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Ecological risk evaluation of heavy metals in soils of Carya cathayensis plantations, Lin'an |
Dao-Rong LIU, Ji-Zi ZHENG, Xuan ZHAN, Wen-Dan WU |
Zhejiang Geological Prospecting Institute of China Chemical Geology and Mine Bureau, Hangzhou 310002, Chinaa |
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Abstract Through investigation and sampling Carya cathayensis kernels and soil of plantations, the heavy metals, Se, organic matter and other indicators in soil were analyzed, and the pollution degrees of heavy metals in soil were evaluated with risk screening values as the criteria. The content of heavy metals, Se, Ge and other trace components in kernels was analyzed, and the relationship between soil and kernels was discussed. The results show that the average values of Cu, Pb, Zn, Ni, Cr, Cd, As, Hg and Se in the soil of Carya cathayensis plantations are higher than those of the average soil of China, especially Cd is 5.6 times that of the average soil of China. Local soil Cd and As in the study area have reached the pollution level while the ecological risk of other heavy metals is slight. Carya cathayensis kernels have low Cd, Hg, Pb, As and other heavy metals content, no excessive heavy metal elements, low ecological risk, and high zinc content, with the potential to develop zinc-rich health food. Carya cathayensis has a significant difference in the absorption capacity of different heavy metals. The absorption capacity of zinc and copper is much greater than that of Cd, Cr and Hg.
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Received: 20 May 2019
Published: 28 November 2019
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Geological background and sampling sites of Lin'an area (modified after Lin'an geology sketch map(1:100 000))
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分析指标 | 分析方法 | 检出限 | 单位 | 分析指标 | 分析方法 | 检出限 | 单位 | As | 氢化物—原子荧光光谱法 | 0.2 | 10-6 | Ni | X-射线荧光光谱法 | 1 | 10-6 | Cd | 等离子体质谱法 | 0.03 | 10-6 | Pb | 等离子体质谱法 | 2 | 10-6 | Cr | X-射线荧光光谱法 | 2 | 10-6 | Se | 氢化物—原子荧光光谱法 | 0.01 | 10-6 | Cu | 等离子体质谱法 | 1 | 10-6 | Zn | X-射线荧光光谱法 | 2 | 10-6 | F | 离子选择电极 | 100 | 10-6 | 有机质 | 电位法 | 0.1 | % | Ge | 氢化物—原子荧光光谱法 | 0.1 | 10-6 | pH | 玻璃电极法 | 0.1 | | Hg | 冷蒸汽—原子荧光光谱法 | 2 | 10-9 | | | | |
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Analytical method and detection limit of soil geochemical indicators
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指标 | Cu | Pb | Zn | Ni | Cr | Cd | As | Hg | Se | Ge | 有机质 | F | pH | 最大值 | 59.4 | 84.7 | 151 | 62.8 | 108 | 3.60 | 181 | 215 | 1.82 | 2.44 | 7.83 | 1963 | 7.38 | 最小值 | 11.3 | 13.0 | 54.2 | 9.66 | 26.8 | 0.10 | 3.43 | 36.0 | 0.26 | 0.30 | 1.41 | 409 | 5.06 | 平均值 | 35.5 | 35.9 | 103 | 38.9 | 79.1 | 0.53 | 25.1 | 97.4 | 0.61 | 1.62 | 3.43 | 865 | 5.83 | 标准离差 | 12.56 | 13.04 | 22.46 | 12.52 | 22.28 | 0.65 | 34.14 | 40.57 | 0.33 | 0.40 | 1.21 | 405.62 | | 变异系数Cv/% | 35.34 | 36.33 | 21.81 | 32.21 | 28.15 | 122.33 | 136.18 | 41.63 | 53.94 | 24.86 | 35.17 | 46.88 | | 中国土壤平均值 | 22.6 | 26.0 | 74.2 | 26.9 | 61.0 | 0.097 | 11.20 | 65 | 0.29 | 1.70 | | 478 | | 富集系数q | 1.70 | 1.39 | 1.40 | 1.43 | 1.45 | 5.62 | 2.48 | 1.88 | 3.02 | 0.97 | | 1.80 | | 风险筛选值 | 150 | 90 | 200 | 70 | 150 | 0.3 | 40 | 1800 | | | | | |
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Statistical parameters of element contents in surface soils of Lin'an area(n=32)
