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Carbon sink in farmland soils in Luoyang City, China |
XIA Yan( ), WANG Run-Tao, DU Qian-Qian, WANG Xi-Kuan( ), Lyu Hong-Jie, HOU Jin-Kai, LI Bing-Hui |
Henan First Geology and Mineral Survey Institute Co., Ltd., Luoyang 471023, China |
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Abstract This study investigates the spatial distribution characteristics, temporal changes, and influencing factors of total carbon density, organic carbon density, and reserves in the farmland soils in Luoyang City based on repeated sampling data from multi-purpose regional geochemical survey points over different periods. The results indicate that in 2005, the topsoils in the multi-purpose survey area exhibited an average total carbon content of 1.57%, an average total carbon density of 44.74 t/hm2, an average organic carbon content of 1.12%, and an average organic carbon density of 34.27 t/hm2. With annual average increases in the total carbon density and organic carbon density of 0.709 t/hm2 and 6.643 t/hm2, respectively, this year witnessed increases in the total carbon and organic carbon of 41.73 kg/(hm2·a) and 390.75 kg/(hm2·a), respectively. The respective reserves of total carbon and organic carbon were 12.511 3 million tons and 8.879 59 million tons, with respective increases of 198.28 thousand tons and 1.857 8 million tons. In 2018, the topsoils in the multi-purpose survey area displayed an average total carbon content of 1.18%, an average total carbon density of 34.27 t/hm2, an average organic carbon content of 1.07%, and an average organic carbon density of 30.94 t/hm2. With annual average increases in the total carbon density and organic carbon density of 9.642 t/hm2 and 4.727 t/hm2, respectively, this year witnessed increases in the total carbon and organic carbon of -2,410.5 kg/(hm2·a) and 1,181.75 kg/(hm2·a), respectively. The respective reserves of total carbon and organic carbon were 1.963 5 million tons and 1.772 61 million tons. The total carbon reserves in topsoils in the whole study area were 14.474 81 million tons, including organic carbon reserves of 10.652 2 million tons. The total carbon reserves decreased by 552.41 thousand tons, while the organic carbon reserve increased by 270.82 thousand tons. Overall, the study area experienced a total carbon decrease of 354.13 thousand tons and an increase in the organic carbon reserves of 2.128 62 million tons. The total carbon showed significant positive correlations with the contents of organic carbon, CaO, MgO, N, and P, the organic carbon displayed significant positive correlations with the contents of total carbon, N, and P, and there was a significant positive correlation between pH and the CaO content. Fertilization led to an increase in the organic carbon and total carbon contents in farmland soils, with total carbon being significantly affected by the CaO content. In the carbonate areas, alkaline soil environments exhibited carbon sink characteristics. In the southern regions with acidified soil environments, the decomposition of carbonates in soils led to carbon loss and reduced calcium content. The results of this study provide important scientific evidence for research on peak carbon dioxide emissions and carbon neutrality of Luoyang City.
