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Content characteristics and genesis of soil selenium in important cultivated areas of Leibo County, Sichuan Province |
SHI Zhang-Liang1,2, JIN Li-Xin1,2, LIAO Chao1,2, BAO Yu-Han1,2, LIU Xiao-Bo1,2, DENG Huan1,2, XU Ke-Quan1,2 |
1.Sichuan Geological Survey, Sichuan Bureau of Geology & Mineral Resources, Chengdu 610081, China 2.Evaluation and Utilization of Strategic Rare Metals and Rare Earth Resource Key Laboratory of Sichuan Province, Sichuan Geological Survey, Chengdu 610081, China |
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Abstract Selenium is a trace element that has an important impact on human health and hence has received increasing attention in recent years. There are many factors affecting the level of selenium in the soil, and the differences in different regions are obvious. In this paper, the content, distribution and main influencing factors of selenium in the soil of this area were studied in Gumi Town, Leibo County. The results show that the selenium content in the soil of the study area is not high, mainly concentrated around 0.226×10-6. Selenium content in soil is positively correlated with organic matter, thiophilic heavy elements cadmium, mercury, lead, arsenic and zinc, but is not simply linearly correlated with pH value. In soils with different acidities and alkalinities as well as different land use patterns and parent materials, the two are significantly different. The selenium content in the soil in the survey area is mainly controlled by the parent material of the soil. The Silurian and Ordovician black shale and carbonate area in the old strata are more likely to be enriched with selenium, while the selenium content in the Triassic sandstone area in the newer strata is lower.
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Received: 26 November 2019
Published: 26 October 2020
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统计样品数 | 最小值/10-6 | 最大值/10-6 | 平均值/10-6 | 1469 | 0.030 | 1.08 | 0.226 | 统计样品数 | 标准离差 | 变异系数 | 成都经济区 平均值/10-6 | 1469 | 0.134 | 0.594 | 0.23 |
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Characteristics of total soil selenium content in the key cultivated land area of Leibo County
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Frequency distribution of selenium content in surface soil in the key cultivated land area of Leibo County
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分级含义 | 面积/km2 | 面积比例/% | 富硒无风险 | 3.89 | 18.49 | 富硒风险可控 | 16.52 | 78.48 | 富硒风险较高 | 0.64 | 3.03 |
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Statistics on the area distribution of selenium-rich soil environmental quality in key cultivated areas of Leibo County
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Spatial distribution characteristics of soil selenium in key farming areas of Leibo County
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用地类型 | 样本数 | 平均值/10-6 | 最大值/10-6 | 最小值/10-6 | 标准离差 | 变异系数 | 水田 | 278 | 0.18 | 0.719 | 0.042 | 0.085 | 0.470 | 旱地 | 718 | 0.21 | 1.04 | 0.029 | 0.118 | 0.560 | 草地 | 97 | 0.26 | 1.08 | 0.056 | 0.175 | 0.677 | 林地 | 213 | 0.32 | 0.941 | 0.047 | 0.168 | 0.518 | 园地 | 163 | 0.21 | 0.749 | 0.017 | 0.117 | 0.567 |
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Characteristics of selenium content in different land use types
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土壤类型 | 样本数 | 平均值/10-6 | 最大值/10-6 | 最小值/10-6 | 标准偏差/10-6 | 变异系数 | 有机质平均值/% | 平均海拔/m | 红壤 | 445 | 0.22 | 0.749 | 0.05 | 0.110 | 0.495 | 2.38 | 816 | 黄壤 | 835 | 0.21 | 1.08 | 0.017 | 0.136 | 0.639 | 2.55 | 1250 | 黄棕壤 | 62 | 0.33 | 0.941 | 0.064 | 0.166 | 0.502 | 4.84 | 2001 | 紫色土 | 127 | 0.27 | 0.787 | 0.073 | 0.148 | 0.553 | 3.01 | 1308 |
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Characteristics of selenium content in different soil types
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Relationship between soil pH and selenium content
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指标 | As | Cd | Cu | Hg | Mn | Mo | Se | 0.550 | 0.620 | 0.108 | 0.645 | 0.162 | 0.497 | 指标 | N | P | Pb | 有机质 | V | Zn | Se | 0.674 | 0.206 | 0.635 | 0.598 | 0.110 | 0.414 |
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Correlation coefficient table of selenium and other indicators
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The relationship between soil selenium and organic matter, sulfur-philic elements and other indicators
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地层 | 主要岩性 | 样本数 | 平均值/10-6 | 最大值/10-6 | 最小值/10-6 | 标准偏差/10-6 | 变异系数 | 三叠系 | T3 | 须家河组 | 砂岩 | 399 | 0.17 | 0.598 | 0.031 | 0.067 | 0.384 | T2 | 雷口坡组 | 白云岩 | 194 | 0.25 | 0.858 | 0.064 | 0.139 | 0.568 | T1 | 大冶组—嘉陵江组并层 | 灰岩 | 198 | 0.25 | 0.787 | 0.061 | 0.090 | 0.363 | T1 | 飞仙关组—嘉陵江组并层 | 灰岩 | 122 | 0.19 | 0.652 | 0.017 | 0.135 | 0.707 | 二叠系 | P2 | 宣威组 | 砂岩、炭质页岩 | 169 | 0.17 | 0.504 | 0.042 | 0.081 | 0.482 | P | 峨眉山玄武岩组 | 玄武岩 | 299 | 0.27 | 0.941 | 0.047 | 0.145 | 0.546 | P1 | 梁山组—阳新组并层 | 铁质页岩、灰岩 | 40 | 0.45 | 1.080 | 0.050 | 0.271 | 0.607 | 志留系 | S | 龙马溪组—回星哨组并层 | 页岩、灰岩 | 32 | 0.33 | 0.836 | 0.104 | 0.177 | 0.538 | 奥陶系 | O | 红石崖组—大箐组并层 | 页岩、白云岩 | 16 | 0.34 | 0.702 | 0.099 | 0.202 | 0.602 |
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Statistics of selenium content in different soil parent materials
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The distribution of selenium content in different soil parent materials
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The distribution of main selenium-rich strata in the study area
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