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Research progress in the geological characteristics and material sources of fluorite deposits in the Heyu-Checun area, western Henan Province |
ZHANG Kai-Tao1( ), BAI De-Sheng1( ), Li Jun-Sheng1, LIU Ji-Feng1, XU Dong2, SU Yang-Yan1, FAN Kang1 |
1. No.2 Institute of Geological & Mineral Resources Survey of Henan, Zhengzhou 450001, China 2. No.3 Institute of Geological & Mineral Resources Survey of Henan, Zhengzhou 450000, China |
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Abstract Based on the data on the geology, minerals, exploration, and geochemistry of more than 30 fluorite deposits in the Heyu-Checun area, western Henan Province, this study summarized the types, spatial distribution, and geochemical characteristics of fluorite deposits in the area and explored the genesis and material sources of the deposits. The fluorite deposits in this area have simple types and are distributed in Yanshanian granites and along the fault zone of the external contact zone of the granites. The formation ages of the Heyu and Taishanmiao plutons are 124.7~148.2 Ma and 115~123.1 Ma, respectively. The mineralized age of fluorites is 120~126.8 Ma, indicating that the mineralization occurred in the late stage of the intrusion of the Heyu pluton and the early stage of the intrusion of the Taishanmiao pluton. The ore-forming fluids belong to the NaCl-H2O system with a medium-low temperature, a low salinity, and a low density, indicating that the deposits in the area are medium-low-temperature supergene hydrothermal fluorite deposits. The chondrite-normalized REE patterns of fluorites in the area can be divided into slightly leftward, flat, and rightward types dominated by the rightward type. Moreover, the rightward chondrite-normalized REE patterns of fluorites are similar to those of the Yanshanian granites, both showing strongly negative Eu anomalies and weakly negative Ce anomalies. This finding indicates that the Yanshanian granites provide materials for the formation of fluorites. The metallogenic element F may mainly originate from the Heyu and Taishanmiao plutons, while the metallogenic element Ca partly comes from granites as surrounding rocks.
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Received: 09 August 2021
Published: 17 August 2022
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Corresponding Authors:
BAI De-Sheng
E-mail: dkeyzkt@163.com;baidh1968@163.com
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Regional geological map of Heyu-Checun area fluorite deposit
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Distribution mapof fluorite deposits in Heyu-Checun area
