泌阳凹陷双河油田原油地球化学特征及精细油—源对比研究

doi:10.11720/wtyht.2019.1470

Abstract
Figure/Table
References
Related Citation (1)

Download: PDF (4598 KB) HTML (0 KB)
Export: BibTeX | EndNote (RIS)

Abstract

In this paper the authors mainly studied geochemical characteristics and oil-source rock correlations of 28 oil samples from the Shuanghe oilfield based on the gas chromatography-mass spectrometry and biomarkers. The results indicate that the peaks of C₁₉, C₂₀, C₂₁- tricyclic terpanes gradually rise and the peaks of C₂₇~C₂₉ steranes are characterized by "V" shape of crude oils in the Shuanghe Oilfield. Besides, the concentration of gammacerane is high. The peak shapes of saturates are characterized by "prepeak" and "double peak", and the relative values of diasteranes and tricyclic terpanes are low in oils from upper layer of the Eh₃ member. However, the peak shapes of saturates are characterized by "prepeak" and the relative content of diasteranes and tricyclic terpanes is high in oils from lower layer of the Eh₃ member. For both the oils of Eh₂ member and Eh₃ member, the sedimentary environments are reductive and are sourced from higher plant and aquatic organism. However, the maturity of the oil from lower layer of Eh₃ member is significantly higher than that of the oil from the upper layer of Eh₃ member. In conclusion, the oils from the lower layer of Eh₃ member are mainly sourced from the lower layer of Eh₃ member, and the oils from the upper layer of Eh₃ member are sourced from lower and upper layer of Eh₃ member.

Key words： Shuanghe oilfield crude oil biomarkers gas chromatography-mass spectrometry oil-source rock correlations

Received: 20 December 2018 Published: 25 October 2019

P632

Corresponding Authors: Xuan-Bo GAO E-mail: gaoxuanbo@qq.com

	Service

	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	Xin-Wen ZHANG
	Xuan-Bo GAO
	Yun-Fei YANG
	Chun-An XIE
	Jing-Juan TAN

Cite this article:

Xin-Wen ZHANG,Xuan-Bo GAO,Yun-Fei YANG, et al. Geochemistry and oil-source rock correlations in the Shuanghe oilfield, Biyang sag, Nanxiang basin[J]. Geophysical and Geochemical Exploration, 2019, 43(5): 966-975.

URL:

https://www.wutanyuhuatan.com/EN/10.11720/wtyht.2019.1470 OR https://www.wutanyuhuatan.com/EN/Y2019/V43/I5/966

Structural division and regional location of Biyang Sag

Crude oil group analysis of Biyang Sag

m/z 85 chromatograms showing saturated hydrocarbons of typical oil samples from Shuanghe Oilfield

