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Geochemical characteristics and environmental quality assessment of fluorine in soil and water in northern Tianjin |
Wei-Xing WANG, Shu-Ping CAO, Gong-Ke LI, Ya-Na ZHANG |
Tianjin Institute of Geological Survey, Tianjin 300191, China |
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Abstract Fluorine is a necessary trace element for human beings, and lack or excess of fluorine will exert adverse effects on human health. In this paper, the geochemical characteristics and environmental quality of fluorine in soil, groundwater and crops in Jizhou district of northern Tianjin were studied. The results are as follows: The fluorine content in surface soil ranges from 201×10 -6 to 8545×10 -6, with an average of 757×10 -6. The average content is 1.25 times the background value of surface soil in Tianjin and 1.58 times that in China. In the vertical profile of soil, the fluorine content is higher in cohesive soil than that in sandy soil. The average fluoride content of groundwater in plain area is 1.50 mg/L and that in mountainous area is 0.47 mg/L. The fluoride content in plain area is obviously higher than that in mountainous area. Over 90% of the surface soil fluoride content in the region is excessive and high, and the proportion of groundwater samples of fluoride IV and V in plain area reaches 61.54%. The proportion of fluorine exceeding the standard in maize samples is 26.67%, with the maximum exceeding multiple over two times. Generally speaking, the fluorine content in surface soil and groundwater in the plain area of northern Tianjin is significantly higher than that in the high fluoride area. The fluorine content in some agricultural products has exceeded the standard, to which more attention should be paid by the relevant departments.
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Received: 13 February 2019
Published: 03 March 2020
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样品种类 | 处理方法 | 测试方法 | 检测依据 | 土壤 | 0.5000 g样品、碱熔 | 选择性离子电极法 | DD2005-01 | 地下水 | | 选择性离子电极法 | DZ/T0064.54-1993 | 小麦、玉米籽实 | 扩散法 | F试剂比色法 | GB/T5009-2003,DD2005-03 GB/T5009-2003,DD2005-03 | 水果类 | 扩散法 | F试剂比色法 |
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Complementary scheme for fluorine analysis of various samples
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等级 | 缺乏 | 边缘 | 适量 | 高 | 过剩 | 土壤标准值/10-6 | ≤400 | >400~500 | >500~550 | >550~700 | >700 | 类别 | Ⅰ类 | Ⅱ类 | Ⅲ类 | Ⅳ类 | Ⅴ类 | 地下水限值/(mg·L-1) | ≤1.0 | ≤1.0 | ≤1.0 | ≤2.0 | >2.0 | 地表水限值/(mg·L-1) | ≤1.0 | ≤1.0 | ≤1.0 | ≤1.5 | ≤1.5 |