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Received: 19 July 2023
Published: 26 February 2025
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The scope of 1∶250,000 multi-target regional geochemical surveys in 2005 and 2018 and the repeated sampling sites in 2022 in Luoyang City
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时间 | 项目 | CaO | TC | Corg | 项目 | CaO | TC | Corg | 2005年 | ΔlgCB | -0.003 12 | 0.001 58 | -0.002 3 | 精密度 (RSD)/% | 4.28 | 5.03 | 5.18 | 2018年 | -0.003 17 | 0.001 67 | -0.002 5 | 4.75 | 5.63 | 5.89 | 2022年 | -0.003 2 | 0.001 68 | -0.002 6 | 4.88 | 5.39 | 5.36 | 2005年 | ΔlgCB 合格率 | 100% | 100% | 100% | 合格率 | 100% | 100% | 100% | 2018年 | 100% | 100% | 100% | 100% | 100% | 100% | 2022年 | 100% | 100% | 100% | 100% | 100% | 100% | 2005年 | 抽样及重复 样合格率 | 100% | 100% | 100% | 报出率 | 100% | 100% | 100% | 2018年 | 100% | 100% | 100% | 100% | 100% | 100% | 2022年 | 100% | 100% | 100% | 100% | 100% | 100% |
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Statistics of sample analysis quality at different times
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项目 | 北部2005年多目标调查区(n=145) | 南部2018年多目标调查区(n=36) | 时间 | 最小值 | 最大值 | 均值 | 变异系数 | 时间 | 最小值 | 最大值 | 均值 | 变异系数 | pH | 2005年 | 6.95 | 8.32 | 7.89 | 0.03 | 2018年 | 5.90 | 9.26 | 7.59 | 0.13 | 2022年 | 5.31 | 8.56 | 7.91 | 0.05 | 2022年 | 5.74 | 7.86 | 6.90 | 0.06 | 全碳 | 2005年 | 0.77 | 2.61 | 1.53 | 0.27 | 2018年 | 0.70 | 2.45 | 1.51 | 0.29 | 2022年 | 0.67 | 3.31 | 1.57 | 0.27 | 2022年 | 0.49 | 2.57 | 1.18 | 0.44 | 有机碳 | 2005年 | 0.41 | 2.73 | 0.89 | 0.36 | 2018年 | 0.51 | 1.60 | 0.90 | 0.27 | 2022年 | 0.47 | 3.21 | 1.12 | 0.3 | 2022年 | 0.46 | 2.47 | 1.07 | 0.44 | CaO | 2005年 | 0.98 | 11.28 | 4.30 | 0.49 | 2018年 | 1.55 | 11.17 | 3.86 | 0.64 | 2022年 | 1.11 | 11.89 | 4.57 | 0.42 | 2022年 | 0.89 | 6.98 | 2.28 | 0.50 |
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Content characteristics of pH, total carbon, organic carbon and CaO in soil of Luoyang City
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Isograms of total carbon and organic carbon in different periods of soil in Luoyang City a—multi-objective survey full carbon contour; b—full carbon contour of this survey; c—multi-objective investigation of organic carbon contours; d—this survey of organic carbon contours
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项目 | 北部2005年多目标调查区(n=145) | 南部2018年多目标调查区(n=36) | 时间 | 最小值 | 最大值 | 均值 | 时间 | 最小值 | 最大值 | 均值 | pH | 2005~ 2022年 | -26.35 | 10.40 | 0.28 | 2018~ 2022年 | -26.74 | 22.54 | -7.80 | 全碳 | -39.46 | 240.91 | 6.55 | -71.72 | 55.63 | -19.45 | 有机碳 | -50.08 | 167.21 | 33.44 | -60.90 | 141.83 | 23.47 | CaO | -54.45 | 352.17 | 14.47 | -77.60 | 46.67 | -30.70 |
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Statistical table of change rate of total carbon and organic carbon content in soil of Luoyang City %
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Distribution of total carbon, organic carbon, pH and CaO change rates in soil of Luoyang City
