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Assessment of heavy metal pollution and potential ecological risks of soils in Zhenxiong County,Yunnan Province |
Ya-Long ZHOU1,2, Zhi-Juan GUO1,2, Cheng-Wen WANG1,2, Jie CHEN3, Min PENG1,2, Hang-Xin CHENG1,2 |
1. Institute of Geophysical and Geochemical Exploration, CAGS, Langfang 065000, China 2. Key Laboratory of Geochemical Cycling of Carbon and Mercury in the Earth's Critical Zone,CAGS, Langfang 065000, China 3. Yunnan Institute of Geological Survey,Kunming 650216, China |
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Abstract Based on the current evaluation standards of soil environmental quality and food safety, the authors used the single factor index method, Nemero composite index method and Hakanson potential ecological hazard index method to carry out soil heavy metal pollution and potential ecological risk assessment so as to find out the environmental risk level and spatial distribution characteristics of soil heavy metal pollution in the study area. The results of Nemero composite index evaluation indicate that high pollution occurs in the study area, and the proportion of slight pollution , moderate pollution and high pollution is respectively 39.03%, 16.62% and 28.57%. However, the potential ecological risk of Cu, Hg, As, Ni, Pb, Cr, Zn is low in soil in eight heavy metals, while the level of risk of Cd is higher, and the proportion of the samples with low, medium, slight, high, seriously potential risk is 17.71%, 17.71%, 22.77%, 12.31% and 8.00%, with the average of potential ecological harm index ( )being 118.24. The sites of high and higher potential ecological hazard of Cd in the soil are mainly located in the Lower Permian stratigraphic unit. Meanwhile, the heavy metal evaluation of 45 corn seeds shows that only one corn seed has excessive Cd content, and there is no obvious correlation between the content of Cd in corn seeds and the corresponding crop root soil. The high content of Cd seems mainly affected by geological background, but has no influence on corn seeds in the study area,and the risk of the absorption and enrichment of Cd by crops is higher with the increase of the soluble Cd content in a highly acidic soil environment.
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Received: 15 April 2019
Published: 28 November 2019
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指标 | 一等 | 二等 | 三等 | 四等 | 五等 | 单因子污染指数 | Pi≤1 | 1﹤Pi≤2 | 2﹤Pi≤3 | 3﹤Pi≤5 | Pi>5 | 描述 | 清洁 | 轻微污染 | 轻度污染 | 中度污染 | 重度污染 | 内梅罗综合指数 | P综≤0.7 | 0.7﹤P综≤1 | 1﹤P综≤2 | 2﹤P综≤3 | P综>3 | 描述 | 清洁 | 尚清洁 | 轻度污染 | 中度污染 | 重度污染 | 潜在生态危害指数 | RI﹤150 | 150≤RI﹤300 | 300≤RI﹤600 | RI≥600 | | 描述 | 低 | 中 | 较高 | 高 | | 颜色 | | | | | | R:G:B | 0:176:80 | 146:208:80 | 255:255:0 | 255:192:0 | 255:0:0 |
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Classification and expression of heavy metal environmental quality in soil
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评价 | 指标 | 一等 | 二等 | 三等 | 四等 | 五等 | 单因子污染评价 | Pi | Pi≤1 | 1﹤Pi≤2 | 2﹤Pi≤3 | 3﹤Pi≤5 | Pi>5 | | 描述 | 清洁 | 轻微污染 | 轻度污染 | 中度污染 | 重度污染 | | As | 98.46 | 1.49 | 0.04 | 0 | 0 | | Cd | 8.97 | 31.12 | 22.68 | 15.34 | 21.89 | | Cr | 78.42 | 21.14 | 0.44 | 0 | 0 | | Cu | 69.76 | 16.22 | 7.43 | 6.37 | 0.22 | | Hg | 99.91 | 0.04 | 0 | 0 | 0.04 | | Ni | 81.67 | 17.67 | 0.44 | 0.18 | 0.04 | | Pb | 95.25 | 3.34 | 0.70 | 0.44 | 0.26 | | Zn | 93.58 | 5.45 | 0.62 | 0.31 | 0.04 | 内梅罗综合评价 | P综 | P综≤0.7 | 0.7﹤P综≤1 | 1﹤P综≤2 | 2﹤P综≤3 | P综>3 | | 描述 | 清洁 | 尚清洁 | 轻度污染 | 中度污染 | 重度污染 | | P综 | 4.92 | 10.86 | 39.03 | 16.62 | 28.57 | 潜在生态危害评价 | RI | RI﹤150 | 150≤RI﹤300 | 300≤RI﹤600 | RI≥600 | | | 描述 | 低 | 中 | 较高 | 高 | | | RI | 72.75 | 16.40 | 9.63 | 1.23 | |
