地表土壤微细粒测量中微量元素和同位素对福建罗卜岭隐伏铜钼矿床的示踪与判别

doi:10.11720/wtyht.2022.2585

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Abstract

This paper collected surface soil above the known concealed deposit the Luoboling porphyry-type copper-molybdenum deposit and acquired samples of ore and surrounding rocks from typical boreholes of the deposit. Then, it analyzed the changes in the contents of six trace elements (Cu, Mo, Ba, Pb, Zn, and V) and the isotopic composition of S and Pb, aiming to verify the ore prospecting effects of the measurement technology of mobile forms of metals in soil and full analysis of fine-grained soil in concealed deposits and to identify the sources of surface geochemical anomalies according to the isotopic composition of Pb and S. The study results are as follows. The total analysis of fine-grained soil showed the best effects in indicating deep ore bodies in the Luoboling deposit, and the areas with high contents of Cu, Ba, and Mo correlated strongly with the distribution of deeply concealed ore bodies. Both the mobile forms of metals in the soil and the total analysis of fine-grained soil showed that it is quite possible that concealed ore bodies occur below sampling points No.14 and 15. Meanwhile, the changes in the contents of V, Pb, and Zn obtained using both methods can accurately delineate the scopes of mineralized rock masses close to the ground surface. However, most of the total sulfur isotopic composition in the soil of anomaly zones inherits from the non-ore-hosting surrounding rocks and masked the contribution from the deep ore bodies. Consequently, sulfur isotopes showed poor effects in indicating the sources of anomalies in the surface soil in the Luoboling deposit. Therefore, it is more reasonable to measure the sulfur isotopic composition according to the mobile forms of metals in the soil. In contrast, the total Pb isotopes in the soil of the anomaly zones inherit the characteristics of the Pb isotopes of deep ore bodies. This serves as direct evidence of full analysis of fine-grained soil in the mineral exploration of coverage areas.Moreover, the changes in the ²⁰⁶Pb/²⁰⁴Pb ratio in the full analysis of surface fine-grained soil correlated strongly with the distribution of underlying concealed ore bodies and thereby can effectively indicate the deep concealed ore bodies.

Key words： Luoboling copper-molybdenum deposit lead and sulfur isotopes trace elements fine particle soil survey ore prospecting of coverage areas

Received: 25 December 2020 Published: 25 February 2022

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Corresponding Authors: LIU Xue-Min E-mail: 448287250@qq.com;451245437@qq.com

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	Jian-Ting LI
	Xue-Min LIU
	Xue-Qiu WANG
	Zhi-Xuan HAN
	Yao JANG

Cite this article:

Jian-Ting LI,Xue-Min LIU,Xue-Qiu WANG, et al. Tracing and identification of concealed Luoboling copper-molybdenum deposit in Fujian Province using trace elements and isotopes in fine-grained surface soils[J]. Geophysical and Geochemical Exploration, 2022, 46(1): 32-45.

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https://www.wutanyuhuatan.com/EN/10.11720/wtyht.2022.2585 OR https://www.wutanyuhuatan.com/EN/Y2022/V46/I1/32