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项目 | 地区 | pH | 全碳 | 有机碳 | N | P | SiO2 | Al2O3 | K2O | Na2O | CaO | MgO | Fe2O3 | pH | 2022年 | 1 | 0.24** | -0.10 | -0.12 | 0.04 | -0.25** | -0.37** | -0.22** | 0.13 | 0.53** | 0.39** | -0.44** | 2005年 | 1 | 0.35** | -0.21* | -0.45** | -0.08 | -0.44** | -0.36** | -0.10 | 0.07 | 0.51** | 0.23** | -0.29* | 2018年 | 1 | 0.14 | -0.26 | -0.31 | -0.05 | -0.18 | 0.12 | 0.06 | -0.38* | 0.61** | 0.23 | -0.18 | 全碳 | 2022年 | 0.24** | 1 | 0.66** | 0.23** | 0.25** | -0.53** | -0.42** | -0.34** | -0.06 | 0.72** | 0.27** | -0.36** | 2005年 | 0.35** | 1 | 0.34** | -0.07 | 0.21* | -0.48** | -0.61** | -0.42** | 0.15 | 0.67** | 0.10 | -0.53** | 2018年 | 0.14 | 1 | 0.76** | 0.67** | 0.24 | -0.05 | -0.45** | 0.06 | -0.20 | 0.43** | 0.02 | -0.21 | 有机 碳 | 2022年 | -0.10 | 0.66** | 1 | 0.37** | 0.32** | -0.14 | 0.01 | -0.05 | -0.13 | 0.01 | -0.06 | 0.01 | 2005年 | -0.21* | 0.34** | 1 | 0.64** | 0.34** | 0.14 | 0.23** | 0.11 | -0.10 | -0.25** | -0.20* | 0.02 | 2018年 | -0.26 | 0.76** | 1 | 0.91** | 0.19 | 0.31 | -0.42* | -0.14 | 0.06 | -0.22 | -0.17 | -0.27 | CaO | 2022年 | 0.53** | 0.72** | 0.01 | -0.08 | 0.11 | -0.59** | -0.60** | -0.42** | 0.09 | 1 | 0.44** | -0.51** | 2005年 | 0.51** | 0.67** | -0.25** | -0.44** | -0.03 | -0.81** | -0.63** | -0.45** | -0.10 | 1 | 0.19* | -0.35** | 2018年 | 0.61** | 0.43** | -0.23 | -0.20 | 0.24 | -0.52** | -0.13 | 0.26 | -0.24 | 1 | 0.36* | 0.12 |
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Correlation of total carbon, organic carbon, pH, main elements and oxide content in soil of Luoyang City
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项目 | 地区 | pH | 全碳 | 有机碳 | N | P | SiO2 | Al2O3 | K2O | Na2O | CaO | MgO | Fe2O3 | pH | 2022年 | 1 | 0.11 | -0.06 | -0.13 | -0.05 | -0.09 | -0.22** | -0.30** | 0.09 | 0.31** | 0.14 | -0.37** | 2005年 | 1 | -0.03 | -0.07 | -0.10 | -0.05 | -0.02 | -0.05 | 0.03 | -0.05 | 0.1 | 0.05 | -0.14 | 2018年 | 1 | -0.03 | -0.18 | -0.25 | -0.26 | -0.14 | 0.17 | 0.004 | -0.23 | 0.43** | 0.23 | -0.07 | 全碳 | 2022年 | 0.11 | 1 | 0.51** | 0.22** | 0.19** | -0.43** | -0.49** | -0.47** | 0.22** | 0.74** | 0.29** | -0.44** | 2005年 | -0.03 | 1 | 0.4** | 0.14 | 0.18* | -0.50** | -0.38** | -0.47** | 0.12 | 0.79** | 0.41** | -0.31** | 2018年 | -0.03 | 1 | 0.90** | 0.87** | 0.14 | 0.10 | -0.58** | -0.28 | 0.11 | 0.27 | -0.12 | -0.47** | 有机 碳 | 2022年 | -0.06 | 0.51** | 1 | 0.43** | 0.33** | -0.07 | -0.08 | -0.17* | 0.06 | 0.10 | 0.08 | -0.13 | 2005年 | -0.07 | 0.4** | 1 | 0.32** | 0.4** | -0.14 | 0.09 | -0.06 | 0.001 | 0.09 | 0.19* | 0.08 | 2018年 | -0.18 | 0.90** | 1 | 0.96** | 0.09 | 0.21 | -0.39* | -0.3 | 0.10 | -0.01 | -0.19 | -0.42 | CaO | 2022年 | 0.31** | 0.74** | 0.10 | -0.06 | 0.12 | -0.58** | -0.60** | -0.49** | 0.08 | 1 | 0.33** | -0.45** | 2005年 | 0.1 | 0.79** | 0.09 | -0.05 | 0.1 | -0.59** | -0.55** | -0.56** | -0.03 | 1 | 0.39** | -0.37** | 2018年 | 0.43** | 0.27 | -0.01 | -0.06 | 0.01 | -0.49** | -0.26 | 0.16 | -0.41* | 1 | 0.15 | -0.02 |
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Correlation of the change rate between total carbon, organic carbon, pH, major elements and oxide in soil of Luoyang City
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区域 | 样品数 | 项目 | 最小值 | 最大值 | 均值 | 标准偏差 | 变异系数 | 2005年多目标调查区 | 145 | 全碳密度/(t·hm-2) | 11.48 | 95.91 | 44.74 | 12.43 | 0.28 | 有机碳密度/(t·hm-2) | 10.86 | 73.61 | 31.75 | 8.81 | 0.28 | 2018年多目标调查区 | 36 | 全碳密度/(t·hm-2) | 14.55 | 79.62 | 34.27 | 15.69 | 0.46 | 有机碳密度/(t·hm-2) | 13.65 | 76.54 | 30.94 | 14.30 | 0.46 | 全区 | 181 | 全碳密度/(t·hm-2) | 11.48 | 95.91 | 42.66 | 13.75 | 0.32 | 有机碳密度/(t·hm-2) | 10.86 | 76.54 | 31.59 | 10.10 | 0.32 |
