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物探与化探  2019, Vol. 43 Issue (4): 692-701    DOI: 10.11720/wtyht.2019.0013
     地质调查·资源勘查 本期目录 | 过刊浏览 | 高级检索 |
土壤铁锰氧化物结合态元素提取技术在内蒙古新巴尔虎右旗头道井铜金矿地球化学勘查中的应用试验
杨帆1,2,3,4, 郝志红2,3, 张素荣5, 徐进力2,3, 王京彬1, 成杭新2,3(), 胡瑞忠4, 张舜尧2,3
1. 北京矿产地质研究院,北京 100012
2. 中国地质调查局 土地质量地球化学调查评价研究中心,河北 廊坊 065000
3. 中国地质科学院 地球表层碳—汞地球化学循环重点实验室,河北 廊坊 065000;
4. 中国科学院地球化学研究所 矿床地球化学国家重点实验室,贵州 贵阳 550002
5. 天津地质矿产研究所,天津 300170
A geochemical ore-prospecting experiment by extracting Fe-Mn oxides bound in soil samples in the Toudaojing Cu-Au deposit in Xin Barag Right Banner, Inner Mongolia
Fan YANG1,2,3,4, Zhi-Hong HAO2,3, Su-Rong ZHANG5, Jin-Li XU2,3, Jing-Bin WANG1, Hang-Xin CHENG2,3(), Rui-Zhong HU4, Shun-Yao ZHANG2,3
1. Beijing Institute of Geology for Mineral Resources, Beijing 100012, China
2. Research Center of Geochemical Survey and Assessment on Land Quality, China Geological Survey, Langfang 065000, China
3. Key Laboratory of Geochemical Cycling of Carbon and Mercury in the Earth's Critical Zone, Chinese Academy of Geological Sciences, Langfang 065000, China
4. State Key Laboratory of Ore Deposit Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550002, China
5. Tianjin Institute of Geology and Mineral Resources, Tianjin 300170, China
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摘要 

针对常规地球化学方法在水系不发育而风成砂较发育的内蒙古丘陵草原覆盖区找矿效果均不理想的问题,以新巴尔虎右旗头道井铜金矿为试验研究区,开展土壤样品中的铁锰氧化物结合态地球化学找矿试验。采用等离子体质谱法、原子荧光光谱法和无火焰原子吸收光谱法配套测试土壤铁锰氧化物结合态的元素含量,利用面积性试验对比矿体上方和外围土壤铁锰氧化物结合态的元素异常特征,圈定并发现了新的隐伏金矿体。结果表明,本次土壤铁锰氧化物结合态元素分析测试方法的精确度和准确度满足地球化学找矿的需求;土壤铁锰氧化物结合态可有效圈定找矿靶区,寻找隐伏金矿。本试验是一项成功的找矿案例,可为该类丘陵草原覆盖区开展地球化学找矿活动提供借鉴。

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杨帆
郝志红
张素荣
徐进力
王京彬
成杭新
胡瑞忠
张舜尧
关键词 覆盖区地球化学找矿铁锰氧化物结合态金矿隐伏矿    
Abstract

The ore-prospecting effect of the stream sediment survey and the soil geochemistry survey is not ideal in the covered areas of the hilly grassland landscape where the water system is not developed whereas the aeolian sand is very developed. Therefore, it is imperative to carry out some new ore-prospecting experiment for prospecting breakthrough. In this study, the experiment was carried out by using the Fe-Mn oxides bound in the soil samples in a selected experimental site. The Toudaojing Cu-Au deposit in Xin Barag Right Banner of Inner Mongolia was selected as the experimental site. Soil samples were collected in the ore area and its periphery. Element concentrations in the Fe-Mn oxides bound in soil samples were determined by matched analysis of scheme including plasma mass spectrometry, atomic fluorescence spectroscopy and flameless atomic absorption spectrometry. Areal test for this geochemical ore-prospecting technique was carried out for delineating geochemical anomaly. Geochemical anomaly was verified by drilling, and new concealed gold orebodies were found. The results show that accuracy and precision tests of the analytical method could satisfy the requirements of geochemical ore-prospecting. The Fe-Mn oxides bound in soil samples can effectively delineate the prospecting target area and find concealed gold deposits in the Toudaojing Cu-Au deposit in Xin Barag Right Banner of Inner Mongolia. Therefore, it is a successful case of geochemical ore-prospecting in the covered area.