井号	层位	深度/m	Pr/ nC₁₇	Ph/ nC₁₈	Pr/ Ph	∑nC₂₁-/ ∑nC₂₂+	主峰碳	OEP	低碳数甾烷/ 规则甾烷	重排甾烷/ 规则甾烷	C₂₉S/ (S+R)	C₂₉ββ/ (αα+ββ)	Ts/ Tm	C₂₉M/ C₃₀H	Tr/H	C₃₀G/ C₃₀H	C₂₄TeT/ C₂₆Tr
双浅3	H21	884.8	0.53	2.88	0.38	1.43	C₁₇	1.11	0.01	0.05	0.30	0.22	0.12	0.08	0.24	0.32	0.98
双资1	H31	1345.8	1.60	2.77	0.40	0.42	C₂₅	1.06	0.02	0.11	0.45	0.35	0.58	0.06	0.13	0.26	0.53
双T121	H31	1411.3	0.49	1.45	0.41	1.35	C₁₇	1.07	0.02	0.13	0.46	0.36	0.61	0.06	0.15	0.26	0.50
双T306L	H31	1378	0.55	1.43	0.33	0.44	C₂₇	1.01	0.04	0.11	0.49	0.36	0.50	0.14	0.22	0.21	0.49
双T306X	H31	1377.95	0.53	1.42	0.31	0.39	C₂₇	1.02	0.02	0.09	0.47	0.35	0.47	0.15	0.09	0.21	0.49
双3240	H32	1457.1	0.49	1.32	0.39	1.19	C₁₇	0.96	0.03	0.11	0.47	0.37	0.54	0.05	0.16	0.26	0.51
双资1	H33	1586.8	0.95	1.71	0.42	0.41	C₂₅	1.03	0.02	0.13	0.49	0.39	0.63	0.07	0.16	0.28	0.52
双资1	H33	1614.2	1.08	2.25	0.42	0.42	C₂₃	1.06	0.02	0.09	0.46	0.35	0.54	0.04	0.12	0.20	0.61
双K3103	H33	1649.7	0.45	1.37	0.40	1.02	C₁₇	0.96	0.02	0.12	0.47	0.37	0.59	0.05	0.12	0.22	0.52
双资1	H34	1722	1.09	2.16	0.38	0.31	C₂₇	1.03	0.02	0.12	0.45	0.37	0.53	0.07	0.08	0.26	0.55
双资2	H34	1660.8	1.47	1.93	0.32	0.27	C₁₈	0.94	0.06	0.17	0.55	0.54	1.41	0.33	0.67	0.38	0.43
双资2	H34	1799.5	0.88	1.02	0.67	0.51	C₂₂	1.03	0.07	0.19	0.53	0.51	0.74	0.33	1.30	0.50	0.52
双JK452	H34	1730.2	0.56	1.51	0.44	1.33	C₁₇	0.96	0.02	0.12	0.46	0.36	0.52	0.05	0.12	0.21	0.59
双H417L	H34	1752.9	0.50	1.33	0.33	0.46	C₂₇	1.02	0.03	0.10	0.50	0.38	0.53	0.15	0.14	0.19	0.52
双H417X	H34	1752.9	0.55	1.42	0.33	0.39	C₂₇	1.02	0.02	0.10	0.49	0.37	0.48	0.15	0.10	0.18	0.53
双资2	H35	1965.4	0.72	0.93	0.55	0.80	C₂₁	1.05	0.08	0.16	0.52	0.52	0.73	0.22	1.40	0.97	0.32
双资2	H35	1891.7	1.42	1.90	0.45	0.46	C₂₃	1.06	0.04	0.15	0.50	0.46	0.32	0.23	0.94	0.80	0.50
双资2	H35	1901	1.03	1.54	0.35	0.50	C₂₃	1.06	0.02	0.15	0.50	0.43	0.24	0.23	1.29	0.73	0.44
双3-23	H35	1917.6	0.33	0.61	0.55	1.64	C₁₈	0.95	0.08	0.19	0.56	0.55	1.45	0.30	0.85	0.26	0.43
双H494	H35	1758.4	0.62	1.77	0.46	1.58	C₂₂	0.97	0.07	0.12	0.54	0.52	0.81	0.18	0.11	0.26	0.56
双资2	H36	2028.3	0.87	1.69	0.34	0.60	C₂₂	1.09	0.06	0.17	0.50	0.47	0.39	0.30	1.27	0.83	0.34
双资2	H36	2097.9	0.86	1.41	0.46	1.05	C₂₀	0.96	0.06	0.17	0.51	0.47	1.29	0.27	1.01	0.67	0.37
双T4-136	H36	1953.6	0.43	1.06	0.51	1.62	C₁₇	1.05	0.04	0.13	0.49	0.43	3.35	0.19	0.96	0.71	0.42
双观20	H37	2005	0.46	1.31	0.42	1.73	C₁₇	1.06	0.07	0.20	0.53	0.50	0.80	0.68	1.38	0.96	0.26
双10-107	H37	1918.8	0.43	1.26	0.44	1.67	C₁₇	1.07	0.06	0.16	0.48	0.42	0.47	0.34	1.47	1.00	0.39
双资2	H38	2342.3	1.26	2.37	0.31	0.59	C₂₂	1.05	0.06	0.21	0.51	0.55	0.51	0.62	1.65	0.90	0.32
双资2	H38	2388.7	1.14	2.42	0.39	0.53	C₂₂	1.03	0.05	0.22	0.53	0.53	0.40	0.56	1.39	0.81	0.41
新泌42	H38	2282.4	0.59	1.93	0.32	2.70	C₁₇	1.06	0.00	0.00	0.50	0.46	0.30	0.07	1.00	1.08	0.38

Biomarker parameters of oils from Shuanghe Oilfield

Distribution diagram of Pr/Ph、Pr/nC₁₇、Ph/nC₁₈ of oils from Shuanghe Oilfield

m/z 217 chromatograms showing steranes of typical oil samples from Shuanghe Oilfield

Distribution diagram of C₂₇~C₂₉αααR steranes of oils from Shuanghe Oilfield

Plot of C₂₉ββ/(αα+ββ) versus C₂₉S/(S+R) showing the maturities of oils from Shuanghe Oilfield

m/z 191 chromatograms showing tricyclic terpanes and hopanes of typical oil samples from Shuanghe Oilfield

m/z 85 chromatograms showing saturated hydrocarbons of typical source rock and oil samples from Shuanghe Oilfield

m/z 217 chromatograms showing steranes of typical source rock and oil samples from Shuanghe Oilfield

Distribution diagram of Pr/Ph、Pr/nC₁₇、Ph/nC₁₈ of source rocks and oils from Shuanghe Oilfield

Plot of C₂₉ββ/(αα+ββ) versus C₂₉S/(S+R) showing the maturities of source rocks and oils from Shuanghe Oilfield

Distribution diagram of Pr/Ph versus C₃₀G/ C₃₀H of source rocks and oils from Shuanghe Oilfield

Distribution diagram of tricyclic terpanes /17α(H)-hopane versus C₃₀G/C₃₀H of source rocks and oils from Shuanghe Oilfield