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Characteristic values of total carbon and organic carbon density in soil of Luoyang City
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国家和地区 | 有机碳密度/ (t·hm-2) | 文献 | 发表时 间/年 | 全球表土 | 47. 8 | [15] | 2019 | 欧盟农田表土 | 53.0 | [15] | 2019 | 美国表土 | 50. 3 | [15] | 2019 | 巴西表土 | 44.1 | [15] | 2019 | 印度表土 | 63.8 | [15] | 2019 | 中国自然土壤 | 48.7 | [16] | 2005 | 中国农田土壤(2008) | 38.5 | [17] | 2008 | 中国农田土壤(1981) | 28.6 | [18] | 2018 | 中国农田土壤(2011) | 32.9 | [18] | 2018 | 中国东北农田土壤(2011) | 42.2 | [18] | 2018 | 中国北部农田土壤(2011) | 21.2 | [18] | 2018 | 中国东部农田土壤(2011) | 30.4 | [18] | 2018 | 中国西南农田土壤(2011) | 34.1 | [18] | 2018 | 中国中南农田土壤(2011) | 29.6 | [18] | 2018 | 中国西北农田土壤(2011) | 21.0 | [18] | 2018 | 中国土壤 | 91.7 | [19] | 2003 | 河南省耕地土壤 | 23.9 | [20] | 2014 | 2005年调查区 | 31.75 | 本次研究 | 2023 | 2018年调查区 | 30.94 | 本次研究 | 2023 |
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Comparison of soil carbon density between the study area and domestic and foreign farmland
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区域 | 样品数 | 项目 | 最小值 | 最大值 | 均值 | 标准偏差 | 2005年多目标调查区 | 145 | 全碳密度变化量/(t·hm-2) | -28.73 | 67.78 | 0.71 | 12.05 | 有机碳密度变化量/(t·hm-2) | -31.51 | 28.90 | 6.64 | 8.31 | 2018年多目标调查区 | 36 | 全碳密度变化量/(t·hm-2) | -37.92 | 23.01 | -9.64 | 14.87 | 有机碳密度变化量/(t·hm-2) | -21.25 | 41.89 | 4.73 | 13.92 | 全区 | 181 | 全碳密度变化量/(t·hm-2) | -37.92 | 67.78 | -1.35 | 13.28 | 有机碳密度变化量/(t·hm-2) | -31.51 | 41.89 | 6.26 | 9.67 |
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Characteristics of soil carbon density change in Luoyang City
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调查区 | 全碳/(kg·(hm2·a-1)) | 有机碳/(kg·(hm2·a-1)) | 2005年 | 41.73 | 390.75 | 2018年 | -2 410.50 | 1 181.75 |
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Scale of carbon density change in soil of Luoyang City
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区域 | 面积/km2 | 面积/hm2 | 全碳密度/ (t·hm-2) | 全碳储量 (万t) | 2005年调查区 | 2 796.634 | 279 663.424 | 44.737 | 1 251.130 | 2018年调查区 | 572.918 | 5 7291.747 | 34.272 | 196.350 | 合计 | 3 369.552 | 336 955.171 | 42.958 | 1447.481 | 区域 | 面积/km2 | 面积/hm2 | 有机碳密度/ (t·hm-2) | 有机碳储量 (万t) | 2005年调查区 | 2 796.634 | 279 663.424 | 31.751 | 887.959 | 2018年调查区 | 572.917 | 57 291.747 | 30.940 | 177.261 | 合计 | 3 369.552 | 336 955.171 | 31.613 | 1 065.220 |
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Total carbon and organic carbon reserves in soil of Luoyang City
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区域 | 面积/km2 | 面积/hm2 | 全碳密度变化 /(t·hm-2) | 全碳汇变 化/(万t) | 2005年调查区 | 2 796.634 | 279 663.424 | 0.709 | 19.828 | 2018年调查区 | 572.918 | 57 291.747 | -9.642 | -55.241 | 合计 | 3 369.552 | 336 955.171 | -1.051 | -35.413 | 区域 | 面积/km2 | 面积/hm2 | 有机碳密度变 化/(t·hm-2) | 有机碳汇变 化/(万t) | 2005年调查区 | 2 796.634 | 279 663.424 | 6.643 | 185.780 | 2018年调查区 | 572.918 | 57 291.747 | 4.727 | 27.082 | 合计 | 3 369.552 | 336 955.171 | 6.317 | 212.862 |
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Change table of total carbon and organic carbon sink in farmland soil of Luoyang City
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