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指标 | Cu | Pb | Zn | Ni | Cr | Cd | As | Hg | Se | Ge | 有机质 | F | pH | Cu | 1 | | | | | | | | | | | | | Pb | -0.039 | 1 | | | | | | | | | | | | Zn | 0.656** | 0.290 | 1 | | | | | | | | | | | Ni | 0.876** | -0.096 | 0.679** | 1 | | | | | | | | | | Cr | 0.669** | -0.222 | 0.446** | 0.818** | 1 | | | | | | | | | Cd | 0.058 | 0.713** | 0.431* | -0.011 | -0.344 | 1 | | | | | | | | As | 0.209 | 0.128 | 0.006 | 0.078 | 0.084 | 0.008 | 1 | | | | | | | Hg | 0.044 | 0.024 | -0.140 | -0.227 | -0.243 | -0.125 | 0.131 | 1 | | | | | | Se | 0.361* | 0.137 | 0.458** | 0.364* | 0.128 | 0.267 | 0.110 | 0.016 | 1 | | | | | Ge | 0.343 | -0.325 | -0.034 | 0.221 | 0.524** | -0.600** | 0.033 | 0.085 | -0.252 | 1 | | | | 有机质 | 0.058 | -0.062 | -0.201 | -0.004 | 0.024 | -0.009 | 0.007 | 0.173 | 0.178 | -0.130 | 1 | | | F | 0.704** | 0.125 | 0.539** | 0.502** | 0.397* | 0.234 | 0.087 | -0.011 | 0.124 | 0.348* | 0.004 | 1 | | pH | 0.061 | 0.290 | 0.352* | 0.006 | -0.112 | 0.553** | -0.080 | -0.222 | -0.087 | -0.412* | 0.185 | 0.389* | 1 |
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Correlation coefficient between heavy metals and physico-chemical properties in soil(n=32)
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地层 | 样品数 | Cu | Pb | Zn | Ni | Cr | Cd | As | Hg | Se | Ge | 有机质 | F | pH | 侏罗系 | 2 | 12.7 | 30.4 | 61.3 | 11.2 | 29.9 | 0.17 | 5.88 | 117 | 0.29 | 1.51 | 2.79 | 500 | 5.46 | 震旦系 | 4 | 26.2 | 48.1 | 106 | 26.1 | 47.2 | 1.45 | 15.8 | 109 | 0.62 | 1.13 | 4.36 | 785 | 6.70 | 寒武系 | 11 | 45.9 | 34.5 | 116 | 47.4 | 87.1 | 0.64 | 34.3 | 87.8 | 0.81 | 1.69 | 3.32 | 1085 | 5.76 | 奥陶系 | 15 | 33.5 | 34.3 | 98.4 | 39.8 | 88.4 | 0.24 | 23.3 | 98.8 | 0.49 | 1.72 | 3.36 | 775 | 5.71 | 平均值 | 32 | 35.5 | 35.9 | 103 | 38.9 | 79.1 | 0.53 | 25.1 | 97.4 | 0.61 | 1.62 | 3.43 | 865 | 5.83 |
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Average concentrations of elements in surface soils of study area with different geological settings
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参数 | Cu | Pb | Zn | Ni | Cr | Cd | As | Hg | 平均值 | 0.24 | 0.40 | 0.51 | 0.56 | 0.53 | 1.76 | 0.63 | 0.05 | 最大值 | 0.40 | 0.94 | 0.76 | 0.90 | 0.72 | 12.00 | 4.53 | 0.12 | 最小值 | 0.08 | 0.14 | 0.27 | 0.14 | 0.18 | 0.34 | 0.09 | 0.02 | 超标率/% | 0 | 0 | 0 | 0 | 0 | 50 | 12.5 | 0 |
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Evaluated results of single factor pollution index for soil heavy metals
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评价标准 | 清洁 P综≤0.7 | 尚清洁 0.7<P综≤1.0 | 轻度污染 1.0<P综≤2.0 | 中度污染 2.0<P综≤3.0 | 重度污染 P综>3.0 | 风险筛选值/% | 46.88 | 9.38 | 25.0 | 9.38 | 9.38 |
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Overall evaluation results of soil heavy metals in study area
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参数 | Cu | Pb | Zn | Ni | Cr | Cd | Ge | As | Hg | Se | 最大值 | 20.24 | 0.13 | 82.71 | 27.03 | 0.56 | 0.082 | 2.15 | <0.04 | 2.92 | 0.009 | 最小值 | 7.65 | <0.05 | 49.96 | 0.59 | 0.46 | 0.011 | <1.00 | | 0.76 | <0.005 | 平均值 | 14.87 | | 63.91 | 11.14 | 0.53 | 0.044 | | | 1.88 | | 标准离差 | 3.00 | | 7.73 | 6.59 | 0.02 | 19.10 | | | 0.63 | | 变异系数/% | 20.17 | | 12.10 | 59.11 | 4.45 | 43.50 | | | 33.26 | | 标准值 | | 0.2 | | | | 0.5 | | | | |
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Contents of trace elements in Carya cathayensis kernels
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参数 | Cu | Zn | Ni | Cr | Cd | Hg | 平均值 | 0.487 | 0.663 | 0.303 | 0.008 | 0.163 | 0.022 | 最大值 | 1.363 | 1.526 | 0.675 | 0.020 | 0.435 | 0.037 | 最小值 | 0.182 | 0.419 | 0.029 | 0.005 | 0.004 | 0.005 |
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The BCFs of some heavy metals in Carya cathayensis kernels
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Relationship between the contents of Zinc in Carya cathayensi kernels and soil
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