[1]	Peters K E, Walters C C, Moldowan J M. The biomarker guide: Biomarkers and isotopes in petroleum exploration and earth history[M]. UK: Cambridge University Press, 2005.
[2]	李祖兵, 颜其彬, 罗明高 . 非均质综合指数法在砂砾岩储层非均质性研究中的应用——以双河油田V下油组为例[J]. 地质科技情报, 2007(6):83-87.
[2]	Li Z B, Yan Q B, Luo M G . Reservoir heterogeneity indication applied in researching for heterogeneity of the grail oil :An example of oil group below V in Shuanghe Oilfield[J]. Geological Science and Technology Information, 2007(6):83-87.
[3]	尹太举, 张昌民, 陈程 , 等. 建立储层流动单元模型的新方法[J]. 石油与天然气地质, 1999(2):74-79.
[3]	Yin T J, Zhang C M, Chen C , et al. A new method for founding the model of flow unit reservoirs[J]. OIL & GAS GEOLOGY, 1999(2):74-79.
[4]	赵跃华, 王敏 . 双河油田储层孔隙结构特征分类及影响因素[J]. 石油学报, 1994(4):31-39.
[4]	Zhao Y H, Wang M . Characteristics, classifications and affecting factors of reservoir pore structures in Shuanghe Oilfield[J]. ACTA PETROLEI SINICA, 1994(4):31-39.
[5]	尹太举, 张昌民, 赵红静 , 等. 依据高分辨率层序地层学进行剩余油分布预测[J]. 石油勘探与开发, 2001(4):79-82.
[5]	Yin T J, Zhang C M, Zhao J H , et al. Remaining oil distribution prediction based on high-resolution sequence stratigraphy[J]. Petroleum Exploration and Development, 2001(4):79-82.
[6]	陆建林, 李国强, 樊中海 , 等. 高含水期油田剩余油分布研究[J]. 石油学报, 2001,22(5):48-52.
[6]	Lu J L, Li G Q, Fan Z H , et al. Residual oil distribution research of high water-cut stage in an oilfield[J]. ACTA PETROLEI SINICR, 2001,22(5):48-52.
[7]	袁向春, 杨凤波 . 高含水期注采井网的重组调整[J]. 石油勘探与开发, 2003(5):94-96.
[7]	Yuan X C, Yang F B . Regrouping adjusting of the producer-injector well-pattern in the high aquifer period of oilfield development[J]. Petroleum Exploration and Development, 2003(5):94-96.
[8]	张昌民, 尹太举, 张尚锋 , 等. 双河油田陆架型扇三角洲的沉积机理及向上变粗层序的成因[J]. 石油与天然气地质, 2005(1):99-103.
[8]	Zhang C M, Yin T J, Zhang S F , et al. Sedimentary mechanism of shelf-type fan delta and genesis of coarsening-upward sequence in Shuanghe oilfield[J]. OIL &GAS GEOLOGY, 2005(1):99-103.
[9]	尹伟, 吴胜和, 林社卿 , 等. 双河油田油气成藏机理研究[J]. 石油学报, 2003(5):40-45.
[9]	Yin W W, Wu S H, Lin S Q , et al. Study on mechanism of oil and gas accumulation in Shuanghe Oilfield[J]. ACTA PETROLEI SINICA, 2003(5):40-45.
[10]	林社卿, 杨道庆, 夏东领 , 等. 双河油田地球化学特征及成藏意义[J]. 石油天然气学报:江汉石油学院学报, 2005(2):162-165.
[10]	Lin S Q, Yang D Q, Xia D L , et al. Geochemistry characteristics and significance of hydrocarbon accumulation in Shuanghe Oilfield[J]. Journal of Oil and Gas Technology, 2005(2):162-165.
[11]	董田, 何生, 林社卿 . 泌阳凹陷核桃园组烃源岩有机地化特征及热演化成熟史[J]. 石油实验地质, 2013(2):187-194.
[11]	Dong T, He S, Lin S Q , et al. Organic geochemical characteristics and thermal evolution maturity history modeling of source rocks in Eocene Hetaoyuan Formation of Biyang Sag,Nanxiang Basin[J]. PETROLEUM GEOLOGY & EXPERIMENT, 2013(2):187-194.
[12]	邱荣华, 林社卿, 涂阳发 . 泌阳凹陷油气成藏特征及勘探潜力分析[J]. 石油天然气学报:江汉石油学院学报, 2005(2):158-161.
[12]	Qiu R H, Lin S Q, Tu Y F . Features of hydrocarbon accumulation and analysis on exploration potential in Biyang depression[J]. Journal of Oil and Gas Technology, 2005(2):158-161.
[13]	Gao X, Zhu S, Zhang W , et al. Analysis of crude oils using gas purge microsyringe extraction coupled to comprehensive two dimensional gas chromatography-time-of-flight mass spectrometry[J]. Fuel, 2016,182:788-797.
[14]	Gao X, Pang L, Zhu S , et al. Gas purge microsyringe extraction coupled to comprehensive two-dimensional gas chromatography for the characterization of petroleum migration[J]. Organic Geochemistry, 2017,106:30-47.
[15]	Huang H, Zhang S, Su J . Palaeozoic oil-source correlation in the Tarim Basin, NW China: A review[J]. Organic Geochemistry, 2016,94:32-46.