金沙江流域底泥重金属污染特征及来源解析——以蜻蛉河为例

    Characteristics and source analysis of heavy metal contamination in the sediments of the Jinsha River Basin: A case study of the Qingling River

    • 摘要: 为了解金沙江流域底泥重金属的污染特征及来源情况,以金沙江南岸支流龙川江的一级支流蜻蛉河流域为研究区,共选取22个代表性断面布设底泥采样点,对底泥中8种重金属元素As、Cd、Cr、Cu、Hg、Ni、Pb和Zn含量进行测试分析。通过数据统计分析了底泥重金属元素的含量分布特征和沿程分布特征;运用相关性分析、主成分分析方法探究了重金属的来源;运用地累积指数法、内梅罗指数法对蜻蛉河底泥重金属的污染程度进行了评价。研究结果表明,As、Cd、Cu、Hg、Ni、Pb、Zn主要受矿产开采、农业活动和工业活动的共同影响;Cr、Ni主要来源于成土母质,而Ni除了自然来源外,还受到了人为来源的影响。地累积指数法、内梅罗指数法的评价结果表明,8种重金属元素的平均污染程度不高,但存在部分元素在流域局部污染富集,主要集中在老街子Au-Pb-Ag多金属矿区和县城下游的城乡结合区,代表元素为Cd、Hg、Pd和Zn。

       

      Abstract: To understand the characteristics and sources of heavy metal contamination in the sediments of the Jinsha River basin, this study investigated the Qingling River basin-a primary tributary of Longchuan River on the south bank of the Jinsha River. Samples were collected from the sediments of 22 representative sections, and the concentrations of eight heavy metal elements, i.e., As, Cd, Cr, Cu, Hg, Ni, Pb, and Zn, were tested and analyzed. Statistical analysis was conducted on the distribution characteristics of these heavy metal elements in the sediments along the basin. The sources of these heavy metals were investigated using correlation analysis and principal component analysis, and the degree of heavy metal contamination in the sediments was assessed using the geo-accumulation index and the Nemero index. The results indicate that As, Cd, Cu, Hg, Ni, Pb, and Zn are primarily influenced by mining, agricultural, and industrial activities. Cr and Ni originate primarily from soil-forming parent materials. Besides natural sources, Ni is also affected by anthropogenic sources. The assessment results derived using the geo-accumulation and Nemero indices reveal that the eight heavy metal elements exhibit moderate or low contamination on average. However, partial elements, represented by Cd, Hg, Pb, and Zn, exhibit localized enrichment within the basin, primarily concentrated in the Laojiezi Au-Pb-Ag polymetallic mining area and the urban-rural junction in the lower reaches of the county.

       

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