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Standards for classification of fluorine in soil,groundwater and surface water
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Fluorine geochemical map of surface soil
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编号 | 采样深度/cm | 岩性 | J01-1 | 0~20 | 棕色黏土 | J01-2 | 20~40 | 棕色黏土 | J01-3 | 40~60 | 棕色黏土 | J01-4 | 60~80 | 棕黄色粉砂质黏土 | J01-5 | 80~100 | 灰黄色粉砂质黏土 | J01-6 | 100~120 | 灰褐色粉砂土 | J01-7 | 120~150 | 灰褐色、黄褐色粉砂土 | J02-1 | 0~20 | 灰褐色黏土 | J02-2 | 20~40 | 灰褐色粉质黏土 | J02-3 | 40~60 | 灰褐色粉砂质黏土 | J02-4 | 60~80 | 黄褐色粉砂质黏土 | J02-5 | 80~100 | 黄褐色粉砂质黏土 | J02-6 | 100~120 | 灰褐色粉砂质黏土 | J02-7 | 120~150 | 灰褐色、灰黑色黏土 | J03-1 | 0~20 | 黄褐色粉砂质黏土 | J03-2 | 20~40 | 黄褐色粉砂质黏土 | J03-3 | 40~60 | 黄褐色粉砂质黏土 | J03-4 | 60~80 | 黄褐色粉质黏土 | J03-5 | 80~100 | 黄褐色粉质黏土 | J03-6 | 100~120 | 黄褐色粉质黏土 | J03-7 | 120~150 | 黄褐色粉质黏土 | J04-1 | 0~20 | 灰褐色黏土 | J04-2 | 20~40 | 灰褐色黏土 | J04-3 | 40~60 | 深灰褐色黏土 | J04-4 | 60~80 | 黄褐色黏土 | J04-5 | 80~100 | 黄褐色黏土 | J04-6 | 100~120 | 黄褐色粉砂质黏土 | J04-7 | 120~150 | 黄褐色粉砂质黏土 | J05-1 | 0~20 | 褐色黏土 | J05-2 | 20~40 | 褐色黏土 | J05-3 | 40~60 | 黄褐色粉砂质黏土 | J05-4 | 60~80 | 黄褐色粉砂质黏土 | J05-5 | 80~100 | 黄褐色黏土 | J05-6 | 100~120 | 黄褐色黏土 | J05-7 | 120~150 | 黄褐色黏土 | J06-1 | 0~20 | 褐色黏土 | J06-2 | 20~40 | 褐色黏土 | J06-3 | 40~60 | 黄褐色粉砂质黏土 | J06-4 | 60~80 | 黄褐色粉砂质黏土 | J06-5 | 80~100 | 黄褐色粉砂质黏土 | J06-6 | 100~120 | 黄褐色粉砂质黏土 | J06-7 | 120~150 | 黄褐色粉砂质黏土 | J07-1 | 0~20 | 褐色黏土 | J07-2 | 20~40 | 褐色黏土 | J07-3 | 40~60 | 褐色黏土 | J07-4 | 60~80 | 褐色黏土 | J07-5 | 80~100 | 黄褐色黏土 | J07-6 | 100~120 | 黄褐色黏土 | J07-7 | 120~150 | 黄褐色黏土 |
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Brief description of soil profile characteristics
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Distribution characteristics of fluorine in soil profile in Jizhou district
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样品 编号 | 地理 位置 | 井深 /m | 氟含量 /(mg·L-1) | 评价 类别 | 样品 编号 | 地理 位置 | 井深 /m | 氟含量 /(mg·L-1) | 评价 类别 | 平原区 | 山区 | JP1 | 马伸桥镇 | 100 | 0.86 | | JS1 | 下营镇 | 100 | 0.32 | | JP2 | 出头岭镇 | 160 | 1 | | JS2 | 下营镇 | 15 | <0.20 | | JP3 | 出头岭镇 | 30 | 0.32 | | JS3 | 下营镇 | 30 | 0.5 | | JP4 | 西龙虎峪镇 | 110 | 0.56 | | JS4 | 罗庄子镇 | 208 | 0.5 | | JP5 | 殷溜镇 | 70 | 0.92 | | JS5 | 穿芳峪镇 | 330 | 0.45 | | JP6 | 殷溜镇 | 70 | 2.02 | Ⅴ | JS6 | 孙各庄乡 | 30 | 0.96 | | JP7 | 五百户镇 | 60 | 0.32 | | JS7 | 孙各庄乡 | 15 | 0.25 | | JP8 | 别山镇 | 120 | 