22])
1—early Cretaceous Luoboling granodiorite porphyry;2—early Cretaceous Sifang granodiorite; 3—early Cretaceous Shimaoshan volcanic rocks;4—Quaternary alluvial sediments;5—late Jurassic Caixi monzogranite pluton;6—middle Jurassic Zijinshan granite batholith;7—Cretaceous dacitic porphyries;8—Cretaceous cryptoexplosive breccia pipes;9—early Cretaceous Lindi clasitic sediments;10—late Devonian clasitic sediments (Tianwadong & Taozikeng formations);11—Neoproterozoic Louziba metamorphosed clasitic sediments;12—fault;13—section view of exploration line 264;14—ore deposit;15—mineralization alteration zone (K-Phl: weakly potassium-sericitization alteration zone, Chl-Phl: weakly chlorogenic-sericitization alteration zone, Kl-Phy: kaolinitization-pyrite sericitization, Ms-Di-Alu: dolomitization-kazitritization-alum petrochemistry);16—the study area;17—soil sampling points;18—drill hole
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Geological schematic diagram (a) of Zijinshan ore field in Fujian Province, geological schematic diagram (b) of Luoboling mining area (modified from Zhong J,et al.^[22])
1—early Cretaceous Luoboling granodiorite porphyry;2—early Cretaceous Sifang granodiorite; 3—early Cretaceous Shimaoshan volcanic rocks;4—Quaternary alluvial sediments;5—late Jurassic Caixi monzogranite pluton;6—middle Jurassic Zijinshan granite batholith;7—Cretaceous dacitic porphyries;8—Cretaceous cryptoexplosive breccia pipes;9—early Cretaceous Lindi clasitic sediments;10—late Devonian clasitic sediments (Tianwadong & Taozikeng formations);11—Neoproterozoic Louziba metamorphosed clasitic sediments;12—fault;13—section view of exploration line 264;14—ore deposit;15—mineralization alteration zone (K-Phl: weakly potassium-sericitization alteration zone, Chl-Phl: weakly chlorogenic-sericitization alteration zone, Kl-Phy: kaolinitization-pyrite sericitization, Ms-Di-Alu: dolomitization-kazitritization-alum petrochemistry);16—the study area;17—soil sampling points;18—drill hole

Analysis methods of sampling media

Statistical parameters of 6 trace elements in fine soils of the exploration line 264 in Luoboling Cu-Mo deposit area (n=15)

34])
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Line graphs of six trace elements’ concentration in the fine grained soils of the 264 exploration line in the Luoboling ore area (modified from Zhao C,et al^[34])

Statistical parameters of active states for 6 trace elements in fine soils of 264 exploration line in Luoboling Cu-Mo mining area (n=15)

Line diagrams of active states for 6 trace elements in fine soils of 264 exploration line in Luoboling Cu-Mo mining area

Sulfur isotopic data of fine-grained soil, ore and wall rock samples in Luoboling Cu-Mo mining area (n=39)

Sulfur isotopic composition diagrams of ores, rocks, soil background and soil anomalies in the Luoboling Cu-Mo mining area

P values of variance analysis of sulfur isotope data of different media in Luoboling mining area

Sulfur isotope distribution of total soil fine particles along exploration line 264 of Luoboling mining area

