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Characteristics and influencing factors of fluorine content in soils along the Guohe River in Anhui Province |
Peng-Fei LI, Fu-Rong CHEN, Guo-Qiang DU, Chun-Jun TAO, Chao LIU, Kun LIU |
Geological Survey Institute of Anhui Province, Hefei 230001,China |
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Abstract The 0~20 cm surface soil, the horizontal profile soil and the 0~200 cm vertical profile soil samples were collected systematically to determine the content of soil fluoride and related indicators, and the distribution characteristics and influencing factors of soil fluorine content in surface soil and profile soil were studied. The results show that the fluorine content in the surface soil of the study area ranges from 448×10 -6 to 1 009×10 -6, with the average content being 685×10 -6. The distribution characteristics of fluorine content in surface soil are obviously restricted by geological and geomorphological conditions. The soil with high fluoride background (>730×10 -6) is concentrated in the sub-clay of Qhb group, and the landform is flood plain.The surface soil fluorine is positively correlated with TFe2O3 (r=0.76), Mn (r=0.79), CaO (r=0.66) and Al2O3 (r=0.59), and negatively correlated with w(SiO2)/w(Al2O3).In the vertical section, soil fluorine is mainly concentrated in 0~155 cm. Iron and manganese oxides are important factors that restrict the vertical distribution of soil fluorine.
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Received: 06 May 2019
Published: 22 April 2020
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Sampling sites in the study area
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指标 | 分析方法 | 检出限 | 报出率/% | 准确度 合格率/% | 精密度 合格率/% | 重复检验 合格率/% | F | 离子选择性电极法(ISE) | 50 | 100 | 100 | 100 | 100 | Mn | 质光谱法(ICP-AES) | 5 | 100 | 100 | 100 | 100 | SiO2 | X射线荧光光谱法(XRF) | 0.05 | 100 | 100 | 100 | 100 | Al2O3 | X射线荧光光谱法(XRF) | 0.05 | 100 | 100 | 100 | 100 | TFe2O3 | X射线荧光光谱法(XRF) | 0.05 | 100 | 100 | 100 | 100 | CaO | X射线荧光光谱法(XRF) | 0.05 | 100 | 100 | 100 | 100 | Corg | 容量法 (VOL) | 0.05 | 100 | 100 | 100 | 100 | pH | 离子选择性电极法(ISE) | 0.1 | 100 | 100 | 100 | 99.82 |
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Parameters of the sample analysis quality
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单元 | 微地貌 | 岩性 | 参数 | F | TFe2O3 | Mn | CaO | 有机质 | w(SiO2)/w(Al2O3) | pH | | | | 最小值 | 448 | 4.03 | 382 | 1.26 | 0.72 | 3.44 | 6.4 | | | | 最大值 | 1009 | 6.65 | 1003 | 7.93 | 3.05 | 5.80 | 8.7 | 全区 | | | 中位数 | 685 | 5.43 | 725 | 6.06 | 1.66 | 4.19 | 8.0 | (726件) | | | 平均值 | 685 | 5.37 | 717 | 5.69 | 1.75 | 4.31 | | | | | 标准离差 | 93.5 | 0.64 | 129.58 | 1.6 | 0.45 | 0.54 | 0.28 | | | | 变异系数 | 0.14 | 0.12 | 0.18 | 0.28 | 0.26 | 0.12 | 0.04 | 峁塘组 (Qpm) | 河间平地 (106件) | 亚黏土 | 中位数 | 591 | 4.86 | 541 | 2.72 | 1.91 | 4.72 | 7.8 | 平均值 | 601 | 4.93 | 561 | 2.99 | 1.93 | 4.73 | | 变异系数 | 0.14 | 0.11 | 0.23 | 0.52 | 0.19 | 0.12 | 0.06 | 河间洼地 (10件) | 亚黏土 | 中位数 | 605 | 5.10 | 607 | 3.75 | 1.43 | 4.52 | 8.1 | 平均值 | 643 | 5.23 | 630 | 4.16 | 1.42 | 4.39 | | 变异系数 | 0.16 | 0.09 | 0.17 | 0.33 | 0.19 | 0.08 | 0.01 | 蚌埠组 (Qhb) | 泛滥坡平地 (394件) | 亚黏土 | 中位数 | 721 | 5.81 | 792 | 6.65 | 1.71 | 3.94 | 8.0 | 平均值 | 729 | 5.73 | 785 | 6.34 | 1.83 | 4.00 | | 变异系数 | 0.11 | 0.08 | 0.12 | 0.17 | 0.25 | 0.08 | 0.02 | 泛滥微高地 (170件) | 亚砂、粉砂 | 中位数 | 637 | 4.76 | 651 | 5.83 | 1.40 | 4.78 | 8.1 | 平均值 | 641 | 4.87 | 666 | 5.85 | 1.48 | 4.69 | | 变异系数 | 0.11 | 0.11 | 0.13 | 0.13 | 0.25 | 0.10 | 0.02 | 决口扇形地 (33件) | 亚砂土 | 中位数 | 648 | 4.85 | 679 | 6.26 | 1.72 | 4.66 | 8.0 | 平均值 | 652 | 4.83 | 659 | 5.99 | 1.75 | 4.76 | 8.0 | 变异系数 | 0.09 | 0.08 | 0.11 | 0.12 | 0.19 | 0.09 | 0.02 | 河漫滩 (13件) | 亚黏土 | 中位数 | 796 | 5.63 | 709 | 5.69 | 2.33 | 3.98 | 7.8 | 平均值 | 778 | 5.70 | 745 | 5.67 | 2.24 | 4.00 | | 变异系数 | 0.06 | 0.05 | 0.11 | 0.18 | 0.09 | 0.06 | 0.02 |
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Element content parameters of surface Layer soil along the Guohe River in Anhui Province
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氟含量/10-6 | ≤400 | >400~500 | >500~550 | >550~700 | >700 | 分级 | 缺乏 | 边缘 | 适量 | 高 | 过剩 |
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Classification standard of the soil fluorine content
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Distribution pattern of surface soil components in different geological backgrounds
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指标 | F | TFe2O3 | Mn | Al2O3 | CaO | 有机质 | w(SiO2)/w(Al2O3) | pH | F | 1 | | | | | | | | TFe2O3 | 0.76** | 1 | | | | | | | Mn | 0.79** | 0.89** | 1 | | | | | | Al2O3 | 0.59** | 0.90** | 0.64** | 1 | | | | | CaO | 0.66** | 0.60** | 0.83** | 0.23 | 1 | | | | 有机质 | 0.24 | 0.37** | 0.23** | 0.39 | -0.04 | 1 | | | w(SiO2)/w(Al2O3) | -0.78** | -0.97** | -0.89** | -0.88** | -0.66** | -0.31 | 1 | | pH | 0.10 | 0.10 | 0.28 | -0.09 | 0.49** | -0.36 | -0.15 | 1 |
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Correlation between surface soil fluorine and main indicators(n=726)
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Fluorine geochemical distribution of surface soils along the Guohe River in Anhui Province
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项目 | F含量累积频率 | ≤1.5% | 1.5%~15% | 15%~25% | 25%~75% | 75%~95% | 95%~98.5% | >98.5% | 含量/10-6 | ≤510 | 510~600 | 600~640 | 640~730 | 730~825 | 825~862 | >862 | 色区 | 强低值区 | 低值区 | 低背景区 | 背景区 | 高背景区 | 高值区 | 强高值区 |
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Color division of soil fluorine geochemical
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Distribution of elements and organic matter in horizontal profile soil
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Vertical distribution of soil composition of section CP01
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Vertical distribution of soil composition of section CP02
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