黑龙江省海伦地区黑土剖面常量元素地球化学特征及其对物源的指示意义

doi:10.11720/wtyht.2022.0040

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Abstract

The geochemical characteristics of the major elements in the black soil profiles and their ratios are closely related to the formation and development of the soil. They reflect the degree of the formation and development of soil as well as the environmental changes in the provenance areas. Moreover, they are important geological records of environmental evolution and climate change in the Songnen Plain. To explore the origin, provenance, and chemical weathering intensity of the typical black soil in northeast China, this study analyzed the major elements of nine representative black soil profiles in the Hailun area and then compared these elements with the element geochemical characteristics of typical aeolian deposits. The results are as follows. ①The sum of the content of the major elements (SiO₂, Al₂O₃, and Fe₂O₃) and the UCC standardized curve of the Hailun black soil profiles were highly similar to those of typical aeolian deposits, indicating that the typical black soil in Hailun is aeolian; ②The average chemical index of alteration (CIA) was 63.97. The CIA-Na/K diagrams all indicated a low degree of chemical weathering. By comparison with the weathering intensity of typical aeolian deposits, the weathering intensity of the soil was in the order of loess in Huangshan, Harbin > loess in Xiashu, Zhenjiang > red clay in Xifeng > black soil in Hailun≈loess in Luochuan; ③The black soil at a depth of 0~30 cm has higher w(SiO₂)/w(TiO₂) and w(SiO₂)/w(Al₂O₃) ratios than the black soil below 30 cm, indicating that the late typical black soil in Hailun has a coarser grain size and higher quartz content. The geochemical characteristics of the major elements indicate that the typical black soil in the surface layer and the deep layer may not have the same climate, environment, and provenance conditions, which may change at a depth of approximately 30 cm.

Key words： typical black soil in Hailun major elements provenance chemical weathering intensity geochemistry

Received: 27 January 2022 Published: 03 January 2023

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Corresponding Authors: YANG Feng-Chao E-mail: yunhong408@163.com;yangfc123@163.com

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	Yun-Hong SONG
	Feng-Chao YANG
	Kai LIU
	Hui-Min DAI
	Jiang XU
	Xiao-Meng HAN

Cite this article:

Yun-Hong SONG,Feng-Chao YANG,Kai LIU, et al. Geochemical characteristics of major elements in the black soil profiles of the Hailun area, Heilongjiang Province and their implications for provenance[J]. Geophysical and Geochemical Exploration, 2022, 46(5): 1105-1113.

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https://www.wutanyuhuatan.com/EN/10.11720/wtyht.2022.0040 OR https://www.wutanyuhuatan.com/EN/Y2022/V46/I5/1105

The sampling position of typical black soil profile in Hailun area

剖面号	参数	SiO₂	Al₂O₃	Fe₂O₃	K₂O	Na₂O	MgO	CaO	TiO₂	CIA
PM1901 n=7	最小值	65.51	13.53	4.57	2.51	1.71	1.22	1.25	0.77	60.80
	最大值	66.51	15.21	5.41	2.61	1.79	1.54	1.52	0.81	65.03
	平均值	66.05	14.67	5.10	2.56	1.75	1.40	1.33	0.80	63.62
PM1902 n=7	最小值	65.51	13.83	4.69	2.5	1.74	1.24	1.28	0.77	61.68
	最大值	66.32	15.26	5.50	2.6	1.84	1.57	1.44	0.80	64.77
	平均值	65.98	14.77	5.21	2.54	1.78	1.44	1.35	0.80	63.57
PM1903 n=10	最小值	65.34	13.96	4.72	2.49	1.74	1.29	1.30	0.77	61.78
	最大值	66.62	15.14	5.40	2.73	1.96	1.57	1.47	0.80	73.05
	平均值	65.75	14.83	5.15	2.59	1.83	1.46	1.35	0.79	66.42
PM1904 n=7	最小值	65.77	13.71	4.53	2.52	1.80	1.23	1.27	0.77	60.67
	最大值	66.61	15.01	5.38	2.6	1.88	1.49	1.53	0.80	63.83
	平均值	66.19	14.46	5.01	2.54	1.83	1.37	1.37	0.79	62.72
PM1907 n=11	最小值	65.52	13.78	4.53	2.51	1.70	1.24	1.19	0.78	61.69
	最大值	66.17	15.09	5.50	2.68	1.81	1.48	1.42	0.81	65.31
	平均值	65.89	14.72	5.17	2.55	1.75	1.39	1.28	0.80	63.94
PM1908 n=10	最小值	65.56	14.02	4.46	2.54	1.69	1.20	1.21	0.78	62.17
	最大值	66.27	15.07	5.44	2.62	1.91	1.58	1.37	0.81	64.56
	平均值	65.93	14.69	5.08	2.58	1.80	1.42	1.28	0.80	63.61
PM1909 n=9	最小值	65.43	13.42	4.62	2.47	1.59	1.23	1.24	0.76	60.55
	最大值	66.69	14.73	5.26	2.66	1.97	1.35	1.64	0.81	63.94
	平均值	66.14	14.18	4.92	2.59	1.77	1.28	1.43	0.79	62.31
PM1910 n=10	最小值	65.67	13.67	4.64	2.53	1.71	1.24	1.17	0.78	60.47
	最大值	66.87	15.07	5.38	2.61	1.95	1.49	1.47	0.82	65.29
	平均值	66.24	14.57	5.12	2.58	1.84	1.39	1.24	0.80	63.40
PM1921 n=10	最小值	65.9	13.25	4.29	2.52	1.75	1.15	1.15	0.77	60.58
	最大值	67.87	14.86	5.39	2.71	2.01	1.57	1.39	0.82	63.61
	平均值	66.58	14.38	5.07	2.61	1.93	1.41	1.27	0.80	62.44
荒山黄土 n=62	最小值	55.74	16.98	3.03	2.75	1.51	1.56	0.72
	最大值	66.70	21.97	4.85	3.19	2.45	2.07	1.01
	平均值	60.85	19.47	4.22	3.00	1.84	1.88	0.87		74.66
洛川黄土 n=12	平均值	66.4	14.2	4.81	3.01	1.66	2.29	1.02		63.73
镇江下蜀土n=54	平均值	68.07	13.32	5.3	2.35	0.92	1.61	1		70.45
西峰红黏土n=5	平均值	63.75	15.05	5.28	3	1.16	2.89	0.9		69.11
上陆壳 (UCC)	平均值	66.00	15.20	5.00	3.40	3.90	2.20	4.20		47.92

Element contents of Hailun black soil profile and other aeolian dust deposits%

Distribution characteristics of major elements in Hailun black soil profile

Correlation coefficient of element contents in Hailun Black soil profile

UCC-normalized pattern of elements of the Hailun black soil parent material and other aeolian dust deposits

Scatter diagram of CIA—w(Na)/w(K) molar ratio of the Hailun Black soil parent material(a), and variation of w(Na)/w(K)(b) and CIA(c) in Hailun area

w(TiO₂)/w(Al₂O₃) versus w(SiO₂)/w(Al₂O₃) (a)and w(TiO₂)/w(Al₂O₃) versus w(SiO₂)/w(TiO₂) (b)plots for the Hailun Black soil parent material

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