	样品编号	点性	²⁰⁸Pb/²⁰⁴Pb	误差	²⁰⁷Pb/²⁰⁴Pb	误差	²⁰⁶Pb/²⁰⁴Pb	误差
	264-1	背景	38.799	0.006	15.655	0.002	18.555	0.003
	264-2	背景	38.787	0.003	15.64	0.001	18.578	0.001
	264-3	背景	38.805	0.003	15.639	0.001	18.582	0.002
	264-4	背景	38.815	0.004	15.649	0.002	18.611	0.002
	264-5	背景	38.846	0.003	15.661	0.001	18.645	0.001
	264-6	异常	38.804	0.003	15.651	0.001	18.607	0.001
	264-7	异常	38.694	0.003	15.626	0.001	18.481	0.001
土壤	264-8	异常	38.788	0.003	15.655	0.001	18.529	0.002
	264-9	异常	38.751	0.003	15.646	0.001	18.521	0.001
	264-10	异常	38.773	0.005	15.651	0.002	18.492	0.002
	264-11	异常	38.694	0.004	15.627	0.002	18.493	0.002
	264-12	异常	38.754	0.003	15.637	0.001	18.508	0.001
	264-13	异常	38.728	0.004	15.635	0.001	18.48	0.001
	264-14	异常	38.774	0.005	15.636	0.002	18.495	0.002
	264-15	异常	38.773	0.003	15.642	0.001	18.54	0.002
	IX04-7	黄铁矿	38.767	0.007	15.634	0.008	18.509	0.008
	IX04-8	黄铁矿	38.951	0.007	15.595	0.003	18.537	0.003
	IX04-10	黄铁矿	38.899	0.004	15.629	0.001	18.491	0.002
	VI03-10	黄铁矿	39.067	0.007	15.643	0.003	18.764	0.003
	VII03-7	黄铁矿	39.215	0.009	15.618	0.003	18.617	0.004
	VII03-8	黄铁矿	38.864	0.008	15.622	0.003	18.634	0.004
	M1^#	辉钼矿	38.741	0.001	15.655	0.001	18.479	0.001
	M4^#	辉钼矿	38.732	0.011	15.666	0.004	18.48	0.005
	M5^#	辉钼矿	38.751	0.001	15.667	0.001	18.455	0.002
	Py5^#	黄铁矿	38.67	0.013	15.666	0.005	18.493	0.006
	Py8^#	黄铁矿	38.749	0.007	15.667	0.003	18.417	0.004
	Py9^#	黄铁矿	38.752	0.003	15.661	0.001	18.486	0.002
矿石	Py10^#	黄铁矿	38.788	0.003	15.668	0.001	18.476	0.002
	Py11^#	黄铁矿	38.799	0.001	15.67	0.001	18.491	0.001
	Py18^#	黄铁矿	38.773	0.004	15.668	0.002	18.453	0.002
	Py20^#	黄铁矿	38.736	0.001	15.655	0.001	18.473	0.001
	Py23^#	黄铁矿	38.775	0.003	15.658	0.002	18.469	0.002
	Py32^#	黄铁矿	38.743	0.001	15.654	0.001	18.482	0.001
	Py33^#	黄铁矿	38.812	0.007	15.663	0.003	18.502	0.004
	Py34^#	黄铁矿	38.838	0.007	15.674	0.003	18.503	0.004
	Py35^#	黄铁矿	38.674	0.002	15.644	0.001	18.426	0.001
	Py36^#	黄铁矿	38.772	0.002	15.66	0.001	18.503	0.001
	Py37^#	黄铁矿	38.815	0.005	15.66	0.002	18.505	0.002
	Py39^#	黄铁矿	38.811	0.008	15.67	0.003	18.498	0.004
	Py40^#	黄铁矿	38.719	0.002	15.65	0.001	18.456	0.001
	IX04-20	非赋矿岩体	39.358	0.004	15.659	0.001	19.243	0.002
	VI03-4	非赋矿岩体	39.854	0.004	15.709	0.002	19.86	0.002
	VI03-20	非赋矿岩体	39.463	0.006	15.668	0.002	19.349	0.003
	VII03-15	非赋矿岩体	39.025	0.003	15.647	0.001	18.936	0.001
	VII03-17	非赋矿岩体	39.352	0.004	15.695	0.001	19.253	0.002
围岩	ZK4012-1^#	非赋矿岩体	38.721	0.001	15.647	0.001	18.575	0.001
	16-308^#	非赋矿岩体	38.823	0.001	15.665	0.001	18.525	0.001
	ZL-1-4^#	非赋矿岩体	38.777	0.003	15.654	0.001	18.538	0.001
	IX-01-3^#	非赋矿岩体	38.864	0.002	15.648	0.001	18.634	0.001
	IX01-4^#	非赋矿岩体	38.826	0.001	15.654	0.001	18.589	0.001
	IX01-7^#	非赋矿岩体	38.785	0.001	15.643	0.001	18.565	0.001
	IX01-10^#	非赋矿岩体	38.803	0.002	15.652	0.001	18.627	0.001

Lead isotopic data of fine-grained soil, ore and wall rock samples in Luoboling Cu-Mo mining area (n=52)

²⁰⁸Pb/²⁰⁴Pb vs.²⁰⁶Pb/²⁰⁴Pb(a)、²⁰⁷Pb/²⁰⁴Pb vs.²⁰⁶Pb/²⁰⁴Pb(b) composition diagrams of ores, wall rocks, soil background and soil anomalies in the Luoboling Cu-Mo mining area

P values of variance analysis of lead isotope data of different media in Luoboling mining area

Diagram of ²⁰⁷Pb/²⁰⁴Pb vs.²⁰⁶Pb/²⁰⁴Pb for various media in Luoboing mining area

Lead isotope distribution of total soil fine particles along exploration line 264 of Luoboling mining area

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