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物探与化探  2023, Vol. 47 Issue (5): 1354-1360    DOI: 10.11720/wtyht.2023.1440
  生态地质调查 本期目录 | 过刊浏览 | 高级检索 |
陕西关中土壤富硒标准研究与探讨——以小麦为例
任蕊1,2(), 张志敏1,2, 王晖1,2, 陈继平1,2, 乔新星1,2, 梁东丽3
1.陕西省水工环地质调查中心,陕西 西安 710068
2.陕西省健康地质研究中心,陕西 西安 710054
3.西北农林科技大学 资源环境学院,陕西 杨凌 712100
Exploring selenium enrichment criteria for soils in the Guanzhong area, Shaanxi Province: A case study of wheat
REN Rui1,2(), ZHANG Zhi-Min1,2, WANG Hui1,2, CHEN Ji-Ping1,2, QIAO Xin-Xing1,2, LIANG Dong-Li3
1. Shaanxi Hygrogeology Engineering Geology and Environment Geology Survey Center, Xi’an 710068, China
2. Shaanxi Health Geology Research Center, Xi’an 710054, China
3. College of Natural Resources and Environment, Northwest A&F University, Yangling 712100, China
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摘要 

建立陕西省富硒小麦产地土壤硒阈值不仅关系到天然富硒小麦精益化、精细化、精确化生产,更能够提高富硒土地利用效率,促进陕西富硒产业发展。本文以1∶25万土地质量地球化学调查数据为基础,依托陕西省近年来采集的544组土壤及其对应的小麦籽实样品硒含量数据,基于关中地区表层土壤硒地球化学异常下限和小麦—土壤隶属函数结果,提出以0.27×10-6作为陕西省富硒小麦产地土壤硒阈值。实证研究发现,采用随机抽样得到的验证集的小麦富硒率达到83.78%,第三方检验的富硒率高达87.14%,以该阈值圈定的土地生产出的小麦能够满足中国营养学会规定的硒推荐摄入量(60 μg/d),土地面积约为1 500 km2(225万亩),比按0.3×10-6圈出的富硒土地增加了640 km2(96万亩)。由此可见,按照农作物种类有针对性地界定富硒土壤界限值,能够较大程度地提高富硒土地利用效率,促进富硒产业发展,为制定陕西省富硒土壤标准提供科学依据。

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任蕊
张志敏
王晖
陈继平
乔新星
梁东丽
关键词 富硒土壤评价标准关中地区    
Abstract

Establishing the selenium threshold for soils in selenium-rich wheat producing areas in Shaanxi Province is closely related to the lean, fine-scale, and accurate production of natural selenium-rich wheat. Moreover, it can improve the utilization efficiency of selenium-rich land, thus promoting the development of selenium-rich industry in this province. This study determined the selenium threshold of soils in selenium-rich wheat producing areas in Shaanxi at 0.27×10-6 based on the 1∶250 000 land quality geochemical survey data, the selenium concentration data of 544 sets of soil samples and corresponding wheat seed samples collected in Shaanxi in recent years, the lower limit of geochemical anomalies of selenium in topsoil in the Guanzhong area, and the wheat-soil function. The empirical study showed that the validation set formed via random sampling yielded a selenium accumulation rate of 83.78%, while the third-party inspection yielded a selenium accumulation rate of 87.14%. The wheat produced from selenium-rich land delineated based on the selenium threshold 0.27×10-6 satisfies the recommended nutrient intake of selenium (60 μg/d) stipulated by the Chinese Nutrition Society. Furthermore, the area of the selenium-rich land is about 1 500 km2 (2 250 000 mu), increasing by 640 km2 (960 000 mu) compared with that of land delineated based on a selenium threshold of 0.3×10-6. Therefore, determining selenium-rich soil threshold by crop species can greatly improve the utilization efficiency of selenium-rich land, thus promoting the development of the selenium-rich industry. This study provides a scientific basis for setting selenium enrichment criteria for soils in Shaanxi Province.

