗国文, 马强, 等. 青海东部碱性土壤中硒的形态特征[J]. 物探与化探, 2019, 43(5):1138-1144.
[26]	Zhang Y F, Miao G W, Ma Q, et al. Distribution characteristics of Se speciation of alkaline soil in eastern Qinghai[J]. Geophysical and Geochemical Exploration, 2019, 43(5): 1138-1144.
[27]	陈继平, 任蕊, 王晖, 等. 关中塿土地区土壤pH变化对硒形态及有效性的影响[J]. 西北地质, 2020, 53(1):244-260.
[27]	Chen J P, Ren R, Wang H, et al. Effect of Lou soil pH change on selenium forms and availability[J]. Northwestern Geology, 2020, 53(1): 244-260.
[28]	程涌, 陈云峰, 岳永强, 等. 湖北省利川市表层土壤中硒元素形态的受控因素研究[J]. 昆明冶金高等专科学校学报, 2020, 36(1):16-21.
[28]	Cheng Y, Chen Y F, Yue Y Q, et al. Study on controlled factors of selenium speciation in surface soil of Lichuan City in Hubei Province[J]. Journal of Kunming Metallurgy College, 2020, 36(1): 16-21.
[29]	魏然, 侯青叶, 杨忠芳, 等. 江西省鄱阳湖流域根系土硒形态分析及其迁移富集规律[J]. 物探与化探, 2012, 36(1):109-113.
[29]	Wei R, Hou Q Y, Yang Z F, et al. An analysis of speciation of selenium asits transformation and enrichment in root soil of Poyang lake basin, Jiangxi Province[J]. Geophysical and Geochemical Exploration, 2012, 36(1): 109-113.
[30]	黄淇, 成杭新, 陈出新, 等. 北京市房山区富硒土壤调查与评价[J]. 物探与化探, 2013, 37(5):889-894.
[30]	Huang Q, Cheng H X, Chen C X, et al. The investigation and evaluation of Selenium-rich soil in Fangshan District of Beijing City[J]. Geophysical and Geochemical Exploration, 2013, 37(5): 889-894.
[31]	陈东平, 张金鹏, 聂合飞, 等. 粤北山区连州市土壤硒含量分布特征及影响因素研究[J]. 环境科学学报, 2021, 41(7):2838-2848.
[31]	Chen D P, Zhang J P, Nie H F, et al. Selenium distribution in soils of Lianzhou City, mountain area of northern Guangdong Province and its influencing factors[J]. Acta Scientiae Circumstantiae, 2021, 41(7): 2838-2848.
[32]	张立, 姜侠, 崔玉军, 等. 松嫩平原吕大火房垂直剖面中硒赋存形态及影响因素分析[J]. 地质与资源, 2020, 29(6):603-608.
[32]	Zhang L, Jiang X, Cui Y J, et al. Analysis on the occurrence forms of selenium and influencing factors in Ludahuofang vertical section of Songnen plain[J]. Geology and Resources, 2020, 29(6): 603-608.
[33]	尹宗义, 王会锋, 任蕊, 等. 陕西省石头河一带土壤及植物富硒特征[J]. 物探与化探, 2014, 38(2):349-353.
[33]	Yin Z Y, Wang H F, Ren R, et al. The selenium-rich characteristics of soils and plants in Shitou river area, Shanxi Province[J]. Geophysical and Geochemical Exploration, 2014, 38(2): 349-353.
[34]	王潇, 张震, 朱江, 等. 青阳县富硒土壤中硒的形态与水稻富硒的相关性研究[J]. 地球与环境, 2019, 47(3):336-344.
[34]	Wang X, Zhang Z, Zhu J, et al. Study of correlation between rice selenium and status of selenium in selenium-rich soil in Qingyang County[J]. Earth and Environment, 2019, 47(3): 336-344.
[35]	谭见安, 李日邦, 侯少范, 等. 环境硒与健康[M]. 北京: 人民卫生出版社, 1989.
[35]	Tan J A, Li R B, Hou S F, et al. Environmental selenium and health[M]. Beijing: People’s Health Publishing House, 1989.
[36]	李永华, 王五一, 杨林生, 等. 陕南土壤中水溶态硒、氟的含量及其在生态环境的表征[J]. 环境化学, 2005, 24(3):279-283.
[36]	Li Y H, Wang W Y, Yang L S, et al. Concentration and environmental significance of water soluble-Se and water soluble-F in soils of south Shanxi Province[J]. Environmental Chemistry, 2005, 24(3): 279-283.
[37]	武少兴, 龚子同, 黄标, 等. 我国土壤中的水溶态硒含量及其与土壤理化性质的关系[J]. 中国环境科学, 1997, 17(6):522-525.
[37]	Wu S X, Gong Z T, Huang B, et al. Water-soluble selenium in main soil types of China and in relation to some soil properties[J]. China Environmental Science, 1997, 17(6): 522-525.
[38]	何振立, 杨肖娥, 祝军. 中国几种土壤中的有机态硒及其分布特征[J]. 环境科学学报, 1993, 13(3):282-287.
[38]	He Z L, Yang X E, Zhu J. Organic selenium and its distribution in soils[J]. Acta scientiae Circumstantiae, 1993, 13(3): 282-287.
[39]	Rosenfeld I, Beath O A. Selenium geobotany,biochemistry,toxicity and nutrition[M]. New York: Academic Press, 1964.
[40]	董广辉, 武志杰, 陈利军, 等. 土壤—植物生态系统中硒的循环和调节[J]. 农业系统科学与综合研究, 2002, 18(1):65-68.
[40]	Dong G X, Wu Z J, Chen L J, et al. Cycling and regulation of selenium in soil-plant ecosystem[J]. System Sciences and Comprehensive Studies in Agriculture, 2002, 18(1): 65-68.
[41]	Ashworth D J, Moore J, Shaw G. Effects of soil type,moisture content,redox potential and methyl bromide fumigation on Kd values of radio-selenium in soil[J]. Environ Radioactive, 2008, 99: 1136-1142.
[42]	安梦鱼. 富硒土壤硒形态转化的主要影响因子及对作物吸收的研究[D]. 福建: 福建农林大学, 2017.
[42]	An M Y. The main influencing factors of selenium transformation in Se-rich soil and its effects on plant absorption[D]. Fujian: Fujian Agriculture and Forestry University, 2017.
[43]	余飞, 张风雷, 张永文, 等. 重庆典型农业区土壤硒地球化学特征及影响因素[J]. 物探与化探, 2020, 44(4):830-838.
[43]	Yu F, Zhang F L, Zhang Y W, et al. Geochemical characteristics and influential factors of soil selenium in typical agricultural area, Chongqing[J]. Geophysical and Geochemical Exploration, 2020, 44(4): 830-838.