MODES OF OCCURRENCE OF GOLD IN SAMPLES RICH IN ORGANIC MATTER FROM FOREST-SWAMP AREAS AND THEIR INFLUENCE UPON ANALYSIS
CHENG Zhi-zhong1, WANG Xue-qiu1, HU Zhong-xian2, YANG Zhao-wu2
1. Institute of Geophysical and Geochemistry Exploration, CAGS, Langfang Hebei 065000, China;
2. No. 1 Regional Geological Survey of Heilongjiang Province, Harbin 150080, China
In order to probe into the causes of relatively low gold content in samples rich in organic matter from forest-swamp areas of Northeast China, the authors used AAS analysis with aqua regia solution method and AAS analysis with tetracid solution method to determine Au content of samples. The application of the tetracid solution method to eliminating silica gel can obviously raise the determination value of gold. For samples with gold content higher than 10~(-9), the difference between the two methods are especially evident. The above investigation shows that gold in samples rich in organic matter from forest-swamp areas can exist not only in the form of organic combination but also in the colloid or nanometer form. Wrapped by SiO2 colloid, gold can migrate for a long distance in water solution in an active form under the protection of high-concentration organic acid. Nevertheless, the aqua regia solution method fails to determine such SiO2 colloid-wrapped gold.
程志中, 王学求, 胡忠贤, 杨兆武. 森林沼泽区富含有机质样品中金的存在形式及对分析的影响[J]. 物探与化探, 2004, 28(3): 206-208.
CHENG Zhi-zhong, WANG Xue-qiu, HU Zhong-xian, YANG Zhao-wu . MODES OF OCCURRENCE OF GOLD IN SAMPLES RICH IN ORGANIC MATTER FROM FOREST-SWAMP AREAS AND THEIR INFLUENCE UPON ANALYSIS. Geophysical and Geochemical Exploration, 2004, 28(3): 206-208.
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