Key wordsselenium-rich soil    evaluation criterion    Guanzhong area
收稿日期: 2022-09-06      修回日期: 2023-03-30      出版日期: 2023-10-20
ZTFLH:  X142  
  X825  
基金资助:陕西省公益性地质调查项目“秦巴山区健康地质调查与评价”(202201);“陕西省关中地区碱性富硒土地开发利用综合研究”(20180307)
作者简介: 任蕊(1984-),女,高级工程师,主要从事农业地质调查与地球化学研究工作。Email:877529793@qq.com
引用本文:   
任蕊, 张志敏, 王晖, 陈继平, 乔新星, 梁东丽. 陕西关中土壤富硒标准研究与探讨——以小麦为例[J]. 物探与化探, 2023, 47(5): 1354-1360.
REN Rui, ZHANG Zhi-Min, WANG Hui, CHEN Ji-Ping, QIAO Xin-Xing, LIANG Dong-Li. Exploring selenium enrichment criteria for soils in the Guanzhong area, Shaanxi Province: A case study of wheat. Geophysical and Geochemical Exploration, 2023, 47(5): 1354-1360.
链接本文:  
https://www.wutanyuhuatan.com/CN/10.11720/wtyht.2023.1440      或      https://www.wutanyuhuatan.com/CN/Y2023/V47/I5/1354
Fig.1  关中地区行政区划
计算方法 地球化学定义 区间划分 表层Se含量区间/10-6
累积频率法
(n=10 114)
低值区 <5% w(Se)<0.11
低背景区 5%~<25% 0.11≤w(Se)<0.14
背景区 25%~<75% 0.14≤w(Se)<0.20
高背景区 75%~<85% 0.20≤w(Se)<0.22
弱异常区 85%~<95% 0.22≤w(Se)<0.28
异常区 95%~<98.5% 0.28≤w(Se)<0.37
强异常区 ≥98.5% w(Se)≥0.37
Table 1  关中地区表层土壤硒含量分级统计
土壤分组 1组 2组 3组 4组 5组 6组
根系土硒含量 0.1≤w(Se)<0.2 0.2≤w(Se)<0.3 0.3≤w(Se)<0.4 0.4≤w(Se)<0.5 0.5≤w(Se)<0.6 w(Se)>0.6
样本量 32 174 139 78 46 66
根系土硒均值 0.156 0.249 0.346 0.441 0.537 0.808
小麦硒均值 0.079 0.086 0.133 0.207 0.255 0.488
小麦硒最小值 0.018 0.011 0.011 0.027 0.050 0.059
小麦硒最大值 0.339 0.590 0.525 0.472 0.856 1.395
Table 2  小麦样品数据分组统计
根系土硒
含量组别
小麦硒含
量组别
显著性 根系土硒
含量组别
小麦硒含
量组别
显著性
1 2 0.996 4 1 0
3 0.009 2 0
4 0 3 0
5 0 5 0.461
6 0 6 0
2 1 0.996 5 1 0
3 0 2 0
4 0 3 0
5 0 4 0.461
6 0 6 0
3 1 0.009 6 1 0
2 0 2 0
4 0 3 0
5 0 4 0
6 0 5 0
Table 3  小麦硒含量的多重比较检验
Fig.2  不同土壤中小麦硒含量均值折线
Fig 3  土壤—小麦硒含量相关性
指标要求 土壤硒含量/
10-6
土壤环境质量
富硒 w(Se)≥0.27 镉、汞、砷、铅、铬、铜、镍和锌元素含量低于GB 15618—2018标准中农用地土壤污染风险筛选值
Table 4  陕西小麦产地富硒土壤分级指标
Fig.4  验证样本分布位置示意
统计量 小麦籽粒硒/
10-6
根系土硒/
10-6
土壤pH
最小值 0.014 0.102 7.670
最大值 0.165 1.674 8.670
中位数 0.053 0.754 8.185
平均值 0.056 0.781 8.163
标准差 0.031 0.390 0.214
Table 5  小麦样品数据统计表(n=76)
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