Key wordscovered area    geochemical prospecting    Fe-Mn oxides bound    gold mine    concealed orebody
收稿日期: 2019-01-07      出版日期: 2019-08-15
:  P632  
基金资助:中国地质调查局项目“全国土地质量综合监测与评价”(DD20190527);中国地质调查局项目“乌蒙山区土地质量地球化学调查”(DD20190522);中央级公益性科研院所基本科研业务费专项项目(AS2015J03)
通讯作者: 成杭新
作者简介: 杨帆(1983-),男,高级工程师,博士研究生,主要从事勘查地球化学及环境地球化学相关基础理论研究和调查评价工作。Email: yangfan@igge.cn
引用本文:   
杨帆, 郝志红, 张素荣, 徐进力, 王京彬, 成杭新, 胡瑞忠, 张舜尧. 土壤铁锰氧化物结合态元素提取技术在内蒙古新巴尔虎右旗头道井铜金矿地球化学勘查中的应用试验[J]. 物探与化探, 2019, 43(4): 692-701.
Fan YANG, Zhi-Hong HAO, Su-Rong ZHANG, Jin-Li XU, Jing-Bin WANG, Hang-Xin CHENG, Rui-Zhong HU, Shun-Yao ZHANG. A geochemical ore-prospecting experiment by extracting Fe-Mn oxides bound in soil samples in the Toudaojing Cu-Au deposit in Xin Barag Right Banner, Inner Mongolia. Geophysical and Geochemical Exploration, 2019, 43(4): 692-701.
链接本文:  
https://www.wutanyuhuatan.com/CN/10.11720/wtyht.2019.0013      或      https://www.wutanyuhuatan.com/CN/Y2019/V43/I4/692
Fig.1  头道井铜金矿区交通位置及区域构造简图
Fig.2  头道井铜金矿地质图
标准物质 参数 Cu Mo Pb Zn As Hg Sb
GBW07441
GSF-1
平均值 3.5 0.024 15 6.3 1.6 2.1 0.012
标准差 0.8 0.005 3 1.3 0.4 0.5 0.003
精密度(Dr,s)/% 22.8 20.082 19 20.1 24.4 23.1 27.660
标准推荐值 3.5 0.025 16 6.2 1.5 2 0.011
准确度(ΔlgC) 0.001 -0.012 -0.026 0.010 0.017 0.014 0.022
GBW07442
GSF-2
平均值 12.7 0.039 17.7 29.9 1.3 1.3 0.020
标准差 2.6 0.008 3.6 5.7 0.3 0.3 0.005
精密度(Dr,s)/% 20.5 21.144 20.3 19.2 19.9 22.1 22.344
标准推荐值 11.6 0.041 18.2 30 1.2 1.2 0.02
准确度(ΔlgC) 0.038 -0.022 -0.012 -0.001 0.029 0.027 0.009
GBW07443
GSF-3
平均值 12.4 0.045 284 76.9 96.8 154.3 0.454
标准差 2.5 0.007 58 11.7 18.5 32.0 0.102
精密度(Dr,s)/% 20.1 16.426 21 15.2 19.1 20.8 22.424
标准推荐值 12.4 0.036 280 78 100 170 0.48
准确度(ΔlgC) -0.001 0.097 0.006 -0.006 -0.014 -0.042 -0.024
Table 1  方法准确度和精密度
元素 Au Ag Cu Pb Zn As Sb Hg Mo Bi
最小值 16.29 9.18 7.13 6.53 6.14 10.66 12.35 8.51 11.52 13.61
最大值 19.97 17.63 14.61 12.82 13.89 18.15 19.57 16.37 17.13 19.35
Table 2  重复样检验相对误差%
特征值 Au Ag As Bi Cu Hg Mo Pb Sb Zn
最小值 0.001 0.1 12.5 0.2 0.03 0.01 1.7 0.03 1.05 0.01
最大值 2.681 12827 11078 678 8271 338 623 98.8 5637 2074
平均值 0.095 33.22 279.1 27.47 2.88 0.19 16.94 6.19 8.69 6.45
标准离差 0.045 14.32 110.1 15.34 1.51 0.05 6.95 2.78 2.8 2.8
异常下限 0.185 61.8 499.3 58.2 5.9 0.29 30.8 11.8 14.3 12.1
本文所用异常下限(T成图) 0.15 60 400 50 6 0.3 30 12 15 12
Table 3  铁锰氧化物结合态中元素的特征值
Fig.3  试验区金元素及综合异常分布
Fig.4  试验区锑元素异常分布
Fig.5  试验区砷元素异常分布
Fig.6  试验区物化探综合异常剖析
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