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Petrogenic and metallogenic geochronology and its geological significance of the Dawangshan quartz vein type scheelite-molybdenite polymetallic deposit in central Jiangxi Province |
Qing-Kun YANG1, Xiao-Liang ZHANG2, Chen HUA1, Yu-Shuai YU3, Wan-Peng ZHOU1 |
1. State Key Laboratory of Nuclear Resources and Environment, East China University of Technology, Nanchang 330013, China 2. School of Earth Sciences and Resources, China University of Geosciences, Beijing 100083, China 3. China Geological Survey, Wuhan Center, Wuhan 430205, China |
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Abstract The Dawangshan tungsten-molybdenum polymetallic deposit in Jiangxi province is a typical quartz vein type deposit, lies in the Dawangshan-Yudu Cu-Mo-Au-Ag-Pb-Zn ore belt. The ore-bearing rock mass is characterized by multiple stages. According to the LA-ICPMS zircon U-Pb dating technique, the diagenetic age of fine-grained granite in the late stage is 145.1±0.89 Ma, which is close to the formation time of medium-grained granite formed in the early stage (147.8±1.9 Ma). Using the Re-Os isotope dating technique of molybdenite, the metallogenic age was 147.6±1.8 Ma. Indicating that the deposit was formed in the late Jurassic, It is consistent with the diagenesis and mineralization age of Yanshanian quartz vein type tungsten molybdenum polymetallic deposit in Nanling area. Re content of molybdenite has important reference value to indicate the source of mineralization materials. The Dawangshan tungsten-molybdenum polymetallic deposit is related with Yanshanian granites, the Re contents of molybdenite samples is 2 215×10 -9~10 183×10 -9, It is consistent with the characteristics of tungsten deposit associated molybdenum,which indicates that the ore-forming materials are likely to come from the crust or crust-mantle-derived ones. In combination with metallogenic geological background, the author infers that the Dawangshan deposit is associated with the subduction of the Paleo-Pacificocean plate beneath the Eurasian continent. It is proposed that the ore-forming materials were extracted by alkali metasomatism between the magma and the wall rock and then concentrated in the favourable areas.
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Received: 27 December 2018
Published: 31 May 2019
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Geotectonic location map and regional geological map of Dawangshan deposit a—tectonic position of Dawangshan deposit;b—regional geological map of Dawangshan deposit;c—geological sketch map of Dawangshan deposit
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Photos of the granite and W-Mo polymetallic ore samples in Dawangshan tungsten molybdenum polymetallic ore concentration area a—ore-bearing fine-grained granite intrudes into medium-grained granite; b—pegmatitic dikes; c—early tungsten molybdenum polymetallic ore capsule was cut by late quartz veins containing ore; d—pocket; e—sulfide ore in late quartz crystal cave; f—pyrite-chalcopyrite-wolframite-molybdenite symbiosis; g,h—wolframite-chalcopyrite-brightness molybdenum ore (reflection of single polarized light); Mlt—wolframite; Ccp—chalcopyrite; Py—pyrite; Mo—molybdenum