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序号 | 矿区名称 | 规模 | | 序号 | 矿区名称 | 规模 | 1 | 吕布沟萤石矿 | 小型 | | 18 | 马丢萤石矿 | 大型 | 2 | 顺达萤石矿 | 小型 | | 19 | 古满沟萤石矿 | 小型 | 3 | 桑树沟萤石矿 | 小型 | | 20 | 奋进萤石矿 | 小型 | 4 | 砭上萤石矿 | 中型 | | 21 | 康达萤石矿 | 小型 | 5 | 水葫芦沟萤石矿 | 小型 | | 22 | 阳桃沟萤石矿 | 大型 | 6 | 杨寺萤石矿 | 小型 | | 23 | 两叉安通威萤石矿 | 小型 | 7 | 鸡爪沟萤石矿 | 小型 | | 24 | 车村萤石矿 | 大型 | 8 | 杨山萤石矿 | 大型 | | 25 | 竹园沟萤石矿 | 中型 | 9 | 小涩沟萤石矿 | 小型 | | 26 | 龙脖凹萤石矿 | 小型 | 10 | 木植街萤石矿 | 中型 | | 27 | 中兴萤石矿 | 大型 | 11 | 隆博萤石矿 | 小型 | | 28 | 张元河南村萤石矿 | 小型 | 12 | 乱石沟萤石矿 | 小型 | | 29 | 灰菜沟萤石矿 | 小型 | 13 | 玉新萤石矿 | 小型 | | 30 | 栗扎坪萤石矿 | 小型 | 14 | 范进寺萤石矿 | 小型 | | 31 | 六合萤石矿 | 小型 | 15 | 东草沟萤石矿 | 小型 | | 32 | 陈楼萤石矿 | 大型 | 16 | 下马丢萤石矿 | 小型 | | 33 | 段家庄萤石矿 | 小型 | 17 | 枣树凹萤石矿 | 小型 | | | | |
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Thelist of fluorite deposits in Heyu-Checun area
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岩体 | 序号 | 岩性 | 测试方法 | 年龄/Ma | 误差/Ma | 数据来源 | 合 峪 岩 体 | 1 | 黑云母 | 黑云母Ar-Ar | 131.8 | 0.65 | 张宗清等[13] | 2 | 巨斑状黑云二长花岗岩 | 锆石U-Pb | 127.2 | 1.4 | 李永峰[14] | 3 | 黑云母 | 黑云母Ar-Ar | 131.8 | 0.7 | Han,et al[15] | 4 | 黑云母 | 黑云母Ar-Ar | 132.5 | 1.1 | 5 | 黑云母二长花岗岩 | 锆石U-Pb | 134.5 | 1.5 | 郭波等[16] | 6 | 黑云母二长花岗岩 | 锆石U-Pb | 135.4 | 5.4 | 高昕宇等[17] | 7 | 黑云母二长花岗岩 | 锆石U-Pb | 148.2 | 2.5 | 8 | 黑云母二长花岗岩 | 锆石U-Pb | 141.4 | 5.4 | 9 | 黑云母二长花岗岩 | 锆石U-Pb | 135.3 | 4.9 | 10 | 多斑花岗斑岩 | 锆石U-Pb | 136.1 | 1.4 | 李春艳等[18] | 11 | 大斑多斑中粗粒黑云母二长花岗岩 | 锆石U-Pb | 139.8 | 1.3 | 12 | 大斑多斑中粗粒黑云母二长花岗岩 | 锆石U-Pb | 143.5 | 1.3 | 13 | 含中斑中粒黑云母二长花岗岩 | 锆石U-Pb | 133.0 | 1.0 | 14 | 正长花岗岩 | 锆石U-Pb | 143.1 | 2.1 | 庞绪成等[11] | 15 | 正长花岗岩 | 锆石U-Pb | 144.4 | 4.0 | 16 | 细晶岩脉 | 锆石U-Pb | 128.1 | 2.9 | 17 | 细晶岩脉 | 锆石U-Pb | 130.2 | 2.7 | 18 | 花岗斑岩脉 | 锆石U-Pb | 124.7 | 2.9 | 19 | 黑云母二长花岗岩 | 锆石U-Pb | 134.0 | 3.0 | Bao,et al[19] | 20 | 黑云母二长花岗岩 | 锆石U-Pb | 144.0 | 3.0 | 太 山 庙 岩 体 | 21 | 碱长花岗岩 | 锆石U-Pb | 115.0 | 2.0 | 叶会寿等[20] | 22 | 中粗粒正长花岗岩 | 锆石U-Pb | 123.1 | 3.0 | 高昕宇[21] | 23 | 细中粒正长花岗岩 | 锆石U-Pb | 121.3 | 3.0 | 24 | 正长花岗斑岩 | 锆石U-Pb | 112.7 | 5.0 | 25 | 中粗粒钾长花岗岩 | 锆石U-Pb | 121.0 | 2.2 | 齐玥[22] | 26 | 中粗粒钾长花岗岩 | 锆石U-Pb | 116.2 | 1.3 | 27 | 中细粒钾长花岗岩 | 锆石U-Pb | 121.7 | 2.5 | 28 | 中细粒钾长花岗岩 | 锆石U-Pb | 120.0 | 2.2 | 29 | 细粒似斑状花岗岩 | 锆石U-Pb | 122.0 | 1.6 | 30 | 细粒似斑状花岗岩 | 锆石U-Pb | 122.3 | 1.5 |
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Age determination statistics of Heyu pluton
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矿区 | 成矿阶段及位置 | 压力范围/Mpa | 平均压力/Mpa | 成矿深度范围/km | 平均成矿深度/km | 陈楼萤石矿 | 第Ⅱ成矿阶段 | 6.9~24.2 | 14.7 | 0.69~2.42 | 1.47 | 第Ⅲ成矿阶段 | 7.3~20.0 | 11.7 | 0.73~2.00 | 1.17 | 马丢萤石矿 | 773m中段 | 22.4~30.4 | 25.3 | 0.75~1.03 | 0.84 | 730m中段 | 22.4~29.5 | 24.6 | 0.75~0.99 | 0.82 | 717m中段 | 22.4~29.5 | 24.3 | 0.75~0.99 | 0.81 |
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Estimation table of metallogenic pressure and metallogenic depth of fluorite deposits in Heyu-Checun area
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Normalized REE distribution pattern of Heyu granite
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Normalized REE distribution pattern of Taishanmiao granite
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Normalized REE distribution pattern of fluoritein Heyu-Checun area
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