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Characteristics and genesis of selenium-rich soil in Wuping area, Fujian Province |
WU Xing-Sheng( ) |
No.295 Geological Party of Fujian Nuclear Industry, Longyan 364000, China |
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Abstract Based on the data of soil element content obtained from agricultural geological survey in Wuping County, Fujian Province, the authors studied the distribution characteristics of soil selenium content and its controlling factors. According to the result obtained, the average value of selenium content in the study area is 0.25×10-6, the high value area of soil selenium is mainly distributed in the south and east of the investigation area, and the average value of selenium content is 0.42×10-6, reaching the standard of selenium enrichment; the selenium content of the soil in the study area is mainly controlled by the geological background, and the content of selenium in the Carboniferous and Permiancarbonate strata and coal-bearing strata is relatively high The average selenium content of marine sedimentary rock area is the highest, reaching 0.34×10-6. The average values of selenium content in pyroclastic rock, granite area and metamorphic rock area are similar, being 0.25×10-6 and 0.24×10-6, respectively. Soil selenium content in tea garden (0.57×10-6) and orchard (0.40×10-6) is higher than that in paddy field (0.25×10-6). Soil physical and chemical properties have an important impact on selenium content, which shows that soil selenium content has significant correlation with soil pH, organic matter and iron oxide.
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Received: 28 August 2020
Published: 27 July 2021
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样品数 | 剔除离群样品后统计值(平均值±3倍标准差) | 全国丰度[4]/10-6 | k值 | 最大值/10-6 | 最小值/10-6 | 平均值/10-6 | 几何平均值/10-6 | 中值/10-6 | 2906 | 0.8 | 0.06 | 0.25 | 0.23 | 0.23 | 0.29 | 0.79 |
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Characteristics of soil total selenium content in Wuping County
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The distribution of selenium content in soil
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评价元素 | 平均值/10-6 | 中位数/10-6 | 最大值/10-6 | 最小值/10-6 | 标准离差 | 变异系数 | 全国丰度[6]/10-6 | As | 2.62 | 1.7 | 41.3 | 0.35 | 3.09 | 1.18 | 10 | Cd | 0.18 | 0.15 | 2 | 0.01 | 0.13 | 0.7 | 0.09 | Hg | 0.189 | 0.150 | 5.188 | 0.011 | 0.175 | 0.92 | 0.04 | Pb | 50.92 | 47.1 | 270 | 12.7 | 20.52 | 0.4 | 23 | Cr | 28.74 | 20.6 | 243 | 3.2 | 23 | 0.8 | 65 | Ni | 10.91 | 8.5 | 86.5 | 1.7 | 7.91 | 0.73 | 26 |
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Characteristic values of soil heavy metal content in Wuping County
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评价区 | 一等(清洁) 比例/% | 二等(尚清洁) 比例/% | 三等(轻度污染) 比例/% | 四等(中度污染) 比例/% | 五等(重度污染) 比例/% | As | 99.89 | 0.11 | 0 | 0 | 0 | Cd | 89.74 | 9.05 | 0.69 | 0.41 | 0.1 | Hg | 87.99 | 10.26 | 1.32 | 0.24 | 0.19 | Pb | 99.97 | 0.03 | 0 | 0 | 0 | Cr | 100 | 0 | 0 | 0 | 0 | Ni | 99.05 | 0.94 | 0.01 | 0 | 0 |
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Proportion of soil heavy metal environmental quality grade in Wuping County
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Geology and distribution of clean selenium rich soil in Wuping County
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成土母质 | 样品数 | 统计样品 | w(Se)/10-6 | 标准离差 | 变异系数/% | 最大值 | 最小值 | 平均值 | 花岗岩 | 1566 | 1556 | 0.63 | 0.06 | 0.24 | 0.08 | 38.88 | 变质岩 | 577 | 573 | 0.71 | 0.07 | 0.23 | 0.1 | 45.65 | 海相沉积岩 | 635 | 635 | 1.3 | 0.076 | 0.34 | 0.21 | 61.94 | 火山碎屑岩 | 182 | 181 | 0.52 | 0.12 | 0.25 | 0.07 | 26.02 |
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Statistical values of soil selenium content in different parent material areas of Wuping County
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土地利用现状 | 样品数 | 均值/10-6 | 中值/10-6 | 极大值/10-6 | 极小值/10-6 | 标准离差 | 变异系数 | 茶园 | 34 | 0.57 | 0.49 | 1.20 | 0.29 | 0.26 | 0.45 | 果园 | 158 | 0.40 | 0.39 | 0.90 | 0.08 | 0.18 | 0.45 | 旱地 | 371 | 0.27 | 0.24 | 1.30 | 0.08 | 0.15 | 0.48 | 水田 | 2377 | 0.25 | 0.23 | 1.30 | 0.06 | 0.12 | 0.55 |
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Statistical values of soil selenium content in different land use areas of Wuping County
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Scatter plot of soil pH and Se content
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Scatter plot of TFe2O3 and Se contents in soil
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Scatter plot of soil organic matter content and Se content
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元素 | N | P | K | S | CaO | MgO | B | Mo | Mn | 相关系数 | 0.163 | 0.077 | 0.014 | 0.127 | 0.058 | 0.046 | 0.227 | 0.200 | 0.154 | 元素 | Cl | Zn | Cu | Hg | Cd | Pb | As | Cr | Ni | 相关系数 | 0.003 | 0.146 | 0.158 | 0.008 | 0.158 | 0.011 | 0.333 | 0.440 | 0.324 |
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Statistical table of correlation between selenium and other elements (n=292)
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