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Zircon cathodoluminescene(CL) images for the ore-bearing granites from the Dawangshan deposit
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U-Pb concordia diagram of zircons for porphyry from the Dawangshan deposit
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样号 | w(U) /10-6 | w(Th) /10-6 | w(Th) /w(U) | 同位素比值 | 年龄/Ma | | 1σ | | 1σ | | 1σ | | 1σ | | 1σ | | 1σ | | 1σ | | 1σ | DWS17-1-1 | 863 | 364 | 0.42 | 0.0502 | 0.00106 | 0.1575 | 0.00345 | 0.0228 | 0.00030 | 0.0074 | 0.00018 | 204.2 | 49 | 148.5 | 3 | 145.4 | 2 | 149.9 | 4 | DWS17-1-2 | 1463 | 506 | 0.35 | 0.0485 | 0.00096 | 0.1528 | 0.00314 | 0.0228 | 0.00027 | 0.0080 | 0.00016 | 124.2 | 47 | 144.4 | 3 | 145.6 | 2 | 160.3 | 3 | DWS17-1-3 | 331 | 192 | 0.58 | 0.0487 | 0.00200 | 0.1530 | 0.00637 | 0.0229 | 0.00039 | 0.0077 | 0.00022 | 135.2 | 97 | 144.6 | 6 | 146.1 | 2 | 154.6 | 4 | DWS17-1-4 | 3534 | 900 | 0.25 | 0.0510 | 0.00128 | 0.1596 | 0.00572 | 0.0228 | 0.00064 | 0.0080 | 0.00025 | 241.3 | 58 | 150.3 | 5 | 145.3 | 4 | 160.4 | 5 | DWS17-1-5 | 416 | 225 | 0.54 | 0.0495 | 0.00163 | 0.1542 | 0.00507 | 0.0227 | 0.00037 | 0.0087 | 0.00028 | 169.5 | 77 | 145.6 | 4 | 144.6 | 2 | 174.1 | 6 | DWS17-1-6 | 235 | 108 | 0.46 | 0.0487 | 0.00163 | 0.1525 | 0.00514 | 0.0228 | 0.00032 | 0.0078 | 0.00022 | 132.0 | 79 | 144.1 | 5 | 145.1 | 2 | 157.9 | 4 | DWS17-1-7 | 309 | 212 | 0.68 | 0.0485 | 0.00145 | 0.1512 | 0.00452 | 0.0227 | 0.00031 | 0.0084 | 0.00023 | 124.0 | 70 | 143.0 | 4 | 144.6 | 2 | 168.9 | 5 | DWS17-1-8 | 197 | 100 | 0.51 | 0.0506 | 0.00155 | 0.1592 | 0.00508 | 0.0228 | 0.00031 | 0.0074 | 0.00027 | 221.6 | 71 | 150.0 | 4 | 145.5 | 2 | 149.4 | 5 | DWS17-1-9 | 595 | 277 | 0.47 | 0.0507 | 0.00189 | 0.1587 | 0.00734 | 0.0228 | 0.00056 | 0.0072 | 0.00042 | 225.6 | 86 | 149.6 | 6 | 145.5 | 4 | 145.1 | 8 | DWS17-1-10 | 543 | 168 | 0.31 | 0.0489 | 0.00148 | 0.1540 | 0.00482 | 0.0229 | 0.00036 | 0.0082 | 0.00026 | 144.2 | 71 | 145.5 | 4 | 146.1 | 2 | 166.0 | 5 | DWS17-1-11 | 332 | 176 | 0.53 | 0.0490 | 0.00225 | 0.1539 | 0.00634 | 0.0230 | 0.00057 | 0.0086 | 0.00027 | 150.2 | 108 | 145.4 | 6 | 146.7 | 4 | 173.2 | 5 | DWS17-1-12 | 514 | 235 | 0.46 | 0.0485 | 0.00091 | 0.1512 | 0.00308 | 0.0226 | 0.00029 | 0.0077 | 0.00015 | 126.1 | 44 | 143.0 | 3 | 143.8 | 2 | 155.1 | 3 | DWS17-1-13 | 328 | 168 | 0.51 | 0.0490 | 0.00137 | 0.1558 | 0.00482 | 0.0229 | 0.00032 | 0.0084 | 0.00020 | 146.7 | 66 | 147.0 | 4 | 146.2 | 2 | 168.6 | 4 | DWS17-1-14 | 687 | 304 | 0.44 | 0.0497 | 0.00129 | 0.1568 | 0.00397 | 0.0230 | 0.00034 | 0.0076 | 0.00018 | 182.9 | 61 | 147.9 | 3 | 146.4 | 2 | 153.6 | 4 | DWS17-1-15 | 209 | 156 | 0.75 | 0.0486 | 0.00198 | 0.1522 | 0.00633 | 0.0229 | 0.00039 | 0.0080 | 0.00027 | 128.5 | 96 | 143.9 | 6 | 145.9 | 2 | 161.9 | 5 | DWS17-1-16 | 266 | 140 | 0.53 | 0.0500 | 0.00165 | 0.1557 | 0.00493 | 0.0228 | 0.00031 | 0.0077 | 0.00020 | 195.9 | 77 | 146.9 | 4 | 145.2 | 2 | 154.8 | 4 | DWS17-1-17 | 360 | 164 | 0.46 | 0.0493 | 0.00154 | 0.1518 | 0.00480 | 0.0224 | 0.00038 | 0.0082 | 0.00026 | 161.1 | 73 | 143.5 | 4 | 142.9 | 2 | 164.4 | 5 | DWS17-1-18 | 187 | 94 | 0.50 | 0.0511 | 0.00231 | 0.1565 | 0.00615 | 0.0227 | 0.00064 | 0.0084 | 0.00037 | 246.9 | 104 | 147.6 | 5 | 144.8 | 4 | 169.0 | 7 | DWS17-1-19 | 405 | 205 | 0.51 | 0.0506 | 0.00177 | 0.1559 | 0.00551 | 0.0224 | 0.00031 | 0.0074 | 0.00024 | 222.0 | 81 | 147.1 | 5 | 142.7 | 2 | 148.1 | 5 | DWS17-1-20 | 291 | 183 | 0.63 | 0.0498 | 0.00182 | 0.1559 | 0.00550 | 0.0229 | 0.00032 | 0.0079 | 0.00022 | 184.2 | 85 | 147.2 | 5 | 145.9 | 2 | 159.1 | 4 | DWS17-1-21 | 493 | 221 | 0.45 | 0.0494 | 0.00141 | 0.1537 | 0.00386 | 0.0228 | 0.00038 | 0.0079 | 0.00022 | 168.8 | 67 | 145.1 | 3 | 145.2 | 2 | 158.5 | 4 | DWS17-1-22 | 379 | 169 | 0.45 | 0.0505 | 0.00156 | 0.1569 | 0.00442 | 0.0228 | 0.00036 | 0.0079 | 0.00025 | 218.8 | 72 | 148.0 | 4 | 145.4 | 2 | 158.4 | 5 | DWS17-1-23 | 378 | 184 | 0.49 | 0.0486 | 0.00152 | 0.1519 | 0.00466 | 0.0228 | 0.00036 | 0.0075 | 0.00025 | 130.0 | 74 | 143.6 | 4 | 145.0 | 2 | 151.2 | 5 | DWS17-1-24 | 210 | 107 | 0.51 | 0.0493 | 0.00202 | 0.1535 | 0.00635 | 0.0227 | 0.00035 | 0.0075 | 0.00027 | 160.7 | 96 | 145.0 | 6 | 144.6 | 2 | 151.1 | 5 |
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Results of zircon LA-ICP-MS U-Pb ages for ore-bearing granites from the Dawangshan deposit
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样品号 | w(Re)/10-9 | w(Os)/10-9 | w(187Re)/10-9 | w(187Os)/10-9 | 模式年龄/Ma | 测定值 | 不确定度 | 测定值 | 不确定度 | 测定值 | 不确定度 | 测定值 | 不确定度 | 测定值 | 不确定度 | DWS17-2-1 | 2215 | 18 | 0.0286 | 0.0122 | 1392 | 11 | 3.45 | 0.02 | 148.5 | 2.1 | DWS17-2-2 | 7003 | 54 | 0.0003 | 0.0159 | 4401 | 34 | 10.82 | 0.08 | 147.4 | 2.1 | DWS17-2-3 | 6534 | 65 | 0.0003 | 0.0283 | 4107 | 41 | 10.11 | 0.07 | 147.6 | 2.3 | DWS17-2-4 | 6290 | 55 | 0.0003 | 0.0220 | 3953 | 35 | 9.72 | 0.07 | 147.4 | 2.2 | DWS17-2-5 | 10183 | 86 | 0.0003 | 0.0442 | 6400 | 54 | 15.92 | 0.11 | 149.1 | 2.2 | DWS17-2-6 | 2927 | 27 | 0.0001 | 0.0251 | 1840 | 17 | 4.46 | 0.03 | 145.3 | 2.3 |
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Re-Os isotopic data for molybdenite from the Dawangshan deposit
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Isochron diagram and model age weighted diagram of Re-Os isotope for molybdenite form the Dawangshan deposit
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产地 | 矿床名称 | 成因类型(岩体名称) | 成矿(成岩)年龄值/Ma | 测年方法 | 数据来源 | 赣南 | 淘锡坑 | 石英脉型 中粒似斑状黑云母花岗岩 | 154.4±3.8 158.7±3.9、157.6±3.5 | Re-Os SHRIMP | 陈郑辉等[10] 郭春丽等[11] | 赣南 | 摇篮寨 | 石英脉型 | 155.8±2.8 | Re-Os | 丰成友等[12] | 赣南 | 樟斗 | 石英脉型 | 149.1±7.1 | Re-Os | 丰成友等[12] | 赣南 | 茅坪 | 石英脉型 | 158.2~141.4 | Re-Os | 曾载淋等[13] | 赣南 | 牛岭 | 石英脉型 | 154.9±4.1 | Re-Os | 丰成友等[12] | 赣南 | 木梓园 | 石英脉型 中细粒含黑云母花岗岩 | 151.1±8.5 153.3±1.9 | Re-Os 单颗粒锆石U-Pb | 张文兰等[14] 张文兰等[14] | 粤北 | 师姑山 | 石英脉型 | 154.2±2.7 | Re-Os | 付建明等[15] | 粤北 | 石人嶂 | 石英脉型 | 159.1±2.2 | Re-Os | 付建明等[15] | 粤北 | 红岭 | 石英脉型 | 159.1±1.5 | Re-Os | 王小飞等[16] | 闽西 | 行洛坑 | 石英脉型 | 156.3±4.8 | Re-Os | 张家菁等[17] | 赣中 | 浒坑 | 石英脉型 | 149.1±2.0~150.7±3.7 | Re-Os | Liu et al[18] | 赣中 | 下桐岭 | 石英脉型 | 152±3.3 | Re-Os | 李光来等[19] | 赣中 | 麻鸡嶂 | 石英脉型 碱长花岗岩 | 161.3~157.1 152.5±1.3 | Re-Os LA-ICPMS | 宋凯林等[20] 石连成等[21] | 赣中 | 大王山 | 细粒碱长花岗岩 石英脉型 | 145.1±0.89 147.6±1.8 | LA-ICPMS Re-Os | 本文 本文 |
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