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Statistics on the number of samples of geochemical grade evaluation of heavy metal elements in the study area %
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Single factor pollution index evaluation map of Cd in soil in study area
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Box plot of Cd content of soil heavy metal of different geological units in the survey area
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Evaluation map of nemero composite index of soil in study area
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指标等级 | 一等 | 二等 | 三等 | 四等 | 五等 | | 特征值 | 危害程度 | 低 | 中 | 较高 | 高 | 严重 | 平均值 | 最大值 | 最小值 | 中位数 | 指数 | <40 | 40≤<80 | 80≤<160 | 160≤<320 | ≥320 | As | 100.00 | 0 | 0 | 0 | 0 | | 3.92 | 21.17 | 0.40 | 3.42 | Cd | 17.71 | 39.21 | 22.77 | 12.31 | 8.00 | | 118.24 | 2515.00 | 5.90 | 70.30 | Cr | 100.00 | 0 | 0 | 0 | 0 | | 1.55 | 5.69 | 0.51 | 1.35 | Cu | 100.00 | 0 | 0 | 0 | 0 | | 5.37 | 27.80 | 0.74 | 3.51 | Hg | 99.91 | 0.09 | 0 | 0 | 0 | | 4.79 | 227.79 | 0.49 | 4.16 | Ni | 100.00 | 0 | 0 | 0 | 0 | | 3.27 | 37.17 | 0.33 | 2.60 | Pb | 100.00 | 0.09 | 0 | 0 | 0 | | 3.09 | 401.91 | 0.49 | 2.60 | Zn | 100.00 | 0.04 | 0 | 0 | 0 | | 0.74 | 250.63 | 0.12 | 0.56 |
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Statistics on the number of samples of potential ecological hazard index of single factor of soil heavy metal elements%
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Evaluation map of soil potential ecological hazard index in study area
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元素 | 植物籽实重金属含量/10-6 | 富集系数/% | GB2762-2017 上限值/10-6 | 超上限值 样品数 | 最大值 | 最小值 | 平均值 | 中位数 | 最大值 | 最小值 | 平均值 | 中位数 | As | 0.029 | 0.015 | 0.020 | 0.019 | 0.461 | 0.067 | 0.185 | 0.182 | 0.5 | 0 | Cr | 0.175 | 0.092 | 0.103 | 0.099 | 0.198 | 0.037 | 0.096 | 0.096 | 1 | 0 | Cd | 0.189 | 0.006 | 0.022 | 0.015 | 29.844 | 0.388 | 2.867 | 1.424 | 0.1 | 1 | Cu | 3.646 | 1.444 | 2.698 | 2.756 | 15.205 | 1.351 | 6.190 | 6.007 | | | Hg | 0.004 | 0.001 | 0.002 | 0.002 | 5.559 | 0.137 | 1.361 | 1.083 | 0.02 | 0 | Ni | 0.395 | 0.070 | 0.154 | 0.134 | 1.363 | 0.086 | 0.360 | 0.297 | 1 | 0 | Pb | 0.063 | 0.032 | 0.042 | 0.040 | 0.198 | 0.010 | 0.092 | 0.086 | 0.2 | 0 | Zn | 32.754 | 14.782 | 21.322 | 21.008 | 68.137 | 2.034 | 16.759 | 14.410 | | |
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Statistical table of analysis results of corn seed samples in study area
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Evaluation map of Cd of heavy metal in corn seed samples in study area
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相关性分析 | As | Cd | Cr | Cu | Hg | Ni | Pb | Zn | Se | Pearson相关 | 相关性 | 0.169 | 0.034 | 0.031 | -0.014 | -0.243 | -0.097 | 0.1 | 0.445** | 0.389** | | | | | | | | | | 显著性(双侧) | 0.268 | 0.823 | 0.841 | 0.926 | 0.107 | 0.527 | 0.513 | 0.002 | 0.008 | Spearman相关 | 相关系数 | -0.008 | 0.137 | 0.062 | -0.013 | -0.107 | -0.099 | 0.195 | 0.042 | 0.055 | | | | | | | | | | Sig.(双侧) | 0.959 | 0.37 | 0.684 | 0.931 | 0.485 | 0.519 | 0.2 | 0.784 | 0.72 | 偏相关 | 相关性 | 0.168 | 0.022 | 0.044 | -0.004 | -0.236 | -0.143 | 0.099 | 0.431 | 0.383 | | | | | | | | | | 显著性(双侧) | 0.275 | 0.885 | 0.776 | 0.978 | 0.123 | 0.355 | 0.522 | 0.004 | 0.01 |
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Statistical table of correlation analysis of heavy metal elements in crop-root soil in the study area(N=45)
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