0.51 | | JS8 | 官庄镇 | 70 | 0.32 | | JP9 | 尤古庄镇 | 60 | 2.45 | Ⅴ | JS9 | 罗庄子镇 | 200 | 0.29 | | JP10 | 东二营乡 | 60 | 3.1 | Ⅴ | JS10 | 穿芳峪镇 | 130 | 0.7 | | JP11 | 东赵各庄乡 | 100 | 1.6 | Ⅳ | JS11 | 许家台镇 | 44 | 0.27 | | JP12 | 礼明庄镇 | 60 | 2.1 | Ⅴ | JS12 | 官庄镇 | 14 | <0.20 | | JP13 | 别山镇 | 50 | 0.7 | | JS13 | 官庄镇 | 70 | 0.26 | | JP14 | 杨津庄镇 | 60 | 1.68 | Ⅳ | JS14 | 渔阳镇 | 130 | <0.20 | | JP15 | 候家营镇 | 120 | 2.65 | Ⅴ | JS15 | 白涧镇 | 100 | 0.25 | | JP16 | 东施古镇 | 70 | 4.89 | Ⅴ | JS16 | 许家台镇 | 20 | 0.26 | | JP17 | 杨津庄镇 | 100 | 2.49 | Ⅴ | JS17 | 白涧镇 | 90 | 0.25 | | JP18 | 杨津庄 | 60 | 1.81 | Ⅳ | JS18 | 许家台镇 | 100 | 2.55 | Ⅴ | JP19 | 下窝头镇 | 100 | 1.87 | Ⅳ | JS19 | 白涧镇 | 70 | 0.42 | | JP20 | 候家营镇 | 80 | 1.31 | Ⅳ | JS20 | 邦均镇 | 80 | 0.39 | | JP21 | 杨津庄镇 | 100 | 1.13 | Ⅳ | JS21 | 下营镇 | 30 | 0.55 | | JP22 | 杨津庄镇 | 50 | 1.08 | Ⅳ | | | | | | JP23 | 杨津庄镇 | 50 | 1.08 | Ⅳ | | | | | | JP24 | 下仓镇 | 70 | 0.79 | | | | | | | JP25 | 下仓镇 | 60 | 1.13 | Ⅳ | | | | | | JP26 | 下仓镇 | 90 | 0.7 | | | | | | | 最小值 0.32 | 最大值 4.89 | 最小值 <0.20 | 最大值 2.55 | 平均值 1.5 | 中位值 1.13 | 平均值 0.47 | 中位值 0.32 |
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Distribution characteristics and environmental quality assessment of groundwater fluoride in plain and mountain areas of Jizhou
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样品编号 | 地理位置 | 水源 | 氟含量/(mg·L-1) | JB1 | 溵溜镇 | 州河河水 | 0.24 | JB2 | 下仓镇 | 州河河水 | 0.34 | JB3 | 上仓镇 | 州河河水 | 0.35 | JB4 | 上仓镇 | 州河河水 | 0.41 | JB5 | 杨津庄镇 | 州河河水 | 0.60 | JB6 | 下仓镇 | 州河河水 | 0.65 | JB7 | 下仓镇 | 州河河水 | 0.86 | JB8 | 桑梓镇 | 泃河河水 | 0.70 | JB9 | 侯家营镇 | 渠水 | 0.60 | JB10 | 下窝头镇 | 渠水 | 0.73 | JB11 | 下仓镇 | 渠水 | 1.00 | 最小值 0.24 | 最大值 1.00 | 平均值 0.59 | 中位值 0.60 |
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Distribution characteristics and environmental quality assessment of surface water fluoride
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Assessment chart of surface soil fluoride environmental quality
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农作物 | 样品数 | 含量范围/10-6 | 平均值/10-6 | 标准限值/10-6 | 超标数量 | 小麦 | 30 | 0.30~0.80 | 0.56 | 1.0 | 0 | 玉米 | 30 | 0.38~3.41 | 1.21 | 1.5 | 8 | 板栗 | 15 | 0.09~0.24 | 0.16 | 0.5 | 0 | 苹果 | 15 | 0.04~0.24 | 0.15 | 0.5 | 0 | 红果 | 15 | 0.03~0.12 | 0.08 | 0.5 | 0 | 柿子 | 15 | 0.02~0.06 | 0.04 | 0.5 | 0 | 酸梨 | 15 | 0.02~0.04 | 0.03 | 0.5 | 0 |
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Characteristics and evaluation of fluorine content in crops
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